Paper Titles

Application of Green Synthesized Silver Nanoparticles for Dye Wastewater Treatment
p.27

Size-Dependent Surface Plasmon Resonance of Green Synthesized Gold Nanoparticles Using Mangifera indica Fruit Peel Extract
p.35

Synthesis and Characterization of Silver Vanadate and Graphitic Carbon Nitride Composites
p.41

Experimental and Modelling of Shape Memory Effect of Shape Memory Natural Rubber
p.49

Electrochemical Characterization of Battery-Supercapacitor Hybrid Based on Li₄Ti₅O₁₂and Ti₃C₂
p.55

The Modification of Thermal Conductivity of Phase Change Material Using Nano Metal-Oxide Particles
p.69

Cermet Powders Based on TiAl Intermetallic for Thermal Spraying
p.77

Structural and Mechanical Properties of SiC-Rich By-Products of the Metal Grade Si Process
p.87

Effect of Crystallization Properties of Continuous Basalt Fibers on Thermal Stability of Composite Materials
p.95

HomeMaterials Science ForumMaterials Science Forum Vol. 1113Electrochemical Characterization of...

Electrochemical Characterization of Battery-Supercapacitor Hybrid Based on Li₄Ti₅O₁₂and Ti₃C₂

Article Preview

Abstract:

Battery-supercapacitor hybrids (BSHs) are promising energy storage devices that exhibit large energy density, high power density. In this research, BSH devices based on Li₄Ti₅O₁₂ and Ti₃C₂ electrodes are fabricated. Through cyclic voltammetry, it is discovered that the kinetics of charging/discharging are diffusion-controlled. 3D Bode plots and Nyquist Plots indicate that bounded diffusion might occur. Regarding the performance, the 70 wt.% Li₄Ti₅O₁₂-Ti₃C₂ BSH shows the most balanced specific energy (9.9 mW∙h/kg) and specific power (3.0 W/kg) at 100 mV/s. The largest specific capacitance of the 70 wt.% Li₄Ti₅O₁₂-Ti₃C₂ BSH is 81.6 F/kg at 5 mV/s.

You might also be interested in these eBooks

5th International Conference on Advances in Materials, Mechanical and Manufacturing & 12th International Conference on Engineering and Innovative Materials

Synthesis, Properties, and Application of Advanced Nano and Functional Materials

Info:

Periodical:

Materials Science Forum (Volume 1113)

Pages:

55-68

DOI:

https://doi.org/10.4028/p-pYQI38

Citation:

Cite this paper

Online since:

February 2024

Authors:

Zi Yu He*

Keywords:

Battery Supercapacitor Hybrid, Cyclic Voltammetry, Electrochemical Impedance Spectroscopy

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Chad Abbey and Gza Joos. 2007. Supercapacitor Energy Storage for Wind Energy Applications. IEEE Transactions on Industry Applications 43, 3: 769–776

DOI: 10.1109/TIA.2007.895768

[2] N. Bonanos, B. C. H. Steele, and E. P. Butler. 2005. Applications of Impedance Spectroscopy. In Impedance Spectroscopy. 205–537

DOI: 10.1002/0471716243.ch4

[3] Jizhang Chen, Li Yang, Shaohua Fang, and Yufeng Tang. 2010. Synthesis of Sawtooth-like Li4Ti5O12 Nanosheets as Anode Materials for Li-ion Batteries. Electrochimica Acta 55, 22: 6596–6600

DOI: 10.1016/j.electacta.2010.06.015

[4] J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, and P. L. Taberna. 2006. Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer. Science 313, 5794: 1760–1763

DOI: 10.1126/science.1132195

[5] Pei Dong, Marco-Tulio F. Rodrigues, Jing Zhang, Raquel S. Borges, Kaushik Kalaga, Arava L.M. Reddy, Glaura G. Silva, Pulickel M. Ajayan, and Jun Lou. 2017. A Flexible Solar Cell/Supercapacitor Integrated Energy Device. Nano Energy 42: 181–186

DOI: 10.1016/j.nanoen.2017.10.035

[6] Johann M. Feckl, Ksenia Fominykh, Markus Döblinger, Dina Fattakhova-Rohlfing, and Thomas Bein. 2012. Nanoscale Porous Framework of Lithium Titanate for Ultrafast Lithium Insertion. Angewandte Chemie 124, 30: 7577–7581

