The Role of Maleic Anhydride Polypropylene in Improvement Interaction Matrix – Reinforcement in Composites Based Waste Lignocellulose

Abstract:

Composite based waste lignocellulose with matrix Polypropylene (PP) is a potential material tall For application friendly environment in the sector automotive, construction, and products technique sustainable. However , the differences polarity between PP matrix which is hydrophobic and fiber lignocellulose which is hydrophilic cause problem adhesion weak interface , which results in low characteristic mechanics and stability morphology composite . Maleic Anhydride Grafted Polypropylene (MAPP) has Lots used as agent clutch (compatibilizer) for overcome incompatibility said . Article This serve review comprehensive to mechanism MAPP's work in increase interaction matrix – reinforcement in composites based waste lignocellulose . The study was conducted to various five years of primary literature last to report results experiment about characterization chemical, mechanical, thermal, and morphological from reinforced PP–MAPP composite fiber lignocellulose. MAPP works through reaction esterification between group anhydrides and groups hydroxyl on the surface fiber , forming bond covalent bonding that increases adhesion interface and allows efficient voltage transfer . The addition of MAPP in range of 2–5% proven increase strength tensile strength , modulus of elasticity , and resilience thermal. In addition that , MAPP also plays a role in repair distribution fiber and reduce defect structural . With Thus, MAPP plays role key in increase performance composite waste lignocellulose PP matrix, as well as become approach strategic For support green material development and economy circular.

• Periodical: Materials Science Forum (Volume 1189)
• Pages: 21-31
• DOI: https://doi.org/10.4028/p-G3lcMa
• Online since: May 2026
• Authors: Suryo S. Bibit Sugito*, Supriyono Supriyono, Rois Fatoni
• Keywords: Agent Clutch, Bond Interface, Composite Polypropylene, Fiber Lignocellulose, Maleic Anhydride Polypropylene

References

[1] T. Cionita et al., "Mechanical Characteristics of Biocomposites Based on Rice Husk Reinforced Recycled Polypropylene", Int. J. Integr. Eng., roč. 16, č. 2, dub. 2024.

DOI: 10.30880/ijie.2024.16.02.029

[2] VA Yiga, S. Pagel, M. Lubwama, S. Epple, PW Olupot, a C. Bonten, "Development of fiber-reinforced polypropylene with NaOH pretreated rice and coffee husks as fillers: Mechanical and thermal properties", J. Thermoplast. Compost. Mater. , roč. 33, č. 9, s. 1269–1291, zář. 2020.

DOI: 10.1177/0892705718823255

[3] "No Title".

DOI: 10.1016/j.ceja.2021.100186

[4] M. Mujtaba et al. , "Lignocellulosic biomass from agricultural waste to the circular economy: a review with focus on biofuels, biocomposites and bioplastics", J. Clean. Prod. , roč. 402, s. 136815, kvě. 2023.

DOI: 10.1016/j.jclepro.2023.136815

[5] C. Zárate-Pérez, R. Ramírez-Aguilar, EA Franco-Urquiza, a C. Sánchez-Alvarado, "The Role of Coupling Agents in the Mechanical and Thermal Properties of Polypropylene/Wood Flour Composites", Macromol , roč. 3, č. 1, s. 65–78, úno. 2023.

DOI: 10.3390/macromol3010006

[6] S. Borysiak a D. Paukszta, "Mechanical Properties of Lignocellulosic/Polypropylene Composites", Mol. Cryst. Liq. Cryst., roč. 484, č. 1, s. 13/[379]-22/[388], dub. 2008.

DOI: 10.1080/15421400801901464

[7] D. Ndiaye a A. Tidjani, "Effects of coupling agents on thermal behavior and mechanical properties of wood flour/polypropylene composites", J. Compos. Mater. , roč. 46, č. 24, s. 3067–3075, lis. 2012.

DOI: 10.1177/0021998311435675

[8] L. Hu a PY Vuillaume, "Reactive compatibilization of polymer blends by coupling agents and interchange catalysts", in Compatibilization of Polymer Blends , Elsevier, 2020, s. 205–248.

