Polypropylene/Date Palm Fiber Nano Filler Biocomposites: Investigation of some Rheological Aspects

Article Preview

Abstract:

Rotational rheology was used to analyze the performance of polypropylene (PP) composites reinforced with date palm nanofiber (DNF) in the molten state in this study. In the first stage, mechanical ball milling was used to obtain date nanofillers with average filler sizes ranging from 30–110 nm in width and 1–10 mm in length. Dry blending technique was used to reinforce this filler to the polypropylene in the 1-5wt. % loading. The resulting PP/DNF biocomposites were subsequently tested using a rotating rheometer with a 25 mm parallel plate geometry. The broad range of angular frequency from 0.1 rad·s−1 to 100 rad·s−1 was applied to study their complex viscosity (η*) at a fix strain (1%). The decrease in complex viscosity with angular frequency in all the samples was observed compared to the neat PP. The complex viscosity of the neat PP and the 5 wt.% of filler samples at 0.1 rad·s−1 frequency was found to have 18170 Pa. s and 5335 Pa. s, respectively. Therefore, this analysis revealed that this biocomposites exhibits typical viscoelastic behavior of entangled polymeric liquid.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1083)

Pages:

99-104

Citation:

Online since:

April 2023

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2023 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Nassar, M.M.A., et al., New Synthesis Routes toward Improvement of Natural Filler/Synthetic Polymer Interfacial Crosslinking. Polymers, 2022. 14(3): p.629.

DOI: 10.3390/polym14030629

Google Scholar

[2] Rabbani, F.A., et al., Experimental Study of Mechanical Properties of Polypropylene Random Copolymer and Rice-Husk-Based Biocomposite by Using Nanoindentation. Materials, 2022. 15(5): p.1956.

DOI: 10.3390/ma15051956

Google Scholar

[3] Babacar Niang, A.K.F., Abdoul Karim Mbodji, Nicola Schiavone, Haroutioun Askanian, Vincent Verney, Diène Ndiaye, Abdoulaye Bouya Diop, Bouya Diop, Contribution to the Study of the Thermal, Rheological and Morphological Properties of Biocomposites Based on Typha/PP. nternational Journal of Materials Science and Applications, 2022. 11(1): p.8.

DOI: 10.11648/j.ijmsa.20221101.15

Google Scholar

[4] Khieng, T.K., et al., A Review on Mechanical Properties of Natural Fibre Reinforced Polymer Composites under Various Strain Rates. Journal of Composites Science, 2021. 5(5): p.130.

DOI: 10.3390/jcs5050130

Google Scholar

[5] Monteiro, S.N., et al., Thermogravimetric Stability of Polymer Composites Reinforced with Less Common Lignocellulosic Fibers – an Overview. Journal of Materials Research and Technology, 2012. 1(2): pp.117-126.

DOI: 10.1016/s2238-7854(12)70021-2

Google Scholar

[6] Saravanakumaar, A., A. Senthilkumar, and B. Muthu Chozha Rajan, Effect of Fillers on Natural Fiber–Polymer Composite: An Overview of Physical and Mechanical Properties, in Mechanical and Dynamic Properties of Biocomposites. 2021. pp.207-233.

DOI: 10.1002/9783527822331.ch11

Google Scholar

[7] Jagadeesh, P., et al., Effect of natural filler materials on fiber reinforced hybrid polymer composites: An Overview. Journal of Natural Fibers, 2020: pp.1-16.

DOI: 10.1080/15440478.2020.1854145

Google Scholar

[8] Lu, N., S. Oza, and M. Tajabadi, Surface Modification of Natural Fibers for Reinforcement in Polymeric Composites. 2015. pp.224-237.

DOI: 10.1002/9781119044901.ch9

Google Scholar

[9] Faiad, A., et al., Date Palm Tree Waste Recycling: Treatment and Processing for Potential Engineering Applications. Sustainability, 2022. 14(3): p.1134.

DOI: 10.3390/su14031134

Google Scholar

[10] Shaikh, H.M., et al., Isolation and Characterization of Alpha and Nanocrystalline Cellulose from Date Palm (Phoenix dactylifera L.) Trunk Mesh. Polymers, 2021. 13(11): p.1893.

DOI: 10.3390/polym13111893

Google Scholar

[11] Shaikh, H.M., Thermal, rheological, and mechanical properties of polypropylene/phosphate ore composites. Construction and Building Materials, 2020. 263: p.120151.

DOI: 10.1016/j.conbuildmat.2020.120151

Google Scholar

[12] Mazzanti, V. and F. Mollica, A Review of Wood Polymer Composites Rheology and Its Implications for Processing. Polymers, 2020. 12(10): p.2304.13.

DOI: 10.3390/polym12102304

Google Scholar

[13] Nassar, M.et al., New Synthesis Routes toward Improvement of Natural Filler/Synthetic Polymer Interfacial Crosslinking. Polymers, 2022. 14(4): p.629.

DOI: 10.3390/polym14030629

Google Scholar

[14] Soury, E., et al., Rheological Investigation of Wood-Polypropylene Composites in Rotational Plate Rheometer. Journal of Polymers and the Environment, 2012. 20(4): pp.998-1006.

DOI: 10.1007/s10924-012-0502-x

Google Scholar

[15] Durmus, A., M. Ozcan, and I. Aydin, Quantifying effects of compositional variations on microstructural properties of polypropylene-wood fiber composites by melt rheology and tensile test data. Journal of Composite Materials, 2019. 53(4): pp.503-514.

DOI: 10.1177/0021998318786792

Google Scholar