Recent Advances in Incorporating Nanomaterials as Additives in Solid Electrolytes for Efficient Lithium–Battery

Article Preview

Abstract:

Solid polymer electrolytes are recently investigated as alternatives to enhance the efficiency of lithium-ion batteries because of their inherent advantages. However, ionic transport through solid polymer electrolytes and mechanical properties of the electrolyte tend to be poorer compared with the liquid organic salt electrolytes. Granted, nanobased materials have attracted increased interest due to their ability to improve the properties of the electrolytes of lithium-ion batteries. This review is intended to highlight recent advances in utilizing nanomaterials in improving the electrochemical and mechanical characteristics of the solid electrolyte to enhance the performance of lithium-ion batteries. The synthetic techniques employed, as well as limitations of nanomaterials, are summarized. Recommendations for further development of novel functional nanomaterials for lithium-ion batteries are presented. Insight from this research will guide researchers in lithium battery technologies to make informed decisions, specifically when using nanobased materials.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1189)

Pages:

141-149

Citation:

Online since:

May 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Xie, C. J. He, J. Zhang, Y. L. Hou, W. J. Meng, and D. L. Zhao, Nitrogen-doped carbon caging silicon nanoparticles for high-performance lithium-ion battery anodes, J. Alloys Compd. 860 (2021)158487.

DOI: 10.1016/j.jallcom.2020.158487

Google Scholar

[2] J. Yao, Y. Yang, Y. Li, J. Jiang, S. Xiao, and J. Yang, Interconnected α-Fe2O3 nanoparticles prepared from leaching liquor of tin ore tailings as anode materials for lithium-ion batteries, J. Alloys Compd. 855(2021)157288.

DOI: 10.1016/j.jallcom.2020.157288

Google Scholar

[3] H. Cheng, J. G. Shapter, Y. Li, and G. Gao, Recent progress of advanced anode materials of lithium-ion batteries, J. Energy Chem. 57 (2021)451–468.

DOI: 10.1016/j.jechem.2020.08.056

Google Scholar

[4] X. Ji, S. Hou, P. Wang, X. He, N. Piao, J. Chen, X. Fan, and C. Wang, Solid-State Electrolyte Design for Lithium Dendrite Suppression, Adv. Mater. 32 (2020)1–9.

DOI: 10.1002/adma.202002741

Google Scholar

[5] L. Shen, P. Shi, X. Hao, Q. Zhao, J. Ma, Y. He, and F. Kang, Progress on Lithium Dendrite Suppression Strategies from the Interior to Exterior by Hierarchical Structure Designs, Small. 16 (2020) 1–40.

DOI: 10.1002/smll.202000699

Google Scholar

[6] H. Qin, K. Fu, Y. Zhang, Y. Ye, M. Song, Y. Kuang, S. Jang, F. Jiang, L. Cui, Flexible nanocellulose enhanced Li+ conducting membrane for solid polymer electrolyte, Energy Storage Mater. 28(2020), 293–299

DOI: 10.1016/j.ensm.2020.03.019

Google Scholar

[7] T. C. Lourenco, M. Ebadi, D. Brandell, J. L. F. da Silva, and L. T. Costa, Interfacial structures in ionic liquid-based ternary electrolytes for lithium-metal batteries: A molecular dynamics study, J. Phys. Chem. B, 124 (2020) 9648–9657

DOI: 10.1021/acs.jpcb.0c06500

Google Scholar

[8] D. Cao, X. Sun, Q. Li, A. Natan, P. Xiang, and H. Zhu, Lithium Dendrite in All-Solid-State Batteries: Growth Mechanisms, Suppression Strategies, and Characterizations, Matter, 3(2020) 57–94.

DOI: 10.1016/j.matt.2020.03.015

Google Scholar

[9] S. Li , W. Ren, Y. Huang, Q. Zhou, C. Luo, Z. Li X. Li, M. Wang, H. Cao, Building more secure LMBs with gel polymer electrolytes based on dual matrices of PAN and HPMC by improving compatibility with anode and tuning lithium ion transference, Electrochim. Acta, 391(2021)138950

DOI: 10.1016/j.electacta.2021.138950

Google Scholar

[10] M. Fischer, A. Heuer, and D. Diddens, Structure and Transport Properties of Poly(ethylene oxide)-Based Cross-Linked Polymer Electrolytes Molecular Dynamics Simulations Study, Macromolecules,55(2022) 10229–10242.

