Experimental Study of Magnetocaloric Effect in Ni-Fe-Mn-Ga and Ni-Co-Mn-Ga Heusler Alloys

Article Preview

Abstract:

In this work we experimentally studied the MCE in the Heusler alloys Ni2.19-xFexMn0.81Ga (x = 0.01, 0.02, 0.03, 0.04) and Ni2.16-xCoxMn0.84Ga (x = 0.03, 0.06, 0.09). Magnetocaloric effect was measured by the direct method using the installation from the company AMT&C. The temperature dependencies of ∆Tad for the magnetic field change ∆H = 2 T were measured. The phase transition temperatures were determined from temperature dependencies of low field magnetization measured by original setup using Hall effect. Studies have shown that replacement of the Ni atoms with the iron atoms slightly reduces the temperature magnetostructural transition for x = 0.01,0.02, and starting with x = 0.03, magnetic and structural transitions occur separately and a further increase in iron concentration leads to the Curie temperature increase, while the temperature martensitic transformation decreases. When replacing the Ni atoms with the Co atoms of the martensitic transformation temperature and Curie temperature increase.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 738-739)

Pages:

456-460

Citation:

Online since:

January 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] V.K. Pecharsky, A.P. Horn, K.A. Gschneidner Jr., R. Rink, Massive Magnetic-Field-Induced Structural Transformation in Gd5Ge4 and the Nature of the Giant Magnetocaloric Effect, Phys. Rev. Lett. 91 (2003) 197204/1–197204/4.

Google Scholar

[2] V.K. Pecharsky, K.A. Gschneidner Jr., Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ~ 20 to ~ 290 K, Appl. Phys. Lett. 70 (1997) 3299-3301.

DOI: 10.1063/1.119206

Google Scholar

[3] O. Tegus, E. Bruck, K.H.J. Buschow, F.R. de Boer, Transition-Metal-Based Magnetic Refrigerants for Room-Temperature Applications, Nature 415 (2002) 150-152.

DOI: 10.1038/415150a

Google Scholar

[4] S. Gama, A.A. Coelho, A.A. Campos, A.M.G. Cavalho, F.C.G. Gandra, P.J.V. Ranke and N.A.D. Oliveira, Pressure-induced colossal magnetocaloric effect in MnAs, Phys. Rev. Lett. 93 (2004) 237202/1–237202/4.

DOI: 10.1103/physrevlett.93.237202

Google Scholar

[5] A.A. Cherechukin, I.E. Dikshtein, D.I. Ermakov, et al., Shape memory effect due to magnetic field-induced thermoelastic martensitic transformation in polycrystalline Ni–Mn–Fe–Ga alloy, Phys. Lett. A 291 (2001) 175–183.

DOI: 10.1016/s0375-9601(01)00688-0

Google Scholar

[6] G.H. Wu, W.H. Wang, J.L. Chen, et al., Magnetic properties and shape memory of Fe-doped Ni52Mn24Ga24 single crystals, Appl. Phys. Lett. 80 (2002) 634.

DOI: 10.1063/1.1447003

Google Scholar

[7] Z. H. Liu, M. Zhang, W. Q. Wang, et al., Magnetic properties and martensitic transformation in quaternary Heusler alloy of NiMnFeGa, J. Appl. Phys. 92 (2002) 5006.

Google Scholar

[8] A.A. Cherechukin, V.V. Khovailo, R.V. Kposov, et al., Training of the Ni–Mn–Fe–Ga ferromagnetic shape-memory alloys due cycling in high magnetic field, J. Magn. Magn. Mater. 258–259 (2003) 523-525.

DOI: 10.1016/s0304-8853(02)01064-8

Google Scholar

[9] V. Buchelnikov, I. Dikshtein, R. Grechishkin, et al., Ultrasound-induced martensitic transition in ferromagnetic Ni2. 15Mn0. 81Fe0. 04Ga shape memory alloy, J. Magn. Magn. Mater. 272–276 (2004) 2025-(2026).

DOI: 10.1016/j.jmmm.2003.12.778

Google Scholar

[10] M. Khan, I. Dubenko, S. Stadler, and N. Ali, Magnetic and structural phase transitions in Heusler type alloys Ni2MnGa1−xInx, J. Phys.: Condens. Matter. 16 (2004) 5259.

DOI: 10.1088/0953-8984/16/29/017

Google Scholar

[11] M. Khan, I. Dubenko, S. Stadler, and Naushad Ali, The structural and magnetic properties of Ni2Mn1−xMxGa (M=Co, Cu), J. Appl. Phys. 97 (2005) 10M304.

DOI: 10.1063/1.1847131

Google Scholar

[12] S. Stadler, M. Khan, M. Gomes, et al., Magnetocaloric properties of Ni2Mn1−xCuxGa, Appl. Phys. Lett. 88 (2006) 192511.

DOI: 10.1063/1.2202751

Google Scholar

[13] V. Khovaylo, V. Koledov, V. Shavrov, et al., Compositional dependence of magnetic entropy change in Ni2+xMn1-xGa with coupled magnetostructural phase transition, Proc. Second IIF – IIR Intern. Conf. Magnetic Refrigeration at Room Temperature (2007).

Google Scholar

[14] J. Duana, P. Huanga, Hu Zhang, et. al., Negative and positive magnetocaloric effect in Ni–Fe–Mn–Ga alloy, J. Magn. and Magn. Materials, 309 (2007) 96-99.

Google Scholar

[15] Y.I. Spichkin, et al., Direct measurements of the magnetocaloric effect: realization and results Proc. 3rd IIF-IIR Intern. Conf. Magnetic Refrigeration at Room Temperature, (2009) 173.

Google Scholar

[16] V.V. Khovaylo, et al., Adiabatic temperature change at first-order magnetic phase transitions: Ni2. 19Mn0. 81Ga as a case study, Phys. Rev. B 78 (2008) 060403(R).

Google Scholar