DOI: 10.1016/B978-0-12-816006-0.00007-4

[9] W. Qiu, F. Zhang, T. Endo, a T. Hirotsu, "Effect of maleated polypropylene on the performance of polypropylene/cellulose composite", Polym. Compost. , roč. 26, č. 4, s. 448–453, srp. 2005.

DOI: 10.1002/pc.20119

[10] Y. SASASE, J. QIU, E. SAKAI, a G. ZHANG, "Effect of MAPP on Morphologies and Mechanical Properties of PP/Rice Straw Composites", Proc. Mater. Mech. Conf. , roč. 2021, s. OS0124, 2021.

DOI: 10.1299/jsmemm.2021.OS0124

[11] R. Watanabe, A. Sugahara, H. Hagihara, J. Mizukado, a H. Shinzawa, "Insight into interfacial compatibilization of glass-fiber-reinforced polypropylene (PP) using maleic-anhydride modified PP employing infrared spectroscopic imaging", Compos. Sci. Technol. , roč. 199, s. 108379, říj. 2020.

DOI: 10.1016/j.compscitech.2020.108379

[12] OH Margoto, KDS Do Prado, RC Mergulhão, VADS Moris, a JMF de Paiva, "Mechanical and Thermal Characterization of Jute Fabric-Reinforced Polypropylene Composites: Effect of Maleic Anhydride", J. Nat. Fibers, roč. 19, č. 5, s. 1792–1804, kvě. 2022.

DOI: 10.1080/15440478.2020.1788489

[13] C. Sergi, F. Sbardella, M. Lilli, J. Tirillò, A. Calzolari, a F. Sarasini, "Hybrid Cellulose–Basalt Polypropylene Composites with Enhanced Compatibility: The Role of Coupling Agent", Molecules , roč. 25, č. 19, s. 4384, zář. 2020.

DOI: 10.3390/molecules25194384

[14] S. Mohanty, SK Nayak, SK Verma, a SS Tripathy, "Effect of MAPP as a Coupling Agent on the Performance of Jute–PP Composites", J. Reinf. Plast. Compost. , roč. 23, č. 6, s. 625–637, dub. 2004.

DOI: 10.1177/0731684404032868

[15] N. Poonia, V. Kadam, N.M. Rose, a S. Yadav, "Rice Straw Reinforced Biocomposite: A Sustainable Development", Int. J. Innov. Eng. Sci. , roč. 6, č. 10, s. 139, srp. 2021.

DOI: 10.46335/IJIES.2021.6.10.29

[16] M. Bassyouni a S. Waheed Ul Hasan, "The use of rice straw and husk fibers as reinforcements in composites", in Biofiber Reinforcements in Composite Materials , Elsevier, 2015, s. 385–422.

DOI: 10.1533/9781782421276.4.385

[17] Y. Zhang, H. Wang, X. Sun, Y. Wang, a Z. Liu, "Separation and characterization of biomass components (cellulose, hemicellulose, and lignin) from corn stalk", BioResources , roč. 16, č. 4, s. 7205–7219, zář. 2021.

DOI: 10.15376/biores.16.4.7205-7219

[18] MS Rahman, MIH Mondal, MS Yeasmin, MA Sayeed, MA Hossain, a MB Ahmed, "Conversion of Lignocellulosic Corn Agro-Waste into Cellulose Derivative and Its Potential Application as Pharmaceutical Excipient", Processes , roč. 8, č. 6, s. 711, cer. 2020.

DOI: 10.3390/pr8060711

[19] M. Sinner, J. Puls, a H. Dietrichs, "Carbohydrate Composition of Nut Shells and Some Other Agricultural Residues", Starch - Stärke, roč. 31, č. 8, s. 267–269, led. 1979.

DOI: 10.1002/star.19790310807

[20] PF de Oliveira a M. de F. V Marques, "Comparison between coconut and Curaua fibers chemically treated for compatibility with PP matrices", J. Reinf. Plast. Compost. , roč. 33, č. 5, s. 430–439, bře. 2014.

DOI: 10.1177/0731684413516392

[21] B. M. Bright et al., "Characterization of Natural Cellulosic Fiber from Cocos nucifera Peduncle for Sustainable Biocomposites", J. Nat. Fibers, roč. 19, č. 14, s. 9373-9383, říj. 2022.

DOI: 10.1080/15440478.2021.1982827