Fundamental Property of Metals – Grain Boundaries Phase Transition as a Basis of Nanostructured Layers, Materials and Composites Production

Article Preview

Abstract:

The obtained generalized equation for description of a fundamental property of solid crystalline materials i.e. first-order phase transition of the grain boundaries with formation of two-dimensional liquid has been used for calculating of transition temperature of any metals, which value lies in range 0.55 – 086 of melting point. Based on these conclusions to develop strategies for effective forming of coatings by synthesis of nitrides and carbonitrides on surface layers of hard metals and chromium steels have been made. It was shown the hardening of thin surface layer (0.1-0.5mm) due enriched of a nitrides in steels and carbonitrides with diamond like structure and strengthening the following layer by recristallization of W carbides in WC-Co and WC-TiC-Co hard metal. These result to increase of alloys hardness, ductility, and resistance to wear and decrease of sensibility to fragile rupture. Industrial tests have been made.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 654-656)

Pages:

1852-1855

Citation:

Online since:

June 2010

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2010 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y.A. Minaev: J. Phys. Chem. (Rus) Vol. 46(1972), p.1090.

Google Scholar

[2] Y.A. Minaev: Surface Phenomena in Metallurgy (Metallurgia Publis., USSR, Moscow, 1984).

Google Scholar

[3] Y.A. Minaev: J. Phys. Chem (Rus), Vol. 81(2007), p.1.

Google Scholar

[4] Ya.I. Frenkel: Kinetics Theory of Liquids (RAN USSR Publis., Moscow - Leningrad, 1959).

Google Scholar

[5] V.V. Krotov, A.I. Rusanov: Physicochemical Hydrodynamics of Capillary Systems (Imperial College Press, London, 1999); A.I. Rusanov, in: The Modern Theory of Capillarity, edited by A.I. Rusanov (USSR) and F.C. Goodrich (USA) Khimia Publis., Leningrad, (1980).

DOI: 10.1142/p138

Google Scholar

[6] A.I. Rusanov: Phase Equilibriums and Surface Phenomena, (Khimia Publis., Leningrad, 1967).

Google Scholar

[7] F. Inoko, T. Yoshikawa: Mat. Sci. Forum Vol. 204-206 (1996), p . 379.

Google Scholar