Photo Catalytic Properties of Fe-Modified and Magnetic Nanotitanium Prepared by Hydrothermal Method

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In order to improve the separation efficiency and the circular utilization ratio of the catalyst, the Fe-doped nanotitanium and nanotitanium supported on Fe2O3 carrier was prepared by hydrothermal method. The tetra-butyl titanate and ethanol were used as starting materials to prepare nanotitanium. The results of Fe-doped nanotitanium showed that the doping of iron changed the nanotitanium crystal and crystal morphology. No matter UV-light or mercury lamp 577 nm irradiation, the samples with 0.5 mM Fe addition showed the highest photo catalytic activity, with degradation rate of methyl blue above 95%. The structure, photo catalytic activity and magnetic properties analysis showed that the magnetic nanotitanium met the purpose of separation between the catalyst and reaction solution. The photo catalytic activity of nanotitanium supported on Fe2O3 carrier has respond to visible light. With mercury lamp 577 nm as irradiation source, degradation rate of methylene blue light could reach 63.40%.

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Materials Science Forum (Volumes 743-744)

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843-848

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] U. Diebold, The surface science of titanium dioxide, Surface Science Reports. 48 (2003) 53-229.

DOI: 10.1016/s0167-5729(02)00100-0

Google Scholar

[2] J.H. Carey, J.L., H.M. Tosine, Photodechlorination of PCB's in the presence of titanium dioxide in aqueous suspension, J. Bulletin of Environmental contamination and toxicology. V16 (1976)697-701.

DOI: 10.1007/bf01685575

Google Scholar

[3] M. Gratzel, Dye-sensitized solar cells, Journal of Photochemistry and Photobiology C-Photochemistry Reviews. 4 (2003)145-153.

DOI: 10.1016/s1389-5567(03)00026-1

Google Scholar

[4] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature. 238 (1972) 37-38.

DOI: 10.1038/238037a0

Google Scholar

[5] T. Miki, et al., Preparation of nanoporous TiO2 film with large surface area using aqueous sol with trehalose, Materials Letters. 58 (2004) 2751-2753.

DOI: 10.1016/j.matlet.2004.04.015

Google Scholar

[6] A. Murakami, et al., Synthesis of porous titania thin films using carbonatation reaction and its hydrophilic property, Thin Solid Films. 516 (2008) 3888-3892.

DOI: 10.1016/j.tsf.2007.07.148

Google Scholar

[7] S. Kim, S.J. Hwang, W.Y. Choi, Visible light active platinum-ion-doped TiO2 photo catalyst. Journal of Physical Chemistry B. 109 (2005) 24260-24267.

DOI: 10.1021/jp055278y

Google Scholar

[8] T.J. Kemp, R.A. McIntyre, Transition metal-doped titanium (IV) dioxide: Characterisation and influence on photo degradation of poly (vinyl chloride), Polymer Degradation and Stability. 91 (2006) 165-194.

DOI: 10.1016/j.polymdegradstab.2005.04.033

Google Scholar

[9] I.H. Tseng, J.C.S. Wu, H.Y. Chou, Effects of sol-gel procedures on the photocatalysis of Cu/TiO2 in CO2 photo reduction, Journal of Catalysis. 221 (2004) 432-440.

DOI: 10.1016/j.jcat.2003.09.002

Google Scholar

[10] X.Y. Li, P.L. Yue, C. Kutal, Synthesis and photo catalytic oxidation properties of iron doped titanium dioxide nano semiconductor particles, New Journal of Chemistry. 27 (2003) 1264-1269.

DOI: 10.1039/b301998e

Google Scholar

[11] R.S. Sonawane, B.B. Kale, M.K. Dongare, Preparation and photo-catalytic activity of Fe-TiO2 thin films prepared by sol-gel clip coating, Materials Chemistry and Physics. 85 (2004) 52-57.

DOI: 10.1016/j.matchemphys.2003.12.007

Google Scholar

[12] Z.J. Li, et al., Effect of Fe-doped TiO2 nanoparticle derived from modified hydrothermal process on the photo catalytic degradation performance on methylene blue, Journal of Hazardous Materials. 155 (2008) 590-594.

DOI: 10.1016/j.jhazmat.2007.11.095

Google Scholar

[13] Jing Zhang, et al., Preparation of nano-titania by hydrothermal method and progress in research of photo catalytic properties, Inorganic Chemicals Industry. 42 (2010) 6-9.

Google Scholar

[14] Y. Zhang, et al., Preparation and properties of a magnetically separated photocatalyst, New Chemical Materials. 36 (2008) 25-27.

Google Scholar

[15] S.W. Wang, et al., Preparation and characterization of TiO2/SiO2/gamma-Fe2O3-SiO2 magnetic photo catalyst, Chinese Journal of Catalysis. 26 (2005) 938-940.

Google Scholar

[16] T. Tong, J. Zhang, B. Tian, F. Chen, D. He, Preparation of Fe3+-doped TiO2 catalysts by controlled hydrolysis of titanium alkoxide and study on their photocatalytic activity for methyl orange degradation, Journal of Hazardous Materials. V155 (2008).

DOI: 10.1016/j.jhazmat.2007.11.106

Google Scholar

[17] Songwei, W., et al., Preparation and Characterization of TiO2/SiO2/γ-Fe2O3-SiO2 Magnetic Photocatalyst. Chinese Journal of Catalysis, 2005. 26(11): pp.938-940.

Google Scholar