DOI: 10.1021/acs.macromol.2c01795

Google Scholar

[11] S. K. Sharma, G. Sharma, A. Gaur, and A. Arya, EProgress in electrode and electrolyte materials : path to all-solid-state Li-ion batteries, Energy Adv.1 (2022) 457–510.

DOI: 10.1039/d2ya00043a

Google Scholar

[12] Y. W. Chen, H. Huang, Y. Wang, Z. Shen, L. Li, Y. Wang, X. Wang, X. Li, In Situ Polymerized Polydopamine Nanoparticles as Enhanced Polymer Composite Electrolyte for All-Solid-State Lithium-Ion Batteries, ChemElectroChem. 9(2022)202101277.

DOI: 10.1002/celc.202101277

Google Scholar

[13] Y. Guo, J. Bae, Z. Fang, P. Li, F. Zhao, and G. Yu, Hydrogels and Hydrogel-Derived Materials for Energy and Water Sustainability, Chem. Rev. 120(2020) 7642–7707.

DOI: 10.1021/acs.chemrev.0c00345

Google Scholar

[14] L. Cao, D. Tian, B. Lin, W. Wang, L. Bai, H. Chen, L. Yang, H. Yang, D. Wei, Fabrication of self-healing nanocomposite hydrogels with the cellulose nanocrystals-based Janus hybrid nanomaterials," Int. J. Biol. Macromol. 184 (2021)259–270.

DOI: 10.1016/j.ijbiomac.2021.06.053

Google Scholar

[15] M. Zhu, F. Zhu, and O. G. Schmidt, Nano energy for miniaturized systems, Nano Mater. Sci., 3 (2021)107–112.

Google Scholar

[16] J. T Landry, The Next Big Thing Is Really Small: How Nanotechnology Will Change the Future of Your business, Harv. Bus. Rev. 81 (2003)24.

Google Scholar

[17] A. M. Youssef, M. S. Hasanin, M. E. A. El-Aziz, and G. M. Turky, Conducting chitosan/hydroxylethyl cellulose/polyaniline bionanocomposites hydrogel based on graphene oxide doped with Ag-NPs, Int. J. Biol. Macromol. 167 (2021)1435–1444

DOI: 10.1016/j.ijbiomac.2020.11.097

Google Scholar

[18] F. Ye, K. Liao, R. Ran, and Z. Shao, Recent Advances in Filler Engineering of Polymer Electrolytes for Solid-State Li-Ion Batteries: A Review, Energy and Fuels, 34(2020) 9189–9207.

DOI: 10.1021/acs.energyfuels.0c02111

Google Scholar

[19] L. Liu, J. Lyu, J. Mo, H. Yan, L. Xu, P. Peng, J. Li, B. Jiang, L. Chu, M. Li, Comprehensively-upgraded polymer electrolytes by multifunctional aramid nanofibers for stable all-solid-state Li-ion batteries, Nano Energy, 69(2020)104398.

DOI: 10.1016/j.nanoen.2019.104398

Google Scholar

[20] Paras, K. Yadav, P. Kumar, D. R.Teja, S. Chakraborty, M. Chakraborty, S. Sanjeeb, Mohapatra, A. Sahoo, M. M. C. Chou, C. Liang and D. Hang, A Review on Low-Dimensional Nanomaterials: Nanofabrication, Characterization and Applications, Nanomaterials.13(2023)1–44

DOI: 10.3390/nano13010160

Google Scholar

[21] F. Liu, X. Zhang, X. Zhang, L. Wang, M. Liu, and J. Zhang, Dual-template Strategy for Electrocatalyst of Cobalt Nanoparticles Encapsulated in Nitrogen-doped Carbon Nanotubes for Oxygen Dual-template Strategy for Electrocatalyst of Cobalt Nanoparticles Encapsulated in Nitrogen-doped Carbon Nanotubes for Oxygen, J. Colloid Interface Sci.,581 (2020) 523-532

