Effects of Heat Treatments on Corrosion Behavior of Mg AT72 Alloy

Article Preview

Abstract:

The effects of heat treatments, including T4, T5, T6 treatments, on corrosion behaviors of Mg-7Al-2Sn (AT72) alloy processed by high vacuum die casting have been investigated. The optical microscope, scanning electron microscope observations were used to analyze the microstructures, especially the distribution of second phase, phase contents and grain size. The hydrogen evolution tests, electrochemical methods including open circuit potential curves and polarization curves were used to describe the corrosion properties as well. The results indicated that different heat treatments had influence on microstructures, especially distribution of second phase, phase contents and grain sizes. The existence of second phase had a relationship with corrosion properties, in which the as-cast samples showed low corrosion rate in hydrogen evolution tests while the heat treatment methods had little impact on improving corrosion resistance. The electrochemical analyses also agreed with this observation. Based on these results, the optimized heat treatment method for corrosion resistant AT72 magnesium alloy has been established.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 747-748)

Pages:

230-237

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K.Y. Sohn, J.A. Yurko, F.C. Chen, J.W. Jones, J.E. Allison, Proc. Auto Alloys II, San Antonio, TX, The Material, Metals and Minerals Society. (1988) 81.

Google Scholar

[2] R.S. Busk, Magnesium Products Design. (1987) 499.

Google Scholar

[3] B.B. Clow, Magnesium Industry Overview, Advanced Materials and Processes. 150 (1996) 33.

Google Scholar

[4] G. Song, A. Atrens, Corrosion Mechanisms of Magnesium Alloys, Advanced Engineering Materials. 1 (1999) 11-33.

Google Scholar

[5] G.L. Song, A. Atrens, Understanding Magnesium Corrosion, Advanced Engineering Materials. 5 (2003) 837.

Google Scholar

[6] G. Song, Recent Progress in Corrosion and Protection of Magnesium Alloys, Advanced Engineering Materials. 7 (2005) 563.

Google Scholar

[7] N. Winzer, A. Atrens, G. Song, E. Ghali, W. Dietzel, K.U. Kainer, N. Hort, C. Blawert, A Critical Review of the Stress Corrosion Cracking (SCC) of Magnesium Alloys, Advanced Engineering Materials. 7 (2005) 659-693.

DOI: 10.1002/adem.200500071

Google Scholar

[8] G. Song, A. Atrens, Recent Insights into the Mechanism of Magnesium Corrosion and Research Suggestions, Advanced Engineering Materials. 9 (2007) 177-183.

DOI: 10.1002/adem.200600221

Google Scholar

[9] J.X. Jia, G.L. Song, A. Atrens, Influence of geometry on galvanic corrosion of AZ91D coupled to steel, Corrosion Science. 48 (2006) 2133-2153.

DOI: 10.1016/j.corsci.2005.08.013

Google Scholar

[10] N. Winzer, A. Atrens, W. Dietzel, G. Song, K.U. Kainer, Comparison of the linearly increasing stress test and the constant extension rate test in the evaluation of transgranular stress corrosion cracking of magnesium, Materials Science and Engineering A. 472 (2008).

DOI: 10.1016/j.msea.2007.03.021

Google Scholar

[11] N. Winzer, A. Atrens, W. Dietzel, V.S. Raja, G. Song, K.U. Kainer, Materials Science and Engineering A. (2008).

Google Scholar

[12] R.G. Li, Y. Xu, W. Qi, J. An, Y. Lu, Z.Y. Cao, Y.B. Liu, The effect of crystallographic orientation on the active corrosion of pure magnesium, Mater. Charact. 59 (11) (2008) 1643.

Google Scholar

[13] H.K. Lim, S.W. Sohn, D.H. Kim, J.Y. Lee, W.T. Kim, D.H. Kim, J. Effect of addition of Sn on the microstructure and mechanical properties of Mg–MM (misch-metal) alloys, Alloys Compd. 454 (1-2) (2008) 515.

DOI: 10.1016/j.jallcom.2007.09.074

Google Scholar

[14] T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, The Materials Information Society. 1 (1990) 899.

Google Scholar

[15] Alan A. Luo, Anil K. Sachdev. Proceedings of Magnesium Technology, San Francisco, TMS 2009, pp.437-443.

Google Scholar

[16] G.L. Song, A. Atrens, D. StJohn, An hydrogen evolution method for the estimation of the corrosion rate of magnesium alloys, Magnesium Technology 2001 Symposium, Minerals, Metals & Materials Soc., (2001) 255-262.

DOI: 10.1002/9781118805497.ch44

Google Scholar

[17] X.Y. Kang, Effects of chemical composition on the microstructure and mechanical properties of as-cast Mg-Al-Sn Alloys, Shanghai JiaoTong University. (2010) 18-19.

Google Scholar

[18] L.H. Mei, Solid-solution Aging and Electronic Structure of Mg-5wt% Sn Alloy, Sichuan University. (2007) 102-115.

Google Scholar

[19] K. C. Park, Microstructure and Corrosion properties of Mg-xSn-5Al-1Zn (x=0, 1, 5, and 9 mass%) Alloys, Materials Transactions. 51(2010) 472-476.

Google Scholar

[20] Z. Shi, M. Liu, A. Atrens, Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation, Corrosion Science. 52 (2010) 579.

DOI: 10.1016/j.corsci.2009.10.016

Google Scholar