DOI: 10.1002/ange.201201463

[7] Chao Feng and Xinming Wu. 2023. Interfacial Impedance Model and Ion Diffusion Mechanism of MXene/NiCo-LDHs Interstratification Hybrid Assembly Electrode. Journal of Colloid and Interface Science 635: 316–322

DOI: 10.1016/j.jcis.2022.12.143

[8] Simon Fleischmann, James B. Mitchell, Ruocun Wang, Cheng Zhan, De-en Jiang, Volker Presser, and Veronica Augustyn. 2020. Pseudocapacitance: From Fundamental Understanding to High Power Energy Storage Materials. Chemical Reviews 120, 14: 6738–6782

DOI: 10.1021/acs.chemrev.0c00170

[9] Atsushi Funabiki, Minoru Inaba, Zempachi Ogumi, Shin‐ichi Yuasa, Junhiko Otsuji, and Akimasa Tasaka. 1998. Impedance Study on the Electrochemical Lithium Intercalation into Natural Graphite Powder. Journal of The Electrochemical Society 145, 1: 172–178

DOI: 10.1149/1.1838231

[10] Miran Gaberšček. 2021. Understanding Li-based Battery Materials via Electrochemical Impedance Spectroscopy. Nature Communications 12, 1: 6513

DOI: 10.1038/s41467-021-26894-5

[11] Adnan Harb. 2011. Energy Harvesting: State-of-the-art. Renewable Energy 36, 10: 2641–2654

DOI: 10.1016/j.renene.2010.06.014

[12] James L. Hart, Kanit Hantanasirisakul, Andrew C. Lang, Babak Anasori, David Pinto, Yevheniy Pivak, J. Tijn van Omme, Steven J. May, Yury Gogotsi, and Mitra L. Taheri. 2019. Control of MXenes' Electronic Properties through Termination and Intercalation. Nature Communications 10, 1: 522

DOI: 10.1038/s41467-018-08169-8

[13] Minmin Hu, Hui Zhang, Tao Hu, Bingbing Fan, Xiaohui Wang, and Zhenjiang Li. 2020. Emerging 2D MXenes for Supercapacitors: Status, Challenges and Prospects. Chemical Society Reviews 49, 18: 6666–6693

DOI: 10.1039/D0CS00175A

[14] Jun Huang. 2018. Diffusion Impedance of Electroactive Materials, Electrolytic Solutions and Porous Electrodes: Warburg Impedance and Beyond. Electrochimica Acta 281: 170–188

DOI: 10.1016/j.electacta.2018.05.136

[15] Meng Huang, Ming Li, Chaojiang Niu, Qi Li, and Liqiang Mai. 2019. Recent Advances in Rational Electrode Designs for High-Performance Alkaline Rechargeable Batteries. Advanced Functional Materials 29, 11: 1807847

DOI: 10.1002/adfm.201807847

[16] Zi-Hang Huang, Yu Song, Xin-Xin Xu, and Xiao-Xia Liu. 2015. Ordered Polypyrrole Nanowire Arrays Grown on a Carbon Cloth Substrate for a High-Performance Pseudocapacitor Electrode. ACS Applied Materials & Interfaces 7, 45: 25506–25513

DOI: 10.1021/acsami.5b08830

[17] Torben Jacobsen and Keld West. 1995. Diffusion Impedance in Planar, Cylindrical and Spherical Symmetry. Electrochimica Acta 40, 2: 255–262

DOI: 10.1016/0013-4686(94)E0192-3

[18] Wenlong Jing, Chean Hung Lai, Shung Hui Wallace Wong, and Mou Ling Dennis Wong. 2017. Battery‐supercapacitor Hybrid Energy Storage System in Standalone DC Microgrids: a Review. IET Renewable Power Generation 11, 4: 461–469

DOI: 10.1049/iet-rpg.2016.0500

[19] Denis Johnson, Kyle Hansen, Ray Yoo, and Abdoulaye Djire. 2022. Elucidating the Charge Storage Mechanism on Ti3C2 MXene through In Situ Raman Spectroelectrochemistry. ChemElectroChem 9, 18

DOI: 10.1002/celc.202200555

[20] Jesse S. Ko, Megan B. Sassin, Debra R. Rolison, and Jeffrey W. Long. 2018. Deconvolving Double-layer, Pseudocapacitance, and Battery-like Charge-storage Mechanisms in Nanoscale LiMn2O4 at 3D Carbon Architectures. Electrochimica Acta 275: 225–235

