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Influence of the Morphological and Chemical Properties of Nanosized Metal Oxides on Catalytic Efficiency for the Cycloaddition Reaction of CO2 to Epoxides

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Abstract:

Metal oxides represent “workhorse catalysts” for the chemical industry with multifarious applications in dehydrogenation, metathesis, transesterification, and combustion reactions. It is therefore crucial, for each given catalytic process, to investigate the impact of morphological and physicochemical properties on catalytic performance. Metal oxide materials are being increasingly applied as inexpensive catalytic materials for the cycloaddition of CO2 to epoxides but the correlation between the chemical properties of the metal oxides and their catalytic activity has not been systematically investigated. In this work, we prepared nanostructured tin (IV) oxide (SnO2) and zinc oxide (ZnO) materials with different morphologies such as quantum dots (QDs), nanowires (NWs), microdisks (µDs) and nanoplates (NPLs). Following characterization, these materials were investigated, in combination with low amounts of tetrabutylammonium iodide (TBAI) as a nucleophile, for the CO2 cycloaddition to styrene oxide (SO) yielding cyclic styrene carbonate (SC) under atmospheric pressure. The correlation between catalytic performance, surface area, acidity and basicity was investigated and discussed.

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Periodical:

Materials Science Forum (Volume 1099)

Pages:

189-195

DOI:

https://doi.org/10.4028/p-cQ7Xe5

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Online since:

October 2023

Authors:

Sawarin Saengsaen, Silvano Del Gobbo*, Valerio D'Elia

Keywords:

Binary Catalytic System, CO2 Cycloaddition, Cyclic Carbonate, Tin Oxide, Zinc Oxide

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© 2023 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] M. Sathish, K.J. Sreeram, J. Raghava Rao, B. Unni Nair: ACS Sustainable Chem. Eng. 4 (2016) 1032-1040.

DOI: 10.1021/acssuschemeng.5b01121

Google Scholar

[2] S.B. Lawrenson, R. Arav, M. North: Green Chem., 19 (2017) 1685-1691.

Google Scholar

[3] B. Grignard, S. Gennen, C. Jérôme, A.W. Kleij, C. Detrembleur: Chem. Soc. Rev., 48 (2019) 4466-4514.

DOI: 10.1039/c9cs00047j

Google Scholar

[4] N. Yadav, F. Seidi, S. Del Gobbo, V. D'Elia, D. Crespy: Polym. Chem., 10 (2019) 3571-3584.

Google Scholar

[5] W. Guo, J.E. Gómez, À. Cristòfol, J. Xie, A.W. Kleij: Angew. Chem. Int. Ed., 57 (2018) 13735-13747.

DOI: 10.1002/anie.201805009

Google Scholar

[6] F. Della Monica, A.W. Kleij: Catal. Sci. Technol. 10 (2020) 3483-3501.

Google Scholar

[7] V. D' Elia, A.W. Kleij: Green Chem. Eng.,3 (2022) 210-227.

Google Scholar

[8] L. Guo, K.J. Lamb, M. North: Green Chem. 23 (2021) 77-118.

Google Scholar

[9] W. Natongchai, S. Pornpraprom, V. D' Elia: Asian J. Org. Chem. 9 (2020) 801-810.

Google Scholar

[10] J. Meléndez, M. North, R. Pasquale: Eur. J. Inorg. Chem., 2007 (2007) 3323-3326.

Google Scholar

[11] J. Martínez, J. Fernández-Baeza, L.F. Sánchez-Barba, J.A. Castro-Osma, A. Lara-Sánchez, A. Otero: ChemSusChem 10 (2017) 2886-2890.

DOI: 10.1002/cssc.201700898

Google Scholar

[12] V. Aomchad, S. Del Gobbo, P. Yingcharoen, A. Poater, V. D'Elia: Catal. Today 375 (2021) 324-334.

DOI: 10.1016/j.cattod.2020.01.021

Google Scholar

[13] A.M. Hardman-Baldwin, A.E. Mattson: ChemSusChem 7 (2014) 3275-3278.

Google Scholar

[14] M. Debruyne, V. Van Speybroeck, P. Van Der Voort, C.V. Stevens: Green Chem. 23 (2021) 7361-7434.

DOI: 10.1039/d1gc02319e

Google Scholar

[15] S. Saengsaen, S. Del Gobbo, V. D'Elia: Chem. Eng. Res. Des. 191 (2023) 630-645.

Google Scholar

[16] J.C. Védrine: Chinese J. Catal. 40 (2019) 1627-1636.

