Phase Field Model of Modification of Microstructure of Al-15Mg2Si- 4.5Si Composite by Addition of Sr during Semi-Solid Processing

Article Preview

Abstract:

Semi-solid processing over a cooling slope has emerged as an efficient technique for producing near-spherical grain structures in metallic composites. In this study, an Al-15Mg₂Si-4.5Si composite processed using this method exhibited globular Mg₂Si particles embedded within an α-Al matrix. The addition of 0.01% Sr further refined the microstructure by reducing the size of the Mg₂Si particles, acting as a grain-refining agent. To gain deeper insight into the effect of Sr addition on microstructure evolution during semi-solid processing, a two-dimensional phase field model is developed. Wherein, rather than modelling the nucleation of Sr-containing phases explicitly, the influence of Sr is realised by modifying the relevant phase field parameters. The simulations predicted key microstructural characteristics—including grain size, sphericity, area fraction and grain density of P-Mg₂Si —along with interfacial energy and mobility coefficients for both the base and Sr-modified composites. The phase field results show good agreement with experimental observations, validating the modelling approach. Keywords: Semi-solid, Magnesium silicide, Phase field, grain refinement

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1176)

Pages:

23-28

Citation:

Online since:

January 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P. Das, A. Maiti, Gravity cast in-situ Al-15Mg2Si-4.5Si composite and a process thereof, Patent no.: 403839, Application on no.: IN 201811015624 (2022).

Google Scholar

[2] P. Das, T. Ray, S. Sarkar, S. Das, Rheo Gravity die cast in-situ Al-15Mg2Si-4.5Si-0.01Sr-0.015B composite and an Automobile Brake disc cast thereof, Patent No 533358, Application on no.: IN 201911012127 (2024).

Google Scholar

[3] C. Li, Y.Y. Wu, H. Li, X.F. Liu, Morphological evolution and growth mechanism of primary Mg2Si phase in Al–Mg2Si alloys, Acta Mater. 59 (2011) 1058–1067.

DOI: 10.1016/j.actamat.2010.10.036

Google Scholar

[4] I. Mukherjee and P. Das, Phase field model of semi solid slurry generation and isothermal coarsening of novel Al-15Mg2Si-4.5Si composite, Metall. Mater. Trans. B 55B (2024) 3711-3735.

DOI: 10.1007/s11663-024-03212-0

Google Scholar

[5] J. Eiken, B. Bottger, and I. Steinbach, Multiphase-field approach for multicomponent alloys with extrapolation scheme for numerical application, Phys. Rev. E 73 (2006) 066122.

DOI: 10.1103/physreve.73.066122

Google Scholar

[6] B. Bottger, J. Eiken, and I. Steinbach: Acta Mater., 2006, vol. 54, p.2697–2704.

Google Scholar

[7] I. Steinbach: Modelling Simul. Mater. Sci. Eng., 2009, Vol. 17, p.073001 (1-31).

Google Scholar

[8] I. Mukherjee, P. Das, A novel atomistic approach of estimating interfacial free energy and growth kinetics of primary Mg2Si during semi solid slurry formation of the novel Al–15Mg2Si–4.5Si composite, Appl. Phys. A 130 (2024) 338.

DOI: 10.1007/s00339-024-07499-3

Google Scholar

[9] I. Mukherjee and P. Das, Microstructure evolution during solidification in a low superheat casting process of the Al-Mg2Si composites having excess Si: A phase field study, Materials Today Communications, 40 (2024) 109620.

DOI: 10.1016/j.mtcomm.2024.109620

Google Scholar

[10] C. Li, C. Wang, H. Ju, Xue-Na Xue, M. Zha, Hui-Yuan Wang, Prediction of modified morphology for primary Mg2Si induced by trace-element adsorption: A first-principles study, Materialia 14 (2020) 100875.

DOI: 10.1016/j.mtla.2020.100875

Google Scholar

[11] P Das, SK Samanta, B Mondal, P Dutta, Multiphase model of semisolid slurry generation and isothermal holding during cooling slope rheoprocessing of A356 Al alloy, Metallurgical and Materials Transactions B 49 (2018) 1925-1944.

DOI: 10.1007/s11663-018-1211-1

Google Scholar

[12] P. Das, Microstructure evolution during Rheoprocessing of A356 Al alloy using cooling slope, International Journal of Metalcasting, 17(3) (2023) 1982-2001.

DOI: 10.1007/s40962-022-00908-4

Google Scholar

[13] P. Das, P. Dutta, Three-dimensional phase field simulation of spheroidal grain formation during semi solid processing of Al–7Si–0.3Mg alloy. Comput. Mater. Sci. 184 (2020) 109856.

DOI: 10.1016/j.commatsci.2020.109856

Google Scholar

[14] Q.D. Qin, Y.G. Zhao, C. Liu, P.J. Cong, and W. Zhou, Strontium modification and formation of cubic primary Mg2Si crystals in Mg2Si/Al composite, J. Alloys Compd. 454 (2008) 142-146.

DOI: 10.1016/j.jallcom.2006.12.074

Google Scholar

[15] P. Das, M.A. Sultan, Effect of Strontium Addition on Semi-Solid Slurry Generation of Novel Al–15Mg2Si–4.5Si Composite During Cooling Slope Rheoprocessing, Trans Indian Inst Met (2024) 77(10) (2024) 2965–2970.

DOI: 10.1007/s12666-023-03183-x

Google Scholar

[16] 〈www.micress.rwth-aachen.de〉

Google Scholar

[17] 〈www.thermocalc.com〉

Google Scholar

[18] M.G. Mecozzi, M. Militzer, J. Sietsma, and S. Van Der Zwaag, The Role of Nucleation Behavior in Phase-Field Simulations of the Austenite to Ferrite Transformation, Metall. Mater. Trans. A 39 (2008) 1237–1247.

DOI: 10.1007/s11661-008-9517-2

Google Scholar

[19] I. Mukherjee and P. Das, Effect of fluid flow on microstructure evolution during Rheo Gravity die casting of Novel Al-15Mg2Si-4.5Si composite, Transactions of the Indian Institute of Metals, 77 (2024) 3051.

DOI: 10.1007/s12666-023-03217-4

Google Scholar