DOI: 10.1016/j.electacta.2018.04.149

[21] Narendra Kurra, Simge Uzun, Geetha Valurouthu, and Yury Gogotsi. 2021. Mapping (Pseudo)Capacitive Charge Storage Dynamics in Titanium Carbide MXene Electrodes in Aqueous Electrolytes Using 3D Bode Analysis. Energy Storage Materials 39: 347–353

DOI: 10.1016/j.ensm.2021.04.037

[22] Jakub Lach, Kamil Wróbel, Justyna Wróbel, Piotr Podsadni, and Andrzej Czerwiński. 2019. Applications of Carbon in Lead-acid Batteries: a Review. Journal of Solid State Electrochemistry 23, 3: 693–705

DOI: 10.1007/s10008-018-04174-5

[23] Min-Joon Lee, Sanghan Lee, Pilgun Oh, Youngsik Kim, and Jaephil Cho. 2014. High Performance LiMn2O4 Cathode Materials Grown with Epitaxial Layered Nanostructure for Li-Ion Batteries. Nano Letters 14, 2: 993–999

DOI: 10.1021/nl404430e

[24] Shuo Li, Qi Shi, Yang Li, Jie Yang, Ting‐Hsiang Chang, Jianwen Jiang, and Po‐Yen Chen. 2020. Intercalation of Metal Ions into Ti3C2Tx MXene Electrodes for High‐Areal‐Capacitance Microsupercapacitors with Neutral Multivalent Electrolytes. Advanced Functional Materials 30, 40: 2003721

DOI: 10.1002/adfm.202003721

[25] Yu-Sheng Lin and Jenq-Gong Duh. 2011. Facile Synthesis of Mesoporous Lithium Titanate Spheres for High Rate Lithium-ion Batteries. Journal of Power Sources 196, 24: 10698–10703

DOI: 10.1016/j.jpowsour.2011.09.007

[26] Zheng Ling, Chang E. Ren, Meng-Qiang Zhao, Jian Yang, James M. Giammarco, Jieshan Qiu, Michel W. Barsoum, and Yury Gogotsi. 2014. Flexible and Conductive MXene Films and Nanocomposites with High Capacitance. Proceedings of the National Academy of Sciences 111, 47: 16676–16681

DOI: 10.1073/pnas.1414215111

[27] Zhiyong Liu, Yan Zhong, Bo Sun, Xingyue Liu, Jinghui Han, Tielin Shi, Zirong Tang, and Guanglan Liao. 2017. Novel Integration of Perovskite Solar Cell and Supercapacitor Based on Carbon Electrode for Hybridizing Energy Conversion and Storage. ACS Applied Materials & Interfaces 9, 27: 22361–22368

DOI: 10.1021/acsami.7b01471

[28] Maria R. Lukatskaya, Olha Mashtalir, Chang E. Ren, Yohan Dall'Agnese, Patrick Rozier, Pierre Louis Taberna, Michael Naguib, Patrice Simon, Michel W. Barsoum, and Yury Gogotsi. 2013. Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide. Science 341, 6153: 1502–1505

DOI: 10.1126/science.1241488

[29] Arumugam Manthiram. 2020. A Reflection on Lithium-ion Battery Cathode Chemistry. Nature Communications 11, 1: 1550

DOI: 10.1038/s41467-020-15355-0

[30] Ming-Shun Lu, Chung-Liang Chang, Wei-Jen Lee, and Li Wang. 2009. Combining the Wind Power Generation System With Energy Storage Equipment. IEEE Transactions on Industry Applications 45, 6: 2109–2115

DOI: 10.1109/TIA.2009.2031937

[31] Nourhan Mohamed and Nageh K. Allam. 2020. Recent advances in the design of cathode materials for Li-ion batteries. RSC Advances 10, 37: 21662–21685

DOI: 10.1039/D0RA03314F

[32] Guillaume A. Muller, John B. Cook, Hyung-Seok Kim, Sarah H. Tolbert, and Bruce Dunn. 2015. High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide Nanocrystals. Nano Letters 15, 3: 1911–1917

DOI: 10.1021/nl504764m

[33] V.S. Muralidharan. 1997. Warburg impedance ‐ Basics Revisited. Anti-Corrosion Methods and Materials 44, 1: 26–29

