Immobilization of Ascorbic Acid on Ni-Zn Layered Hydroxide Salts and its Application as [AuCl₄]^- Adsorbent

Abstract:

Immobilization of ascorbic acid on Ni-Zn LHS (Nickel-Zink Layered Hydroxide Salt) was done through sample preparations and immobilization studies. Ni-Zn LHS was synthesized using coprecipitation method by mixing Ni (NO₃)₂ and Zn (NO₃)₂ with molar ratio 2:1, respectively. The green solid material was characterized using XRD, FTIR and SEM-EDX. Diffraction pattern of Ni-Zn LHS shows the peaks from (001), (003), (020) and (220) reflections at 9.30, 18.99, 33.36 and 59.50o, respectively. Ni-Zn LHS has zero charge or netral at pH 6.7. There is no significant shift of 2θ shown after immobilization process. It indicated that ascorbic acid was present on the outer material’s surface. The successful of immobilization was confirmed by the presence of ascorbic groups in FTIR spectra. The 2924 and 1465 cm^-1 were the bands of C-H sp³ and C-H sp², respectively. The immobilized material shown the decreasing of wide range particle size. The Ni, Zn, N and O atoms were detected in Ni-Zn LHS, Ni and Zn were the metal and N and O were the nitrate ion. Immobilization were confirmed by the presence of C atom on material’s surface, C was indicated the ascorbic acid. The immobilization process was followed the Langmuir model due to the highest value of correlation coefficient. Langmuir model assumed that there’s one major interaction in adsorption. The Ni-Zn-AA LHS has stability at pH 5-6 due to its lowest amount of ascorbic acid that released from the structure. The adsorption of [AuCl₄]^- was successfully done at pH 6 following pseudo second order kinetic model and Freundlich adsorption isotherm model with correlation coefficient 0.9791 and 0.9381, respectively.

• Periodical: Materials Science Forum (Volume 1067)
• Pages: 139-146
• DOI: https://doi.org/10.4028/p-08z04g
• Online since: August 2022
• Authors: Mikha Meilinda Christina*, Bambang Rusdiarso, Sri Juari Santosa
• Keywords: [AuCl₄]^-, Adsorption, Ascorbic Acid, Immobilization, Ni-Zn LHS

References

[1] Ahmad, R., Hussein, M. Z., Kadir, W. R. W. A., Sarijo, S. H., Hin, T. Y. Y., 2015, Evaluation of Controlled -Release Property and Phototoxicity Effect of Insect Pheromone Zinc-Layered Hydroxide Nanohybrid Intercalated with Hexenoic Acid, J. Agric. Food Chem., 63, 10893-10902.

DOI: 10.1021/acs.jafc.5b03102

[2] Arizaga, G. G. C., Satyanarayana, K. G., Wypych, F., 2007, Layered Hydroxide Salts: Properties and Potential Applications, Solid State Ion., 178, 1143-1162.

DOI: 10.1016/j.ssi.2007.04.016

[3] Leal, D. A., Wypych, F., Marino, C. E. B., 2020, Zinc-Layered Hydroxide Salt Intercalated with Molybdate Anions as a New Smart Nanocontainer for Active Corrosion Protection of Carbon Steel, ACS Appl. Mater. Interfaces, 12, 19823-19833.

DOI: 10.1021/acsami.0c02378

[4] Poul, L., Jouini, N., Fievet, F., 2000, Layered Hydroxide Metal Acetates (Metal = Zinc, Cobalt and Nickel): Elaboration via Hydrolysis in Polyol Medium and Comparative Study, Chem. Mater., 12, 3123-3132.

DOI: 10.1021/cm991179j

[5] Neilson, J. R., Schwenzer, B., Seshadri, R., Morse, D. E., 2009, Kinetic Control of Interlayer Cobalt Coordination in Layered Hydroxides: Co1-0.5x octCoxtet (OH)2(Cl)x(H2O)n, Inor. Chem., 48, 11017-11023.

DOI: 10.1021/ic901167u

[6] Yamanaka, S., Ando, K., Ohashi, M., 1995, New Anion Exchangable Layered Mixed Basic Salt Ni1-xZn2x(OH)2(OCOCH3)2x·nH2O, Mat. Res. Soc. Symp. Proc., 371, 131-142.

[7] Tas, M., Altin, Y., Bedeloglu, A. Y., 2019, Reduction of Graphene Oxide Thin Films using A Stepwise Thermal Annealing Assisted by L-Ascorbic Acid, Diamond & Related Materials, 92, 242-247.

