Isotherm Adsorption Kinetics Study of Methylene Blue on Reduced Graphene Oxide from Borassus flabelifer L Fiber

Abstract:

Reduced graphene Oxide (RGO) was synthesized from treated Borassus Flabelifer L. The Isotherms adsorption kinetics of methylene blue on RGO was studied in this research. Borassus Flabelifer L as the raw material was heated at 650°C, 750°C, 850°C for 2 hours with the flowing of nitrogen gas. X-Ray Diffraction (XRD) used to clarify the RGO phase. The surface morphology was characterized by Scanning Electron Microscopy (SEM), meanwhile the absorbance of methylene blue on RGO studied by UV-Vis Spectrophotometry. The surface area of ​​RGO with 70.31 m²/gr; 110.90 m²/gr and 25.52 m²/gr when heated at 650°C, 750°C, and 850°C, respectively. The RGO phase was obtained through the XRD measurement at all activation temperatures. SEM and surface area measurement proved that the activation temperature of 750°C, was the optimum temperature where the RGO has more pores and a larger surface area. Based on the study of adsorption kinetics, the highest adsorption efficiency was obtained at 850°C.

• Periodical: Materials Science Forum (Volume 1108)
• Pages: 141-148
• DOI: https://doi.org/10.4028/p-GwFOr4
• Online since: December 2023
• Authors: Fandi Angga Prasetya*, Steven Dwi Bintang, Mukhammad Saifudin Maulana, Dian Pratiwi, Maulidsya Qalam Arba’a, Elita Fidiya Nugrahani, Yuni Kurniati, Ahmad Taufiq
• Keywords: Adsorption, Borassus flabelifer L, Fiber, Reduced Graphene Oxide

References

[1] Information on https://kemenperin.go.id/artikel/23435/Pulih-dari-Pandemi,-Utilisasi-Industri-TPT-Naik-Jadi-70-Persen

[2] K. Elsahida, A.M. Fauzi, I. Sailah, I.Z. Siregar, Sustainability of the use of natural dyes in the textile industry, IOP Conference Series: Earth and Environmental Science 399 012065

DOI: 10.1088/1755-1315/399/1/012065

[3] Bechtold, Thomas, A. Turcanu, Erika Ganglberger, and Susanne Geissler. "Natural dyes in modern textile dyehouses—how to combine experiences of two centuries to meet the demands of the future?." Journal of Cleaner Production 11, no. 5 (2003): 499-509.

DOI: 10.1016/s0959-6526(02)00077-x

[4] Bediako, John Kwame, Wei Wei, and Yeoung-Sang Yun. "Low-cost renewable adsorbent developed from waste textile fabric and its application to heavy metal adsorption." Journal of the Taiwan Institute of Chemical Engineers 63 (2016): 250-258.

DOI: 10.1016/j.jtice.2016.03.009

[5] Panigrahi, Tanmayee, and A. U. Santhoskumar. "Adsorption process for reducing heavy metals in Textile Industrial Effluent with low cost adsorbents." Prog. Chem. Biochem. Res 3, no. 2 (2020): 135-139.

DOI: 10.33945/sami/pcbr.2020.2.7

[6] Kurniati, Yuni, O. Putri Prastuti, and E. Lutfi Septiani. "Studi Kinetika Adsorpsi Metil Biru Menggunakan Karbon Aktif Limbah Kulit Pisang." J. Tek. Kim. Ling 3, no. 1 (2019): 34-38.

DOI: 10.33795/jtkl.v3i1.87

[7] Susmanto, Prahady, Yandriani Yandriani, Arin Putri Dila, and Dela Regina Pratiwi. "Pengolahan zat warna direk limbah cair industri jumputan menggunakan karbon aktif limbah tempurung kelapa pada kolom adsorpsi." JRST (Jurnal Riset Sains dan Teknologi) 4, no. 2 (2020): 77-87.

DOI: 10.30595/jrst.v4i2.7309

[8] Sastrawidana, I. Dewa Ketut. "Studi Efisiensi dan Isoterm Adsorpsi Remazol Black B Menggunakan Karbon dari Tempurung Kelapa yang Diaktivasi Secara Pirolisis." Wahana Matematika dan Sains: Jurnal Matematika, Sains, dan Pembelajarannya 16, no. 1 (2022): 1-11.

DOI: 10.33830/jmst.v10i2.581.2009

[9] Hasri, Hasri, Alimin Enre, and Sulfikar Sulfikar. "Adsorpsi Pewarna Tekstil Menggunakan Adsorben Kitosan Sulfat Bead Dari Limbah Kulit Udang." Scientific Pinisi 2, no. 1 (2016): 21-25.

[10] Sukmawati, Patria, and Budi Utami. "Adsorbsi Zat Pewarna Tekstil Malachite Green Menggunakan Adsorben Kulit Buah Kakao (Theobroma Cacao) Teraktivasi Hno3." In PROSIDING: Seminar Nasional Fisika dan Pendidikan Fisika, vol. 5, no. 1. 2014.

DOI: 10.21009/03.snf2017.02.mps.21

[11] Setiyanto, Setiyanto, Indah Riwayati, and Laeli Kurniasari. "Adsorpsi Pewarna Tekstil Rodhamin B Menggunakan Senyawa Xanthat Pulpa Kopi." Majalah Ilmiah MOMENTUM 11, no. 1 (2015).

[12] Aulia, S. D., A. Wijayanti, and R. Hadisoebroto. "The effect of mixing speed and contact time on dye removal using Cassava Peel adsorbents." In IOP Conference Series: Earth and Environmental Science, vol. 737, no. 1, p.012013. IOP Publishing, 2021.

DOI: 10.1088/1755-1315/737/1/012013

[13] Prasetya, Fandi Angga, Ufafa Anggarini, Salim Mustofa, Syarifatus Sholihah, Fathur Iqbal, Hanafi Hanafi, and Dode Bara Septyano. "Synthesis and Characterization of Reduced Graphene Oxide from Fiber of Borassus Flabelifer by Activation Method." Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat 16, no. 1 (2019): 17-22.

DOI: 10.20527/flux.v16i1.5876

[14] Prasetya, Fandi Angga, Ufafa Anggarini, Yudha Zakaria, and Rosa Dwi Sasqia Putri. "Synthesis and Characterization of Supercapacitor Electrode from Fiber of Borassus flabelifer L by Activation Method." In Materials Science Forum, vol. 966, pp.444-450. Trans Tech Publications Ltd, 2019.

DOI: 10.4028/www.scientific.net/msf.966.444

[15] Hidayah, N. M. S., Wei-Wen Liu, Chin-Wei Lai, N. Z. Noriman, Cheng-Seong Khe, U. Hashim, and H. Cheun Lee. "Comparison on graphite, graphene oxide and reduced graphene oxide: Synthesis and characterization." In AIP Conference Proceedings, vol. 1892, no. 1, p.150002. AIP Publishing LLC, 2017.

DOI: 10.1063/1.5005764