Liquid Phase Exfoliation of MoS2 Nanosheets in Aqueous IPA

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In this work, the liquid phase exfoliation (LPE) method was investigated to produce a large quantity of 2D MoS2. The introduction of ultrasound into IPA and IPA/DI solutions containing MoS2 resulted in fragmentation and exfoliation of the MoS2. The determination of the layers of LPE-MoS2 was performed by optical microscopy, atomic force microscopy, non-resonant Raman spectroscopy and XRD. Flakes with few layers were detected by AFM and resonant Raman investigations.

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Materials Science Forum (Volume 1167)

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89-96

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November 2025

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© 2025 Trans Tech Publications Ltd. All Rights Reserved

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[1] E. P. Nguyen, B. J. Carey, T. Daeneke, J. Z. Ou, K. Latham, S. Zhuiykov and K. Kalantar-zadeh, Excitation dependent bidirectional electron transfer in phthalocyanine-functionalised MoS2 nanosheets, Chem. Mater. 27 (2014), 53-59.

DOI: 10.1039/c6nr04326g

Google Scholar

[2] H. S. Matte, A. Gomathi, A. K. Manna, D. J. Late, R. Datta, S. K. Pati and C. N. Rao, MoS2 and WS2 analogues of graphene, Angew. Chem. Int. Ed. Engl. 49 (2010), 4059-4062.

DOI: 10.1002/anie.201000009

Google Scholar

[3] M. Chhowalla, H. Shin, G. Eda et al., The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. Nature Chem. 5 (2013), 263–275.

DOI: 10.1038/nchem.1589

Google Scholar

[4] K. F. Mak, C. Lee, J. Hone, J. Shan and T. F. Heinz, Atomically thin MoS2: A new direct-gap semiconductor. Phys. Rev. Lett. 105 (2010), 136805.

DOI: 10.1103/physrevlett.105.136805

Google Scholar

[5] Y. Liu, N. Naiyan, W. Xing, P. Wan et al. Layer-by-layer thinning of MoS2 by plasma. ACS Nano 7 (2013), 4202–4209.

Google Scholar

[6] T. Onishi, Quantum chemistry in functional inorganic materials, Adv. Quantum Chem. 64 (2012), 31–81.

Google Scholar

[7] E. P. Nguyen, B. J. Carey, T. Daeneke, J. Z. Ou, K. Latham, S. Zhuiykov and K. Kalantar-zadeh, Investigation of Two-Solvent Grinding-Assisted Liquid Phase Exfoliation of Layered MoS2, Chem. Mater. 27 (2014), 53- 59.

DOI: 10.1021/cm502915f

Google Scholar

[8] L. Niu, J. N. Coleman, H. Zhang, H. Shin, M. Chhowalla and Z. Zheng, Production of Two-Dimensional Nanomaterials via Liquid-Based Direct Exfoliation, Small 12 (2016), 272-293.

DOI: 10.1002/smll.201502207

Google Scholar

[9] G. L. Frey, K. J. Reynolds, R. H. Friend, H. Cohen and Y. Feldman, Solution-processed anodes from layer-structure materials for high-efficiency polymer light-emitting diodes, J. Am. Chem. Soc. 125 (2003), 5998-6007.

DOI: 10.1021/ja020913o

Google Scholar

[10] R. C. Sinclair, J. L. Suter, P. V. Coveney, Micromechanical exfoliation of graphene on the atomistic scale, Phys. Chem. Chem. Phys. 21 (2019), 5716.

DOI: 10.1039/c8cp07796g

Google Scholar

[11] H. Li, J. Wu, Z. Yin, H. Zhang, Preparation and applications of mechanically exfoliated single-layer and multilayer MoS2 and WSe2 nanosheets, Acc. Chem. Res. 47 (2014), 1067.

DOI: 10.1021/ar4002312

Google Scholar

[12] V. Nicolosi, M. Chhowalla, M. G. Kanatzidis, M. S. Strano, J. N. Coleman, Liquid Exfoliation of Layered Materials, Science 340 (2013), 1226419.

DOI: 10.1126/science.1226419

Google Scholar

[13] S. Luo, S. Dong, C. Lu, C. Yu, Y. Ou, L. Luo, J. Sun and J. Sun, Rational and green synthesis of novel two-dimensional WS2/MoS2 heterojunction via direct exfoliation in ethanol-water targeting advanced visible-light-responsive photocatalytic performance, J. Colloid. Interface Sci. 513 (2018), 389-399.

