Paper Titles

Piezoelectric Potential Distribution in a Bent ZnO Nanorod Cantilever
p.23

Hydrothermal Synthesis of Monodisperse Leaf-Like Boehmite Nanosheets: Transformation from Irregular to Regular Morphology
p.28

Investigation on Heat Transfer Performances of Nanofluids in Solar Collector
p.33

Study on Nitrogen-Doped Titania Nanotubes as Visible-Light Responded Photocatalysts
p.37

Structure Study of Nanocrystalline O-LiMnO₂
p.42

Study on Photo-Catalytic Properties of Nano-TiO₂/Anthraquinone in a Sandwich-Type Bipolar Membrane
p.49

Hopping Probe Ion Conductance Microscopy and its Combined Patch-Clamping：A Powerful Tool for Structural and Functional Studies in Neural Nanobiology
p.54

High-Yield Synthesis of Bamboo-Like BN Nanotubes Using Self-Propagation High Temperature Synthesized Porous Precursor
p.59

Effect of Nano-SiO₂ on the Rheology of Anionic Viscoelastic Solutions Formed by the Biodegradable Surfactant Fatty Acid Methyl Ester Sulfonate
p.64

HomeMaterials Science ForumMaterials Science Forum Vol. 694Structure Study of Nanocrystalline O-LiMnO2

Structure Study of Nanocrystalline O-LiMnO₂

Article Preview

Abstract:

The nanocrystalline orthorhombic LiMnO2 was successfully synthesized with the raw materials of MnO2, Mn (CH3COO)2 and LiOH by hydrothermal synthesis method, which has the properties of small size, less stacking faults and single phase. High resolution electron microscopy images show that along the b axis of the orthogonal LiMnO2, MnO6 and LiO6 octahedron arrange alternately and regularly. The orthorhombic LiMnO2 is proved to be p-type semiconductor by the Hall test. XPS tests indicate that the trivalent Mn in the o-LiMnO2 is in the high-spin state. And the magnetic study shows that there is reentrant spin glass behavior in o-LiMnO2. The contrast study of Raman spectroscopy and magnetic susceptibility shows that the characteristic mode softening of structural phase transition corresponds to the magnetic phase transition temperature, indicating a possible interaction between phonons and spin.

You might also be interested in these eBooks

Frontier of Nanoscience and Technology

Info:

Periodical:

Materials Science Forum (Volume 694)

Pages:

42-48

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.694.42

Citation:

Cite this paper

Online since:

July 2011

Authors:

Li Zhu Zhao, Gang Chen

Keywords:

HR-TEM, Magnetic, O-LiMnO₂ Material, Raman Spectroscopy

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W.D. Johnston and R. R. Heikes: J. Amer. Chem. Soc. Vol. 78 (1956), p.3255.

[2] V. R. Hoppe, G. Brachtel and M. Jansen: Z. Anorg. Allg. Chem. Vol. 417 (1975), p.1.

[3] L. Croguennec, P. Deniard, R. Brec et al.: J. Mater. Chem. Vol. 5(11) (1995), p. (1919).

[4] A. R. Armstrong and P. G. Bruce: Nature Vol. 381(1996), p.499.

[5] S-T. Myung, S. Komaba and N. Kumagai: Electrochimica Acta Vol. 47 (2002), p.3287.

[6] Q. Liu, D.L. Mao, C. K. Chang et al.: J. Power Sources Vol. 173 (2007), p.538.

[7] F. Zhou, X. M. Zhao, Y. Q. Liu et al.: J. Phys. Chem. Solids Vol. 69 (2008), p. (2061).

[8] E. M. Jin, B. Jin, Y. S. Jeon et al.: J. Power Sources Vol. 189 (2009), p.620.

[9] S. T. Myung, S. Komaba and N. Kumagai: Solid State Ionics Vol. 150 (2002), p.199.

[10] J. M. Kim and H. T. Chung: J. Power Sources Vol. 115 (2003), p.125.

[11] Y.S. Lee, Y.K. Sun, K. Adachi et al.: Electrochimica Acta Vol. 48 (2003), p.1031.

[12] Y. I. Jang, F. C. Chou, B. Y. Huang et al.: J. Phys. Chem. Solids Vol. 64 (2003), p.2525.

[13] L. Croguennec, P. Deniard, R. Brec et al.: Solid State Ionics Vol. 89 (1996), p.127.

[14] M. Q. Wu, A. Chen, R.Q. Xu et al.: Microelectronic Engineering Vol. 66 (2003), p.180.

[15] X-D. Li, W-S. Yang, S-C. Zhang et al.: Solid State Ionics Vol. 176 (2005), p.803.

[16] L. Croguennec, P. Deniard, R. Brec et al.: J. Mater. Chem. Vol. 7(3) (1997), p.511.

[17] B.R. Strohmeier and D.M. Hercules: J. Phys. Chem. Vol. 88 (1984), p.4922.

[18] R. N. Bhowmik and R. Ranganathan: J. Appl. Phys. Vol. 93(5) (2003), p.2780.

[19] R. S. Freitas, L. Ghivelder, F. Damay et al.: Pyhs. Rev. B Vol. 64 (2001), p.144404.

[20] L. Z. Zhao, G. Chen, F. Y. Li et al.: Acta Physica Sinica Vol. 56(10) (2007), p.6045.

[21] J. E. Greedan, N. P. Raju, A. Maignan et al.: Pyhs. Rev. B Vol. 54 (1996), p.7189.

[22] C. A. Cardoso, F. M. Araujo-Moreira,. P. S. Awana et al.: Pyhs. Rev. B Vol. 67 (2003), p.020407(R).

[23] G. X. Cheng: Raman Brillouin Scattering(Pekin science press, 2003, p.226), in Chinese.

[24] L.Z. Zhao, Y.W. Chen and G.R. Wang: Solid State Ionics Vol. 181 (2010), p.1399.