DOI: 10.1016/j.diamond.2019.01.009

[8] Merino, M. J. F., Guardia, L., Paredes, I., Rodil, S. V., Fernandez, P. S., Alonso, A. M., Tascon, J. M. D., 2010, Vitamin C is An Substitute for Hydrazine in The Reduction of Graphene Oxide Suspensions, J. Phys. Chem., 114, 6426-6432.

DOI: 10.1021/jp100603h

[9] Elmagirbi, A., Sulistyarti, H., Atikah, 2012, Study of Ascorbic Acid as Iron(III) Reducing Agent for Spectrophotometric Iron Speciation, J. Pure App. Chem. Res., 1(1), 11-17.

DOI: 10.21776/ub.jpacr.2012.001.01.101

[10] An, F. Q., Li, M., Guo, X. D., Wang, H. Y., Wu, R. Y., Hu, T. P., Gao, J. F., Jiao, W. Z., 2017, Selective Adsorption of AuCl4- on Chemically Modified D301 Resin with Containing N/S Functional Polymer, Journal of Environmental Chemical Engineering, 5, 10-15.

DOI: 10.1016/j.jece.2016.11.010

[11] Ongaratto, G. C., Oro, G., Kalschne, D. L., Cursino, A. C. T., Canan, C., 2021, Cochineal carmine Adsorbed on Layered Zinc Hydroxide Salt Applied on Mortadella to Improve Color Stability, Current Research in Food Science, 4, 758-764.

DOI: 10.1016/j.crfs.2021.10.006

[12] Ikhsani, I. Y., Santosa, S. J., Rusdiarso, B., 2016, Comparative Study of Ni-Zn LHS and Mg-Al LDH Adsorbents of Navy Blue and Yellow F3G Dye, Indones. J. Chem., 16 (1), 36-44.

DOI: 10.22146/ijc.21175

[13] Santosa, S. J., Fitriani, D., Aprilita, N. H., Rusdiarso, B., 2020, Gallic and Salicylic Acid-Functionalized Mg/Al Hydrotalcite as Highly Effective Materials for Reductive Adsorption of AuCl4-, Appl. Surf. Sci., 507, 145115.

DOI: 10.1016/j.apsusc.2019.145115

[14] Musthaq, M., Tan, I. M., Ismail, L., Nadeem, M., Sagir, M., Azam, R., Hashmet, R., 2014, Influence of PZC (Point of Zero Charge) on The Static Adsorption of Anionic Surfactants on A Malaysian Sandstone, J. Dispers. Sci. Tech., 35: 3, 343-349.

DOI: 10.1080/01932691.2013.785362

[15] Tanaka, K., Kozai, N., Yamasaki, S., Ohnuki, T., Kaplan, D. I., 2019, Adsorption Mechanism of ReO4- on Ni-Zn Layered Hydroxide Salt and its Application to Removal of ReO4- as A Surrogate of TcO4-, Appl. Clay Sci., 182, 1-8.

DOI: 10.1016/j.clay.2019.105282

[16] Amnillah, M. R. T., 2019, Sintesis Garam Hidroksi Berlapis Nikel-Seng Terimobilisasi Asam Salisilat (Sal-Ni-Zn-LHS) dan Penggunaannya untuk Adsorpsi Reduktif [AuCl4]-, Tesis, Departemen Kimia FMIPA UGM, Yogyakarta.

[17] Rojas R., Ulibarri, M. A., Barriga, C., Rives, V., 2008, Intercalation of Metal-EDTA Complexes in Ni-Zn Layered Hydroxysalts and Study of their Thermal Stability, Micropor. Mesopor. Mat., 112, 262-272.

DOI: 10.1016/j.micromeso.2007.09.042

[18] Langmuir, I., 1916, The Constitution and Fundamental Properties of Solids amd Liquids, J. Am. Chem. Soc., 38, 2221-2295.

DOI: 10.1021/ja02268a002

[19] Freundlich, H. M. F., 1906, Over the Adsorption in Solution, J. Phys. Chem. A., 57, 385-470.

[20] Lagergren, S., 1898, About The Theory of So-Called Adsorption of Soluble Substances, K. Sven. Vetenskapsakad. Handl., 24, 1-39.

[21] Ho, Y. S., Wase, D. A. J., Forster, C. F., 1996, Removal of Lead Ions from Aqueous Solution using Sphagnum Moss Peat as Adsorbent, Water SA, 22, 219-224.

DOI: 10.1016/0043-1354(94)00236-z

[22] Santosa, S. J., 2014, Sorption Kinetics of Cd(II) Species on Humic Acid-Based Sorbent, Clean-Soil Air Water, 42(6), 760-766.

DOI: 10.1002/clen.201200684

[23] Kumar, K. V., Porkodi, K., Rocha, F., 2008, Langmuir-Hinshelwood Kinetics – A Theoritical Study, Catalyst Communication, 9, 82-84.