Synthesis and Characterization of Schiff Base with Bivalence Transition Metal Complexes Namely Cu, Co, Ni, Mn and Fe

A. Xavier; R Sathya; D. Usha; P.S. Harikrishnan

doi:10.4028/www.scientific.net/MSF.699.265

Paper Titles

A Theoretical Estimation of the Charge Density Distribution in the Diluted Magnetic Semiconductors of Si_1-xM_x and Ge_1-xM_x(M = V, Mn, Co)
p.167

Automation of Photoacoustic Spectrometer for NDE Applications
p.185

Template Synthesis, Spectral and Redox Behavior of Metal Complexes of Macrocyclic Tetraaza Schiff Base and their Interaction with Herring Sperm DNA
p.205

Copper (II) Complexes of Knoevenagel Condensate β-Diketimines as Models for Blue Copper and their Interaction with DNA
p.231

Removal of Methylene Blue by Adsorption Process - A Comparative Study
p.245

Synthesis and Characterization of Schiff Base with Bivalence Transition Metal Complexes Namely Cu, Co, Ni, Mn and Fe
p.265

Synthesis and Characterization of Ligand and its Metal Complexes
p.273

Phenol and Formaldehyde Cationic Resin Blended with Sulphonated Aegle Marmelos Charcoal
p.281

HomeMaterials Science ForumMaterials Science Forum Vol. 699Synthesis and Characterization of Schiff Base with...

Synthesis and Characterization of Schiff Base with Bivalence Transition Metal Complexes Namely Cu, Co, Ni, Mn and Fe

Abstract:

A series of metal complexes have been synthesized by the reaction of Schiff base with metal (II) salt solution. The complexes were characterized by UV and FT- IR studies. The study reveals that the geometry of the complexes were octahedral. The electronic spectra of these complexes show a strong absorption band in 550 - 580nm region. This confirms the coordination of ligand with metal. The FT-IR shows a very strong band at 1616cm^-1 assigned to C=N stretching vibration. It is shifted to lower wave number because of the complex formation, suggesting that coordination of the Schiff base groups through N- atoms with the metal ion. The band at 3496 cm^-1 is due to aromatic N-H stretching, It is noted that a broad band of the asymmetric and symmetric O-H stretching mode around the region 3400 cm^-1 presumably due to H-O-H bending vibrations are not observed in the spectrum of complexes, which are indicating of the absence of the water molecule.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Materials Science Forum (Volume 699)

Pages:

265-271

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.699.265

Citation:

Cite this paper

Online since:

September 2011

Authors:

A. Xavier, R Sathya, D. Usha, P.S. Harikrishnan

Keywords:

FT-IR Study, Metal Complexes, Schiff-Base

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] P.A.N. Reddy, R. Datta, A.R. Chakravarthy, Inorg. Chem. Commun. 3 (2000) p.322.

Google Scholar

[2] P.A.N. Reddy, M. Nethaji, A.R. Chakravarthy, Inorg. Chem. Commun. 337 (2000) p.450.

Google Scholar

[3] P.J. Dardlier, R.E. Holmlin, J.K. Barton, Science 275 (1997) pp.1465-1468.

Google Scholar

[4] D. B. Hall, R.E. Holmlin, J.K. Barton, Nature 382 (1996). p.

Google Scholar

[5] V.V. Mulwad, J.M. Shirodkar, Ind.J. Hetrocyclic chem. 11 (2002) p.199.

Google Scholar

[6] N. Sari, S. Arslan, E. Logoglu, I. ariyan, G.V.J. Sci 16(2003) p.283.

Google Scholar

[7] S.A. Khan, A. A Siddiqui, B. Shibeer, Aian J. chem. 14 (2002) pp.731-735.

Google Scholar

[8] Z.H. Chohan, H. Perrvez, S. Kausar, et. Al., synthesis and characterization of antibacterial Co(II), Cu(II), Ni(II) and Zn(II) complexes of acylhydrazine derived pyrrolyl compound, synthesis React, Inorg. Met. Org. chem. 32(2002) pp.529-543.

DOI: 10.1081/sim-120003793

Google Scholar