Google Scholar

[17] H.P. Boehm Discuss. Faraday Soc. 52 (1971) 264-275.

Google Scholar

[18] F. Lagarde, H. Srour, N. Berthet, N. Oueslati, B. Bousquet, A. Nunes, A. Martinez, V. Dufaud: J. CO2 Util. 34 (2019) 34-39.

DOI: 10.1016/j.jcou.2019.05.023

Google Scholar

[19] J. Poolwong, S. Del Gobbo, V. D'Elia: J. Ind. Eng. Chem. 104 (2021) 43-60.

Google Scholar

[20] M. Tu, R.J. Davis: J. Catal. 199 (2001) 85-91.

Google Scholar

[21] S. Daumann, D. Andrzejewski, M. Di Marcantonio, U. Hagemann, S. Wepfer, F. Vollkommer, G. Bacher, M. Epple, E. Nannen: J. Mater. Chem. C 5 (2017) 2344-2351.

DOI: 10.1039/c6tc05571k

Google Scholar

[22] S. Del Gobbo, J. Poolwong, V. D'Elia: Cryst. Growth Des. 19 (2019) 6792-6800.

Google Scholar

[23] V. Gerbreders, M. Krasovska, E. Sledevskis, A. Gerbreders, I. Mihailova, E. Tamanis, A. Ogurcovs: CrystEngComm 22 (2020) 1346-1358.

DOI: 10.1039/c9ce01556f

Google Scholar

[24] Z. Wu, Y. Wang, Y. Zhang, W. Zhang, Q. Liu, Q. Liu, Q. Chen, Y. Li, J. Li, D. He: Org. Electron. 73 (2019) 7-12.

Google Scholar

[25] Y. Rui, H. Xiong, B. Su, H. Wang, Q. Zhang, J. Xu, P. Müller-Buschbaum: Electrochim. Acta 227 (2017) 49-60.

Google Scholar

[26] Y. Li, Y. Guo, R. Tan, P. Cui, Y. Li, W. Song: Mater. Lett. 63 (2009) 2085-2088.

Google Scholar

[27] O. Sodpiban, C. Phungpanya, S. Del Gobbo, S. Arayachukiat, T. Piromchart, V. D'Elia: Chem. Eng. J. 422 (2021) 129930.

DOI: 10.1016/j.cej.2021.129930

Google Scholar

[28] N. Vorobyeva, M. Rumyantseva, D. Filatova, E. Konstantinova, D. Grishina, A. Abakumov, S. Turner, A. Gaskov: Sens. Actuators B Chem. 182 (2013) 555-564.

DOI: 10.1016/j.snb.2013.03.068

Google Scholar

[29] X. Zhao, T. Wen, J. Zhang, J. Ye, Z. Ma, H. Yuan, X. Ye, Y. Wang: RSC Adv. 7 (2017) 21678-21685.

Google Scholar

[30] S.T. Gadge, A. Mishra, A.L. Gajengi, N.V. Shahi, B.M. Bhanage: RSC Adv. 4 (2014) 50271-50276.

DOI: 10.1039/c4ra07240e

Google Scholar

[31] S. Song, J. Wei, X. He, G. Yan, M. Jiao, W. Zeng, F. Dai, M. Shi: RSC Adv. 11 (2021) 35361-35374.

DOI: 10.1039/d1ra07060f

Google Scholar

[32] P. Bernard, P. Stelmachowski, P. Broś, W. Makowski, A. Kotarba: J. Chem. Educ. 98 (2021) 935-940.

DOI: 10.1021/acs.jchemed.0c01101

Google Scholar

[33] S. Arayachukiat, P. Yingcharoen, S.V.C. Vummaleti, L. Cavallo, A. Poater, V. D'Elia: Mol. Catal., 443 (2017) 280-285

DOI: 10.1016/j.mcat.2017.10.023

Google Scholar

[34] W. Deng, L. Zhang, L. Li, S. Chen, C. Hu, Z.-J. Zhao, T. Wang, J. Gong: J. Am. Chem. Soc. 141 (2019) 2911-2915.

Google Scholar

[35] J. Ma, S. Zuo-Jiang, Y. He, Q. Sun, Y. Wang, W. Liu, S. Sun, K. Chen: Royal Soc. Open Sci. 3 (2016) 160524.

Google Scholar

[36] H. Tamura, K. Mita, A. Tanaka, M. Ito: J. Colloid Interface Sci. 243 (2001) 202-207.

Google Scholar

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