Degradation β-Carotene Model of Degummed Red Palm Oil (DRPO) by RSM-Optimizing Condition

Article Preview

Abstract:

Crude palm oil (CPO) is commonly utilised in processed food items, including cooking oil. Cooking oil is made by heating it at high temperatures and refining it with bleaching earth to remove the sap and brown-red hue. As a result, it can remove β-carotene from CPO, which is no longer physiologically beneficial for human metabolism. This study seeks to eliminate sap and contaminants in CPO by assessing optimal degumming operation model with response surface methodology (RSM) to gain degummed red palm oil (DRPO) at high retaining β-carotene content. The results show that the optimal factors are 70°C heating temperature and 0.4% (v/v) of phosphoric acid concentration, with a β-carotene value was 455.892 ppm. After the degumming process, the physicochemical properties of palm oil remained relatively constant. Group bonds were unchanged since the primary triglyceride component contains C-H and C=O group bonds. The predicted degradation β-carotene model was y = 451.94 - 53.8(X) - 10.99(Y) + 3.61(XY) - 17.23(X2) - 18.56(Y2) by lack of fit 3.47%, X is temperature range, and Y volume range. This quadratic model has function for further degummed reactor design, on range operation variable.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1140)

Pages:

133-144

Citation:

Online since:

December 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] BPS, Indonesian Oil Palm Statistics 2022, vol. 16. 2023. [Online]. Available: http://repositorio.unan.edu.ni/2986/1/5624.pdf%0Ahttp://fiskal.kemenkeu.go.id/ejournal%0Ahttp://dx.doi.org/10.1016/j.cirp.2016.06.001%0Ahttp://dx.doi.org/10.1016/j.powtec.2016.12.055%0Ahttps://doi.org/10.1016/j.ijfatigue.2019.02.006%0Ahttps://doi.org/10.1

Google Scholar

[2] A. W. Nur Sulihatimarsyila, H. L. N. Lau, K. M. Nabilah, and I. Nur Azreena, "Production of refined red palm-pressed fibre oil from physical refining pilot plant," Case Stud. Chem. Environ. Eng., vol. 2, p.100035, 2020.

DOI: 10.1016/j.cscee.2020.100035

Google Scholar

[3] M. L. Olivares-Tenorio et al., "Bioactive compounds in palm oil: A comprehensive review of recent advances in physicochemical characteristics, health-promoting properties and technologies for extraction, concentration, fractionation, encapsulation and functional food applications," J. Food Compos. Anal., vol. 132, p.106306, 2024.

DOI: 10.1016/j.jfca.2024.106306

Google Scholar

[4] R. W. Mwangi, J. M. Macharia, I. N. Wagara, and R. L. Bence, "The antioxidant potential of different edible and medicinal mushrooms," Biomedicine and Pharmacotherapy, vol. 147. Elsevier Masson s.r.l., Mar. 01, 2022.

DOI: 10.1016/j.biopha.2022.112621

Google Scholar

[5] S. Clark, "Beta carotene," xPharm Compr. Pharmacol. Ref., p.1–3, 2007.

DOI: 10.1016/B978-008055232-3.61302-9

Google Scholar

[6] S. Li et al., "Effect of solid-state fermentation with Lactobacillus casei on the nutritional value, isoflavones, phenolic acids and antioxidant activity of whole soybean flour," LWT - Food Sci. Technol., vol. 125, p.109264, 2020.

DOI: 10.1016/j.lwt.2020.109264

Google Scholar

[7] Y.B. Pramono, S.B.M. Abduh, J P. Hidayat, and C. Gunawan, Food Quality Defines Your Own Quality. Balikpapan: ITK PRESS, 2023.

Google Scholar

[8] J.P. Hidayat, A. Hariyadi, and F. Chosta, "Bentonite and RHA Adsorption Performance Against Characteristics Waste-Cooking Oil," J. Sains dan Teknol. Pangan, vol. 7, no. 6, p.5600–5614, 2022.

Google Scholar

[9] B. Jamoussi, C. Jablaoui, A. K. Hajri, R. Chakroun, B. Al-Mur, and K. Allaf, "Deodorization process of vegetal soybean oil using Thermomechanical Multi-Flash Autovaporization (MFA)," LWT, vol. 167, Sep. 2022.

DOI: 10.1016/j.lwt.2022.113823

Google Scholar

[10] L.M. Serrano-Bermúdez et al., "Kinetic models for degumming and bleaching of phospholipids from crude palm oil using citric acid and Super Flo B80® and Tonsil®," Food Bioprod. Process., vol. 129, p.75–83, 2021.

