High Temperature Microstructural Stability of Si3N4 in TiAl Alloys

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Abstract:

Alloys of Ti-50 at.% Al with (3 and 10)wt.% Si3N4 particles were prepared by a mechanical alloying-spark plasma sintering (MA-SPS) method. The matrix consisted primarily of TiAl, Ti2AlN, TiN. Si3N4 was unstable in the matrix and started to decompose forming a Ti5Si3 reaction layer on the surface of former Si3N4 particles during sintering and heat treatment at 1373 K.

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Materials Science Forum (Volumes 534-536)

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1577-1580

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January 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] Concentration ( at% ) Position (b).

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[45] 29(Ti+N) + 29. 51(Al) + 23. 16(O) + 2. 04(Si).

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[2] [73] 95(Si) + 17. 21(O) + 8. 84(Al).

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[1] Concentration ( at% ) Position (b) 1 2 3 4 (a) 10㎛ 2 1 3 (a) 10㎛.

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