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Dissociative Adsorption of Carbonaceous Gases on Ni Containing Representative Elements

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Abstract:

Laboratory metal dusting test of several Ni binary alloys containing the representative element was conducted in a simulated syngas atmosphere at 650°C for 100h. The Ni alloys containing element belonging to Group 14 and 15 in the periodic series exhibited excellent metal dusting resistance, while those containing Group 13 did not. This behavior was able to be reasonably interpreted from the Blyholder mechanism and the concept of Pauling’s electronegativity.

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Periodical:

Materials Science Forum (Volume 696)

Pages:

45-50

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.696.45

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Online since:

September 2011

Authors:

Yoshitaka Nishiyama, Koji Moriguchi, Nobuo Otsuka

Keywords:

Carburization, Electronegativity, Electronic Structure, Metal Dusting, Representative Element, Surface Segregation

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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