DOI: 10.1016/j.jcis.2020.07.008

Google Scholar

[22] J. Xiang, P. Zhang, S. Lv, Y. Ma, Qi. Zhao, Y. Sui, Y. Ye C. Qin, Spinel LiMn2O4 nanoparticles fabricated by the flexible soft template/Pichini method as cathode materials for aqueous lithium-ion capacitors with high energy and power density, RSC Adv,11(2021) 14891–14898

DOI: 10.1039/d0ra07823a

Google Scholar

[23] Y. Kang, Y. Guo, J. Zhao, B. Jiang, J. Guo, Y. Tang, H. Li, V. Malgras, M. A. Amin, H. Nara, Y. Sugahara, Y. Yamauchi, and T. Asahi, Soft Template-Based Synthesis of Mesoporous Phosphorus- and Boron-Codoped NiFe-Based Alloys for Efficient Oxygen Evolution Reaction, Small. 18(2022)2203411

DOI: 10.1002/smll.202203411

Google Scholar

[24] S. Ding, W. Cheng, L. Zhang, G. Du, X. Hao, G. Nie, B. Xu, M. Zhang, Q. Su, C. A. Serra, Organic molecule confinement reaction for preparation of the Sn nanoparticles@graphene anode materials in Lithium-ion battery, J. Colloid Interface Sci. 589(2021)308–317

DOI: 10.1016/j.jcis.2020.12.086

Google Scholar

[25] Z. Lei , J. Shen, J. Wang, Q. Qiu, G. Zhang, S. Chi, H. Xu, S. Li, W. Zhang, Y. Zhao , Y. Den, C. Wang, Composite polymer electrolytes with uniform distribution of ionic liquid-grafted ZIF-90 nanofillers for high-performance solid-state Li batteries, Chem. Eng. J. 412(2020)128733.

DOI: 10.1016/j.cej.2021.128733

Google Scholar

[26] Z. Zhang, Y. Huang, H. Gao, J. Hang, C. Li, and P. Liu, MOF-derived ionic conductor enhancing polymer electrolytes with superior electrochemical performances for all solid lithium metal batteries, J. Memb. Sci.,598(2020) 117800.

DOI: 10.1016/j.memsci.2019.117800

Google Scholar

[27] A. E. Abdelmaoula, L. Du, L. Xu, Y. Cheng, A. A. Mahdy, and M. Tahir, Biomimetic brain-like nanostructures for solid polymer electrolytes with fast ion transport,Sci China Mater. 65(2022) 1476–1484.

DOI: 10.1007/s40843-021-1940-2

Google Scholar

[28] Z. Lei et al., "Exploring porous ( zeolitic imidazolate frame work-8 ) ZIF-8 as an efficient filler for high-performance poly ( ethyleneoxide ) -based solid polymer electrolytes," 12(2020)

DOI: 10.1007/s12274-020-2845-2

Google Scholar

[29] Y. X. Gan, A. H. Jayatissa, Z. Yu, X. Chen, and M. Li, Hydrothermal Synthesis of Nanomaterials. J. of Nanomaterials. 2020 (2020) 8917013

Google Scholar

[30] F. Liu, Y. Cheng, J. Tan, J. Li, H. Cheng, H. Hu , C. Du, S. Zhao, Y. Yan and M. Liu, Carbon Nanomaterials With Hollow Structures: A Mini-Review, Front. Chem. 9,(2021) 1–7.

DOI: 10.3389/fchem.2021.668336

Google Scholar

[31] T. Gupta, J. Cho, and J. Prakash, Hydrothermal synthesis of TiO 2 nanorods: formation chemistry , growth mechanism , and tailoring of surface properties for photocatalytic activities, Mater. Today Chem. 20, (2021)100428.

DOI: 10.1016/j.mtchem.2021.100428

Google Scholar

[32] Z. Lu, D. Xuan,D. Wang, J. Liu, Z. Wang, Q. Liu, D. Wang,Y. Ye,Z. Zheng, and S. Li, Reagent-assisted hydrothermal synthesis of NiCo2O4nanomaterials as electrodes for high-performance asymmetric supercapacitors, New J. Chem. 45(2021)9230–9242

DOI: 10.1039/d1nj00268f

Google Scholar

[33] S. Mohan, M. Vellakkat, A. Aravind, and U. Reka, Hydrothermal synthesis and characterization of Zinc Oxide nanoparticles of various shapes under different reaction conditions, Nano Express, 1(2020) 030028

DOI: 10.1088/2632-959x/abc813

Google Scholar

[34] M. S. Lal, R. Badam, N. Matsumi, and S. Ramaprabhu, Hydrothermal synthesis of single-walled carbon nanotubes/TiO2 for quasi-solid-state composite-type symmetric hybrid supercapacitors, J. Energy Storage. 40(2021) 102794.

