Synthesis of a Novel Lanthanide Oxide Nitrate Compound with 3D Structure

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Abstract:

One lanthanide nitrate (Ln = Tb) with a novel three dimensional structure have been prepared through hydrothermal method. Single crystal X-ray diffraction structures were obtained. The compound crystallizes in the orthorhombic, Pnma space group. The lanthanide ions are eight-coordinate with six oxygen atoms coming from nitrate ions and two from bridge oxygen atoms. If the bridge oxygen atoms could be ignored, the compound can be described as a rare microporous 3D Lanthanide nitride with the open framework.

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Materials Science Forum (Volumes 809-810)

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218-221

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December 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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