DOI: 10.1016/j.fbp.2021.07.005

Google Scholar

[11] M.S. Nidzam et al., "Influence of the degumming process parameters on the formation of glyceryl esters and 3-MCPDE in refined palm: optimization and palm oil quality analyses," MDPI, vol. 11, no. 124, 2022.

DOI: 10.3390/foods11010124

Google Scholar

[12] N. Monjotin, M. J. Amiot, J. Fleurentin, J. M. Morel, and S. Raynal, "Clinical Evidence of the Benefits of Phytonutrients in Human Healthcare," Nutrients, vol. 14, no. 9, p.1–54, 2022.

DOI: 10.3390/nu14091712

Google Scholar

[13] D.A. Arsanto, D.W. Pratama, S.D.S. Murti, S. Soraya, and Widya, "Penentuan tingkat efisiensi komposisi H3PO4 pada proses degumming dalam pembuatan pure plant oil dari crude palm oil off-grade," JIST, vol. 3, no. 7, p.877–889, 2022.

DOI: 10.36418/jist.v3i7.450

Google Scholar

[14] L. Ifa, L. Wiyani, N. Nurdjannah, A. M. T. Ghalib, S. Ramadhaniar, and H. S. Kusuma, "Analysis of bentonite performance on the quality of refined crude palm oil's color, free fatty acid and carotene: the effect of bentonite concentration and contact time," Heliyon, vol. 7, no. 6, p. e07230, 2021.

DOI: 10.1016/j.heliyon.2021.e07230

Google Scholar

[15] S. Suherman et al., "Response surface optimization of time and pressure for freeze-drying mango slices," Food Res., vol. 7, no. 1, p.182–195, 2023.

DOI: 10.26656/fr.2017.7(1).816

Google Scholar

[16] A. Zikri, Erlinawati, P.L. Sutini, M. Agus, and S. Fathona, "Biodiesel Production from Bintaro (Cerbera Manghas L) Seeds with Potassium Hydroxide as Catalyst," J. Phys. Conf. Ser., vol. 1500, no. 012084, 2020.

DOI: 10.1088/1742-6596/1500/1/012084

Google Scholar

[17] B. Mert and T.A. Vilgis, "Hydrocolloid coated oleosomes for development of oleogels," Food Hydrocoll., vol. 119, Oct. 2021.

DOI: 10.1016/j.foodhyd.2021.106832

Google Scholar

[18] W. J. Lee, C. P. Tan, R. Sulaiman, Y. Y. Hee, and G. H. Chong, "Storage stability and degradation kinetics of bioactive compounds in red palm oil microcapsules produced with solution-enhanced dispersion by supercritical carbon dioxide: A comparison with the spray-drying method," Food Chem., vol. 304, Jan. 2020.

DOI: 10.1016/j.foodchem.2019.125427

Google Scholar

[19] BSN, "SNI 7709:2019 Minyak Goreng Sawit," in Minyak goreng sawit, 2019, p.1–33.

DOI: 10.46559/tegi.v11i1.5758

Google Scholar

[20] S.G. Husein, A. Firmansyah, and F.F. Yusuf, "Analisis kemometrika spektrum fourier transformed infrared (FTIR) dari minyak nabati," J. Sains dan Teknol. Farm. Indones., vol. 9, no. 2, pp.45-55, 2020.

DOI: 10.58327/jstfi.v9i2.189

Google Scholar

[21] A.C. Kumoro, S. Mariana, T.H. Maurice, and J.P. Hidayat, "Pectin Derived from Hydrolysis of Ripe Kepok Kuning Banana Peel Powder Employing Crude Pectinases Produced by Aspergillus niger," Sains Malaysiana, vol. 51, no. 7, p.2047–2059, Jul. 2022.

DOI: 10.17576/jsm-2022-5107-09

Google Scholar

[22] S. Pitchaiah, D. Juchelková, R. Sathyamurthy, and A. E. Atabani, "Prediction and performance optimisation of a DI CI engine fuelled diesel–Bael biodiesel blends with DMC additive using RSM and ANN: Energy and exergy analysis," Energy Convers. Manag., vol. 292, p.117386, 2023.

DOI: 10.1016/j.enconman.2023.117386

Google Scholar

[23] P. Sharma and N. Sharma, "RSM approach to pre-treatment of lignocellulosic waste and a statistical methodology for optimizing bioethanol production," Waste Manag. Bull., vol. 2, p.49–66, 2023.

