Influence of Silicon Carbide Incorporation on Thermal and Ablation Properties of Carbon Fabric-Phenolic Resin Composites

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Abstract:

To shield re-entry spacecraft from the extreme heat experienced during hypersonic flight through a planet's or the earth's atmosphere, thermal protection systems (TPS) were developed. This work involved the fabrication of composites using a polyacrylonitrile (PAN) based carbon fabric (Cf)-phenolic resin matrix (PR) modified with different weight percentages (wt.%) of silicon carbide (SiC), namely 0 wt.% (Cf/PR), 1wt.%, 3wt.%, and 5wt.%. The composites were prepared using the hydraulic hot press method. The manufactured composites were analyzed for their thermal conductivity and resistance to ablation using an oxyacetylene torch test. Furthermore, the ablated composites underwent X-ray diffraction (XRD), revealing a SiO2 compound layer on the ablated composite surface. The experimental results demonstrated that the Cf/PR composites modified with 3wt.% of SiC exhibited superior characteristics. The composites consist of 3wt.% Cf/PR-SiC exhibited a thermal conductivity value of 0.57 W/m K. Additionally, these composites showed a noticeable decrease in the mass ablation rate (MAR) at 0.0052 mm/sec and linear ablation rates (LAR) at 0.025061 gm/sec. This study proposed an effective way to improve the thermal and ablation characteristics of TPS materials.

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Materials Science Forum (Volume 1128)

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9-14

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October 2024

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Hou et al., "A novel ablative material for thermal protection system: Carbon fiber/polysiloxane composites," Aerosp. Sci. Technol., vol. 129, p.107822, 2022.

DOI: 10.1016/j.ast.2022.107822

Google Scholar

[2] N. D. Yılmaz and G. M. Arifuzzaman Khan, "Flexural behavior of textile-reinforced polymer composites," Mech. Phys. Test. Biocomposites, Fibre-Reinforced Compos. Hybrid Compos., p.13–42, 2019.

DOI: 10.1016/b978-0-08-102292-4.00002-3

Google Scholar

[3] S. Wang, H. Huang, Y. Tian, and J. Huang, "Effects of SiC content on mechanical, thermal and ablative properties of carbon/phenolic composites," Ceram. Int., vol. 46, no. 10, p.16151–16156, 2020.

DOI: 10.1016/j.ceramint.2020.03.170

Google Scholar

[4] L. Duan, X. Zhao, and Y. Wang, "Oxidation and ablation behaviors of carbon fiber/phenolic resin composites modified with borosilicate glass and polycarbosilane interface," J. Alloys Compd., vol. 827, 2020.

DOI: 10.1016/j.jallcom.2020.154277

Google Scholar

[5] B. S. Raju, L. H. Manjunatha, Santosh, and N. Jagadeeswaran, "Fabrication & characterization of ZnS micro particulate filled glass and jute fibre reinforced hybrid polymer composites," Mater. Today Proc., no. xxxx, 2019.

DOI: 10.1016/j.matpr.2019.10.061

Google Scholar

[6] G. Feng et al., "Ablation behavior of ZrC and ZrO2 coatings on SiC coated C/C composites under oxyacetylene torch with different heat fluxes," Ceram. Int., vol. 47, no. 15, p.21721–21729, 2021.

DOI: 10.1016/j.ceramint.2021.04.187

Google Scholar

[7] R. Yin, H. Cheng, C. Hong, and X. Zhang, "Synthesis and characterization of novel phenolic resin/silicone hybrid aerogel composites with enhanced thermal, mechanical and ablative properties," Compos. Part A Appl. Sci. Manuf., vol. 101, p.500–510, 2017.

DOI: 10.1016/j.compositesa.2017.07.012

Google Scholar

[8] I. Srikanth, N. Padmavathi, S. Kumar, P. Ghosal, A. Kumar, and C. Subrahmanyam, "Mechanical, thermal and ablative properties of zirconia, CNT modified carbon/phenolic composites," Compos. Sci. Technol., vol. 80, p.1–7, 2013.

DOI: 10.1016/j.compscitech.2013.03.005

Google Scholar

[9] J. Ding, T. Yang, Z. Huang, Y. Qin, and Y. Wang, "Thermal stability and ablation resistance, and ablation mechanism of carbon–phenolic composites with different zirconium silicide particle loadings," Compos. Part B Eng., vol. 154, no. July, p.313–320, 2018.

DOI: 10.1016/j.compositesb.2018.07.057

Google Scholar

[10] A. Daniel, I. Srikanth, and B. Kandasubramanian, "Effect of Boron Nitride Addition on Ablation Characteristics of Carbon Fiber Reinforced Resorcinol Formaldehyde Composites," Ind. Eng. Chem. Res., vol. 59, no. 43, p.19299–19311, 2020.

DOI: 10.1021/acs.iecr.0c03818

Google Scholar

[11] A. Harpale, S. Sawant, R. Kumar, D. Levin, and H. B. Chew, "Ablative thermal protection systems: Pyrolysis modeling by scale-bridging molecular dynamics," Carbon N. Y., vol. 130, p.315–324, 2018.

DOI: 10.1016/j.carbon.2017.12.099

Google Scholar