DOI: 10.1016/j.jcis.2017.11.044

Google Scholar

[14] K. Manna, H. N. Huang, W. T. Li, Y. H. Ho and W. H. Chiang, Toward Understanding the Efficient Exfoliation of Layered Materials by Water-Assisted Cosolvent Liquid-Phase Exfoliation, Chem. Mater. 28 (2016), 7586-7593.

DOI: 10.1021/acs.chemmater.6b01203

Google Scholar

[15] J. Shen, Y. He, J. Wu, C. Gao, K. Keyshar, X. Zhang, Y. Yang, M. Ye, R. Vajtai, J. Lou and P. M. Ajayan, Liquid Phase Exfoliation of Two-Dimensional Materials by Directly Probing and Matching Surface Tension Components, Nano Lett. 15 (2015), 5449-5454.

DOI: 10.1021/acs.nanolett.5b01842

Google Scholar

[16] M. Wang, X. Xu, Y. Ge, P. Dong, R. Baines, P. M. Ajayan, M. Ye and J. Shen, Surface Tension Components Ratio: An Efficient Parameter for Direct Liquid Phase Exfoliation, ACS Appl. Mater. Interfaces 9 (2017), 9168-9175.

DOI: 10.1021/acsami.6b16578

Google Scholar

[17] H. Xu, B. W. Zeiger and K. S. Suslick, Sonochemical synthesis of nanomaterials, Chem. Soc. Rev. 42 (2013), 2555–2567.

DOI: 10.1039/c2cs35282f

Google Scholar

[18] K. Wang, J. Wang, J. Fan, M. Lotya, A. O'Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang and W. J. Blau, Ultrafast saturable absorption of two-dimensional MoS2 nanosheets, ACS Nano 7 (2013), 9260-9267.

DOI: 10.1021/nn403886t

Google Scholar

[19] W. Zhao, Z. Ghorannevis, K. K. Amara, J. R. Pang, M. Toh, X. Zhang, C. Kloc, P. H. Tan and G. Eda, Lattice dynamics in mono- and few-layer sheets of WS2 and WSe2, Nanoscale 5 (2013), 9677-9683.

DOI: 10.1039/c3nr03052k

Google Scholar

[20] H. Zeng, G. B. Liu, J. Dai, Y. Yan, B. Zhu, R. He, L. Xie, S. Xu, X. Chen, W. Yao and X. Cui, Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides, Sci. Rep. 3 (2013), 1608.

DOI: 10.1038/srep01608

Google Scholar

[21] G. Pagona, C. Bittencourt, R. Arenal and N. Tagmatarchis, Exfoliated semiconducting pure 2H-MoS2 and 2H-WS2 assisted by chlorosulfonic acid, Chem. Commun. 51 (2015), 12950-12953.

DOI: 10.1039/c5cc04689k

Google Scholar

[22] H. Li, Q. Zhang, C.C.R. Yap, B.K. Tay, T.H.T. Edwin, A. Olivier and D. Baillargeat, From Bulk to Monolayer MoS2: Evolution of Raman Scattering, Adv. Funct. Mater. 22 (2012) 1385.

DOI: 10.1002/adfm.201102111

Google Scholar

[23] B. J. Akeredolu, I. Ahemen, A.N. Amah, A.D. Onojah, J. Shakya, H. N. Gayathri and A. Ghosh, Improved liquid phase exfoliation technique for the fabrication of MoS2/graphene heterostructure-based photodetector, Heliyon 10 (2024), 24964.

DOI: 10.1016/j.heliyon.2024.e24964

Google Scholar

[24] P. Ni, M. Dieng, J. Vanel, I. Florea, F. Z. Bouanis, A. Yassar, Liquid Shear Exfoliation of MoS2: Preparation, Characterization, and NO2-Sensing Properties, Nanomat. 13 (2023), 2505.

DOI: 10.3390/nano13182502

Google Scholar

[25] S. Xu, D. Li, and P. Wu, One-pot, facile, and versatile synthesis of monolayer MoS2/WS2 quantum dots as bio imaging probes and efficient electro catalysts for hydrogen evolution reaction, Adv. Funct. Mater. 25 (2015), 1127–1136.

DOI: 10.1002/adfm.201403863

Google Scholar