Numerical Approach to the Simulation of Vitrimer Matrix Composites Manufacturing by Infusion and Coating by Cold Spray

Abstract:

Aiming to minimize time, energy, and materials-consuming trial and error experimental analyses, a numerical modeling approach of vitrimer flow and cold spray deposition is proposed in this work. The characteristics of vitrimeric matrices were evaluated by elaborating data from previously performed differential scanning calorimetry and dynamic mechanical analysis. The pieces of information related to the transition temperatures and mechanical evolution after curing were exploited to feed the numerical models and to run sensitivity analyses. The flow model is based on prior evaluation of the dry reinforcement permeability at a micro- and meso-scale. The flow model has been implemented using a commercial simulative environment based on the control volumes approach. A single impacting particle was simulated in a finite element environment to analyze, in a focused way, the deposition mechanisms.The objective of this analysis is the integrated implementation of a numerical model for vitrimer flow through carbon fabric reinforcement in infusion processes and single particle deposition on vitrimer matrix composite substrates.

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[1] R. Hsissou, R. Seghiri, Z. Benzekri, M. Hilali, M. Rafik, and A. Elharfi, "Polymer composite materials: A comprehensive review," Apr. 15, 2021, Elsevier Ltd.

DOI: 10.1016/j.compstruct.2021.113640

Google Scholar

[2] P. De Sio, M. Gaito, V. Esperto, E. Cozzolino, A. Astarita, and F. Tucci, "Life Cycle Assessment of a Composite Prototype Battery Enclosure for Electric Vehicles," Sustainability (Switzerland), vol. 17, no. 4, Feb. 2025.

DOI: 10.3390/su17041579

Google Scholar

[3] H. L. Tekinalp et al., "Highly oriented carbon fiber-polymer composites via additive manufacturing," Compos. Sci. Technol., vol. 105, p.144–150, Dec. 2014.

DOI: 10.1016/j.compscitech.2014.10.009

Google Scholar

[4] M. Belhaj et al., "Dry fiber automated placement of carbon fibrous preforms," Compos. B Eng., vol. 50, p.107–111, Jul. 2013.

DOI: 10.1016/j.compositesb.2013.01.014

Google Scholar

[5] A. Gambardella, V. Esperto, F. Tucci, and P. Carlone, "Automated programming for the robotic layup process," in Materials Research Proceedings, Association of American Publishers, 2023, p.367–374.

DOI: 10.21741/9781644902479-40

Google Scholar

[6] V. Esperto, A. Gambardella, G. Pasquino, F. Tucci, M. Durante, and P. Carlone, "Modeling and simulation of the robotic layup of fibrous preforms for liquid composite molding," in ESAFORM 2021 - 24th International Conference on Material Forming, PoPuPS (University of LiFge Library), 2021.

DOI: 10.25518/esaform21.475

Google Scholar

[7] A. Gambardella, V. Esperto, F. Tucci, and P. Carlone, "Defects Reduction in the Robotic Layup Process," in Key Engineering Materials, Trans Tech Publications Ltd, 2022, p.1437–1444.

DOI: 10.4028/p-7v9349

Google Scholar

[8] W. Alabiso and S. Schlögl, "The impact of vitrimers on the industry of the future: Chemistry, properties and sustainable forward-looking applications," Aug. 01, 2020, MDPI AG.

DOI: 10.3390/POLYM12081660

Google Scholar

[9] A. Viscusi et al., "Metallization of Vitrimers by cold spray: A preliminary study," in Materials Research Proceedings, Association of American Publishers, 2024, p.183–191.

DOI: 10.21741/9781644903131-20

Google Scholar

[10] A. Perna et al., "Reprocessable vitrimeric composites metallized via cold spray: A preliminary study on the feasibility of novel hybrid structures," in Materials Research Proceedings, Association of American Publishers, 2024, p.2524–2533.

DOI: 10.21741/9781644903131-278

Google Scholar

[11] D. Helfritch, V. K. Champagne, and A. Papyrin, "The development of the cold spray process," in Advances in Cold Spray: a Coating Deposition and Additive Manufacturing Process, Elsevier, 2023, p.9–41.

DOI: 10.1016/B978-0-08-103015-8.00013-X

Google Scholar

[12] R. Della Gatta, A. S. Perna, A. Viscusi, G. Pasquino, and A. Astarita, "Cold spray deposition of metallic coatings on polymers: a review," Jan. 01, 2022, Springer.

DOI: 10.1007/s10853-021-06561-2

Google Scholar

[13] A. Ganesan, M. Yamada, and M. Fukumoto, "Cold spray coating deposition mechanism on the thermoplastic and thermosetting polymer substrates," in Journal of Thermal Spray Technology, Dec. 2013, p.1275–1282.

