Synthesis and Properties of Nano-TiO₂ Modified Fluorine-Containing Polyacrylate Soap-Free Emulsion

Abstract:

Nano-TiO₂ Modified Fluorine-Containing Polyacrylate Soap-Free Emulsion was Successfully Synthesized via Soap-Free Emulsion Polymerization Technique, in which the Polymerization Monomers Consisted of Methyl Methacrylate (MMA), Butyl Acrylate (BA) and Dodecafluoroheptyl Methacrylate (DFMA). the Influence of Amount of Initiator, Emulsifier, Containing Fluorine Monomer and nano-TiO₂ on the Performance of Emulsion was Investigated. the Results Showed that the Good Polymerization Stability, and High Monomer Conversion were Obtained when the Amount of Ammonium Initiator was 1.2%, the Amount of Reactive Emulsifier was 3.5%. with Increasing Amount of DFMA, the Monomer Conversion Decreased and the Gel Rate Increased Gradually with the Increase of DFMA Amount. UV-Blocking Ability of the Cotton Fabric Treated with the Hybrid Emulsion Containing Nano-Tio₂ increased with Increasing Amount of Nano-TiO₂. IR Spectrum Results Showed that Nano-TiO₂ and Fluorine-Containing Monomer were Successfully Introduced in the Segmental Structure of the Polymer. SEM Revealed that Nano-TiO₂ was Loaded on the Surface of the Treated Cotton Fabric which had Good Hydrophobicity.

• Periodical: Materials Science Forum (Volumes 809-810)
• Pages: 161-168
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.809-810.161
• Online since: December 2014
• Authors: Jian Hua Zhou*, Lin Ben Wang, Yan Jiao Cui, Jian Zhong Ma, Gen Xing Sun
• Keywords: Fabric, Nano-TiO₂, Organic Fluorine, Polyacrylate, Soap-Free Emulsion

References

[1] R. M. Wang, C. Li, Y.G. He, J. F. Wang, R. Li and Z. M. Wu. Fine Chemicals, Vol. 30 (2013) No. 2, p.208. (In Chinese).

[2] S. Ding, H. Li, F. Ai and Y. M. Zhang. New Chemical Materials, Vol. 39 (2011) No. 7, p.130. (In Chinese).

[3] Q. Liu, W.M. Tang, Y. C. Chen and M. Huang. Applied Mechanics and Materials, Vol. 339 (2013) No. 6, p.665.

[4] S. N. Yu, Y. M. Zhou, T. Zhang and M. He. Polymer-Plastics Technology and Engineering, Vol. 53 (2014) No. 6, p.531.

[5] D. H. Kim, Y. H. Lee, C. C. Park and H. D. Kim. Colloid and Polymer Science, Vol. 292 No. 1, p.173.

[6] Y. B. Cheng, Z. G. Wang. Polymer, Vol. 54 (2013) p.3047.

[7] T. Mousanejad, M. Khosravi, S. M. Tabatabaii, A. R. Khataee and K. Zare. Research on Chemical intermediates, Vol. 40 (2014) No. 2, p.711.

[8] J. L. Gong, G. J. Liu, G. X. Zhang, S. H. Liu, J. H. Wu and Q. W. Li. Advanced Materials Research, Vols. 521-822 (2013) p.287.

[9] W. Xu, Q. F. An, L. F. Hao, D. Zhang and M. Zhang. Applied Surface Science, (2013) No. 268, p.373.

[10] X. Y. Xiao and Y. Wang. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 348, p.151.

[11] J. H. Zhou, Lin. Zhang and J. Z. Ma. Chemical Engineering Journal, Vol. 223 (2013) p.8.

[12] S. F. Zhang, Y. F. He, R. M. Wang, Z. M. Wu and P. F. Song. Iran Polym J, (2013) No. 22, p.447.

[13] J. M. Zhang, Z. Y. Wang, X. G. Sun and Z. Peng. Paint & Coating Industry, Vol. 36 (2006) No. 8, p.17. (In Chinese).

[14] X. Y. Ren, K. H. Tian, C. L. Liu, H. J. Yang and S. Wang. China Adhesives, Vol. 20 (2011) No. 2, p.1. (In Chinese).

[15] J. H. Zhou, L. Zhang, C. Chen, X. Q. Hou. Fine Chemicals, Vol. 27 (2010) No. 5, p.480. (In Chinese).

[16] X. Y. Xiao, P. H. Du, C. X. Wan and H. P. Zhang. New Building Materials, Vol. 11 (2007) p.36. (In Chinese).

[17] W. R , H. Deng and J. H. Huan. Journal of Tianjin Polytechnic University, Vol. 27 (2008) No. 2, p.40. (In Chinese).