DOI: 10.1016/j.wmb.2023.12.004

Google Scholar

[24] J. P. Hidayat, A. A. Putri, S. Munfarida, and A. C. Kumoro, "Kinetic bio - reaction modelling durian seed fused Lactobacillus plantarum suspension by high - order embedded runge - kutta," Food Res., vol. 8, p.1–10, 2024.

DOI: 10.26656/fr.2017.8(S1).1

Google Scholar

[25] Y. Jin, S. S. Teh, W. H. Yap, H. L. N. Lau, and S. H. Mah, "In vivo retinoid metabolic and visual cycle pathways assessment of carotenoid-rich refined red palm-pressed mesocarp olein," J. Funct. Foods, vol. 116, p.106140, 2024.

DOI: 10.1016/j.jff.2024.106140

Google Scholar

[26] D. Nurfiqih, L. Hakim, and Muhammad, "Pengaruh suhu, persentase air, dan lama penyimpanan terhadap persentase kenaikan asam lemak bebas (ALB) pada crude palm oil (CPO)," J. Teknol. Kim. Unimal, vol. 10, no. 2, p.1–14, 2021.

DOI: 10.29103/jtku.v10i2.4955

Google Scholar

[27] D. M. Indriyani, Nurhasanah, and D. Herasari, "Optimization of lipase production from local bacteria isolate with palm oil inducer," J. Sci. Appl. Chem., vol. 24, no. 2, p.58–61, 2021.

DOI: 10.14710/jksa.24.2.58-61

Google Scholar

[28] D. Sumarna, S. H. Sumarlan, S. Wijaya, and N. Hidayat, "Processing of olein fraction red palm oil with minimal refining method and optimization of deodorization process," in ICTAFF, Atlantis Press, 2021, p.167–175.

DOI: 10.2991/absr.k.220102.026

Google Scholar

[29] N. M. Stark and L. M. Matuana, "Trends in sustainable biobased packaging materials: a mini review," Mater. Today Sustain., vol. 15, Nov. 2021.

DOI: 10.1016/j.mtsust.2021.100084

Google Scholar

[30] Y. B. Pramono, E. Harmayani, and T. Utami, "Kinetika pertumbuhab lactobacillus plantarum dan lactobacillus sp. pada media MRS cair," J. Teknol. dan Ind. Pangan, vol. 14, no. 1, p.46–50, 2003.

Google Scholar

[31] I. Nor Shafizah, R. Irmawati, H. Omar, M. Yahaya, and A. Alia Aina, "Removal of free fatty acid (FFA) in crude palm oil (CPO) using potassium oxide/dolomite as an adsorbent: Optimization by Taguchi method," Food Chem., vol. 373, Mar. 2022.

DOI: 10.1016/j.foodchem.2021.131668

Google Scholar

[32] S. B. Oey, H. J. van der Fels-Klerx, V. Fogliano, and S. P. J. van Leeuwen, "Effective physical refining for the mitigation of processing contaminants in palm oil at pilot scale," Food Res. Int., vol. 138, p.109748, 2020.

DOI: 10.1016/j.foodres.2020.109748

Google Scholar

[33] S. B. Oey, H. J. van der Fels-Klerx, V. Fogliano, and S. P. J. van Leeuwen, "Chemical refining methods effectively mitigate 2-MCPD esters, 3-MCPD esters, and glycidyl esters formation in refined vegetable oils," Food Res. Int., vol. 156, p.111137, 2022.

DOI: 10.1016/j.foodres.2022.111137

Google Scholar

[34] A. Kumoro and J. Hidayat, "Effect of soaking time in sodium metabisulfite solution on the physicochemical and functional properties of durian seed flour," in MATEC Web of Conferences, EDP Sciences, Mar. 2018, p.1–5.

DOI: 10.1051/matecconf/201815601028

Google Scholar

[35] J. P. Hidayat, S. Munfarida, and A. Hariyadi, "Modified ganyong (Canna edulis Kerr.) starch prospective as wheat flour alternative," Food Res., vol. 8, p.11–17, 2024.

DOI: 10.26656/fr.2017.8(S1).2

Google Scholar

[36] A. P. Mayalibit, Z. L. Sarungallo, and S. N. Paiki, "The effect of degumming process using citric acid on the quality of red fruit oil (Pandanus conoideus Lamk.)," Agritechnology, vol. 2, no. 1, p.23–31, May 2019.

DOI: 10.51310/agritechnology.v2i1.25

Google Scholar

[37] S.S. Teh and H.L.N. Lau, "Quality assessment of refined red palm-pressed mesocarp olein," Food Chem., vol. 340, p.127912, 2021.

DOI: 10.1016/j.foodchem.2020.127912

Google Scholar