DOI: 10.1007/s11666-013-9984-x

Google Scholar

[14] A. S. Perna, A. Astarita, A. Martone, B. Palmieri, and A. Viscusi, "Investigating the Feasibility of Metallizing Reprocessable Vitrimeric Components through Cold Spray Technique," J. Mater. Eng. Perform., vol. 34, no. 8, p.6510–6526, Apr. 2025.

DOI: 10.1007/s11665-025-11108-6

Google Scholar

[15] R. Arbter et al., "Experimental determination of the permeability of textiles: A benchmark exercise," Compos. Part A Appl. Sci. Manuf., vol. 42, no. 9, p.1157–1168, 2011.

DOI: 10.1016/j.compositesa.2011.04.021

Google Scholar

[16] V. Esperto, L. Boccarusso, M. Durante, L. Carrino, and P. Carlone, "Permeability analysis of natural and artificial fiber textiles for liquid composite molding process," in Procedia Manufacturing, Elsevier B.V., 2020, p.435–439.

DOI: 10.1016/j.promfg.2020.04.328

Google Scholar

[17] F. Rubino and P. Carlone, "A semi-analytical model to predict infusion time and reinforcement thickness in VARTM and SCRIMP processes," Polymers (Basel)., vol. 11, no. 1, Jan. 2019.

DOI: 10.3390/polym11010020

Google Scholar

[18] V. Esperto, F. Tucci, and P. Carlone, "Impregnation and saturation analysis of microwave-preheated reactive resin in liquid composite molding," Polym. Compos., vol. 46, no. S1, pp. S159–S170, Sep. 2025.

DOI: 10.1002/pc.29772

Google Scholar

[19] B. Palmieri et al., "Feasibility of Infusion Processing for Carbon Fiber/Vitrimeric Epoxy Composites."

Google Scholar

[20] V. Esperto, C. Gallo, S. Lomov, J. Soete, and P. Carlone, "System Integration for Advanced Manufacturing of Composites by Microwave Preheated Resin Infusion: An Experimental Study," J. Mater. Eng. Perform., vol. 34, no. 10, p.8759–8767, May 2025.

DOI: 10.1007/s11665-024-10397-7

Google Scholar

[21] V. Esperto, M. Durante, P. Carlone, and L. Carrino, "Resin microwave preheating in liquid composite molding process," in AIP Conference Proceedings, American Institute of Physics Inc., Jul. 2019.

DOI: 10.1063/1.5112650

Google Scholar

[22] H. Che, P. Vo, and S. Yue, "Investigation of Cold Spray on Polymers by Single Particle Impact Experiments," Journal of Thermal Spray Technology, vol. 28, no. 1–2, p.135–143, Jan. 2019.

DOI: 10.1007/s11666-018-0801-4

Google Scholar

[23] A. Fardan, C. C. Berndt, and R. Ahmed, "Numerical modelling of particle impact and residual stresses in cold sprayed coatings: A review," Mar. 15, 2021, Elsevier B.V.

DOI: 10.1016/j.surfcoat.2021.126835

Google Scholar

[24] A. Viscusi, M. Bruno, L. Esposito, and G. Testa, "An experimental/numerical study of bonding mechanism in cold spray technology for metals".

Google Scholar

[25] H. Unal and A. Mimaroglu, "Friction and wear characteristics of PEEK and its composite under water lubrication," Journal of Reinforced Plastics and Composites, vol. 25, no. 16, p.1659–1667, Nov. 2006.

DOI: 10.1177/0731684406068406

Google Scholar

[26] F. Tucci, B. Palmieri, A. S. Perna, A. Viscusi, A. Martone, and A. Astarita, "Manufacturing of vitrimer matrix composite substrates for cold-spray coatings," in Materials Research Proceedings, Association of American Publishers, 2025, p.665–672.

DOI: 10.21741/9781644903735-78

Google Scholar

[27] Shubham, C. S. Yerramalli, C. Sumant, R. K. Prusty, and B. C. Ray, "Finite element modelling and experimentation of plain weave glass/epoxy composites under high strain-rate compression loading for estimation of Johnson-Cook model parameters," Int. J. Impact Eng., vol. 167, Sep. 2022.

DOI: 10.1016/j.ijimpeng.2022.104262

Google Scholar

[28] B. Yildirim, H. Fukanuma, T. Ando, A. Gouldstone, and S. Müftü, "A numerical investigation into cold spray bonding processes," J. Tribol., vol. 137, no. 1, Nov. 2014.

DOI: 10.1115/1.4028471

Google Scholar

[29] Q. Du, F. Liu, and Q. Lei, "Numerical Simulation of PMMA Impact Based on the J–C Constitutive and Damage Models under Hydrostatic Pressure Loading," Applied Sciences (Switzerland), vol. 13, no. 15, Aug. 2023.

DOI: 10.3390/app13158640

Google Scholar