DOI: 10.1108/00035599710157387

[34] E. O Ogunniyi and HCvZ Pienaar. 2017. Overview of Battery Energy Storage System Advancement for Renewable (Photovoltaic) Energy Applications. In 2017 International Conference on the Domestic Use of Energy (DUE), 233–239

DOI: 10.23919/DUE.2017.7931849

[35] Tsutomu Ohzuku, Atsushi Ueda, and Norihiro Yamamoto. 1995. Zero‐Strain Insertion Material of Li [ Li1/3Ti5/3]O4 for Rechargeable Lithium Cells. Journal of The Electrochemical Society 142, 5: 1431–1435

DOI: 10.1149/1.2048592

[36] Xiang Sun, Gongkai Wang, Jiann-Yang Hwang, and Jie Lian. 2011. Porous Nickel Oxide Nano-sheets for High Performance Pseudocapacitance Materials. Journal of Materials Chemistry 21, 41: 16581

DOI: 10.1039/c1jm12734a

[37] Faxing Wang, Xiongwei Wu, Xinhai Yuan, Zaichun Liu, Yi Zhang, Lijun Fu, Yusong Zhu, Qingming Zhou, Yuping Wu, and Wei Huang. 2017. Latest Advances in Supercapacitors: from New Electrode Materials to Novel Device Designs. Chemical Society Reviews 46, 22: 6816–6854

DOI: 10.1039/C7CS00205J

[38] John Wang, Julien Polleux, James Lim, and Bruce Dunn. 2007. Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO 2 (Anatase) Nanoparticles. The Journal of Physical Chemistry C 111, 40: 14925–14931

DOI: 10.1021/jp074464w

[39] Martin Winter and Ralph J. Brodd. 2004. What Are Batteries, Fuel Cells, and Supercapacitors? Chemical Reviews 104, 10: 4245–4270

DOI: 10.1021/cr020730k

[40] Jijian Xu. 2022. Critical Review on cathode–electrolyte Interphase Toward High-Voltage Cathodes for Li-Ion Batteries. Nano-Micro Letters 14, 1: 166

DOI: 10.1007/s40820-022-00917-2

[41] Ting-Feng Yi, J. Shu, Ying Wang, Jing Xue, Jun Meng, Cai-Bo Yue, and Rong-Sun Zhu. 2011. Effect of Treated Temperature on Structure and Performance of LiCoO2 Coated by Li4Ti5O12. Surface and Coatings Technology 205, 13–14: 3885–3889

DOI: 10.1016/j.surfcoat.2011.02.003

[42] Fan Zhang, Tengfei Zhang, Xi Yang, Long Zhang, Kai Leng, Yi Huang, and Yongsheng Chen. 2013. A High-Performance Supercapacitor-battery Hybrid Energy Storage Device Based on Graphene-enhanced Electrode Materials with Ultrahigh Energy Density. Energy & Environmental Science 6, 5: 1623

DOI: 10.1039/c3ee40509e

[43] Bote Zhao, Ran Ran, Meilin Liu, and Zongping Shao. 2015. A Comprehensive Review of Li4Ti5O12-based Electrodes for Lithium-ion Batteries: The Latest Advancements and Future Perspectives. Materials Science and Engineering: R: Reports 98: 1–71

DOI: 10.1016/j.mser.2015.10.001

[44] Jingyuan Zhao and Andrew F. Burke. 2021. Review on Supercapacitors: Technologies and Performance Evaluation. Journal of Energy Chemistry 59: 276–291

DOI: 10.1016/j.jechem.2020.11.013

[45] Wenhua Zuo, Ruizhi Li, Cheng Zhou, Yuanyuan Li, Jianlong Xia, and Jinping Liu. 2017. Battery-Supercapacitor Hybrid Devices: Recent Progress and Future Prospects. Advanced Science 4, 7: 1600539

DOI: 10.1002/advs.201600539

[46] Wenhua Zuo, Chong Wang, Yuanyuan Li, and Jinping Liu. 2015. Directly Grown Nanostructured Electrodes for High Volumetric Energy Density Binder-Free Hybrid Supercapacitors: A Case Study of CNTs//Li4Ti5O12. Scientific Reports 5, 1: 7780

DOI: 10.1038/srep07780