DOI: 10.1016/j.est.2021.102794

Google Scholar

[35] O. C. Pore, A. V. Fulari, R. V. Shejwal, V. J. Fulari, and G. M. Lohar, Review on recent progress in hydrothermally synthesized MCo2O4/rGO composite for energy storage devices," Chem. Eng. J. 426(2021)131544.

DOI: 10.1016/j.cej.2021.131544

Google Scholar

[36] I. Clark, J. Smith, and R. L. Gomes, Towards the Continuous Hydrothermal Synthesis of Composite Nanomaterials, Nanomaterials, 10 (2020)2052.

DOI: 10.3390/nano10102052

Google Scholar

[37] Z. Zhang, Y. Huang, H. Gao, C. Li, J. Huang, and P. Liu, 3D glass fiber cloth reinforced polymer electrolyte for solid-state lithium metal batteries, J. Memb. Sci., 621 (2020)118940

DOI: 10.1016/j.memsci.2020.118940

Google Scholar

[38] B. S. Wu, P. Wang, and S. H. Teng, "Controllable synthesis and coating-thickness-dependent electrochemical properties of mesoporous carbon-coated α-Fe2O3 nanoparticles for lithium-ion batteries," Colloids Surfaces A Physicochem. Eng. Asp., 610(2021)125907

DOI: 10.1016/j.colsurfa.2020.125907

Google Scholar

[39] J. Bidal, M. Becuwe, C. Hadad, C. Davoisne, B. Porcheron, and A. N. Van Nhien, Hybrid Electrolytes Based on Optimized Ionic Liquid Quantity Tethered on ZrO 2 Nanoparticles for Solid-State Lithium-Ion Conduction, ACS Appl. Mater. Interfaces. 13 (2021) 15159−15167

DOI: 10.1021/acsami.0c22422

Google Scholar

[40] M. F. Majid, H. Fatimah, M. Zaid, C. F. Kait, A. Ahmad, and K. Jumbri, Ionic Liquid @ Metal-Organic Framework as a Solid Electrolyte in a Lithium-Ion Battery : Current Performance and Perspective at Molecular Level, Nanomaterials. 12(2022)1076.

DOI: 10.3390/nano12071076

Google Scholar

[41] A. K. E Fedeli , O. Garcia-Calvo , A. Gutiérrez-Pardo , T. Thieu , I. Combarro , R. Paris , J. Nicolas, H. Grande, I. Urdampilleta ,Towards advanced lithium metal solid-state batteries: Durable and safe multilayer pouch cell enabled by a nanocomposite solid electrolyte, Solid State Ionics. 392(2023)116148.

DOI: 10.1016/j.ssi.2023.116148

Google Scholar

[42] P. N. Didwal , Y.N. Singhbabu , R. Verma , B. Sung , G. Lee , J. Lee , D.R. Chang , C. Park,., An advanced solid polymer electrolyte composed of poly ( propylene carbonate ) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries, Energy Storage Mater. 37(2021) 476–490, (2021)

DOI: 10.1016/j.ensm.2021.02.034

Google Scholar

[43] H. Zhan, M. Wu, R. Wang, S. Wu, H. Li, T. Tian and H. Tang, Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries, Polymers. 13(2021)2468.

DOI: 10.3390/polym13152468

Google Scholar

[44] L. M. Zhang , L. Xu, Bifunctional MOFs with robust mesoporous armors and superionic conduction, Chem.Eng.J.468(2023)0143599.

DOI: 10.1016/j.cej.2023.143599

Google Scholar

[45] Q. Zhu, J. Ma, S. Li, and D. Mao, Solid-State Electrolyte for Lithium-Air Batteries: A Review, Polymers (Basel).15(2023)2469

DOI: 10.3390/polym15112469

Google Scholar