Preparation and Properties Characterization of N-Doped TiO2 Film

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Abstract:

Nitrogen-doped nanoTiO2 sol was prepared by sol-gel method. The obtained sol was coated onto glass substrates by spin coating method, followed by drying at low temperature and calcined at high temperature. The films were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and ultraviolet-visible spectra (UV-Vis) . The XRD spectra showed that the crystal type of N-doped TiO2 films was anatase. The SEM images showed that the surface of films were flat without obvious crack and average diameter was about 20 nm. The UV-Vis spectra showed that the absorbance of N-doped TiO2 films at ultraviolet region increased. N-doping caused photocatalysis response wavelength to turn longer. The photocatalytic activity of N-doped TiO2 films was researched through the degradation experiment of methyl orange under ultraviolet light. Higher photocatalytic degradation efficiency was exhibited compared to the pure TiO2 films.

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Materials Science Forum (Volumes 809-810)

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573-577

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December 2014

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y.C. Tang, C. Hu, Y.Z. Wang: Progress in Chemistry, Vol. 14 (2002) No. 3, p.192. (In Chinese).

Google Scholar

[2] S. Sato: Chem. Phys. Lett, Vol. 123(1986) No. 1-2, p.126.

Google Scholar

[3] H.M. Yates, M.G. Nolan, D.W. Sheel, et al: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 179(2006) No. 1-2, p.213.

Google Scholar

[4] J.G. Yu, X.J. Zhao: Journal of Inorganic Materials, Vol. 15(2000) No. 2, p.347. (In Chinese).

Google Scholar

[5] W.R. Shen, W.K. Zhao, F. He et al: Progress in Chemistry, Vol. 10(1998) No. 4, p.349. (In Chinese).

Google Scholar

[6] Y.Q. Hou, D.M. Zhuang, G. Zhang, et al: Environmental Protection of Chemical Industry, Vol. 24(2004) No. 3, p.180. (In Chinese).

Google Scholar

[7] Fujishima A, Zhang X T, Tryk D A: Surf Sci. Rep, Vol. 63(2008), No. 12, p.515.

Google Scholar

[8] Xu QC, Wellia DV, Amal R, et al: Nanoscale, Vol. 2(2010), No. 7, p.1122.

Google Scholar

[9] S.L. Chen, X.G. Diao, M. Yang, et al: Functional Material, Vol. 36(2005) No. 3, p.464 (In Chinese).

Google Scholar

[10] Ch. Trapalis, V. Kozhukharov, B. Samuneva, P. Stefanov: Journal of Materials Science, Vol. 28 (1993) No. 5, p.1276.

Google Scholar

[11] M.H. Wang S.J. Xu, H.Z. Zhang, et al: New Chemical Materials, Vol. 37 (2009) No. 10, p.76. (In Chinese).

Google Scholar

[12] Khan SU, Al-Shahry M, Ingler WB, et al: Science, Vol. 297 (2002) No. 5590, p.2243.

Google Scholar

[13] Q.A. Zhu, S.F. Wang, P. Zhang, et al: Fine Chemicals, Vol. 24 (2007) No. 6, p.526. (In Chinese).

Google Scholar

[14] Asahi R, Morikawa T, Ohwaki T, et al. Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides. Science[J]. 2001, 293(5528): 269-271.

DOI: 10.1126/science.1061051

Google Scholar

[15] L.W. Chen, Y. Feng, L.H. Gan Li-hua, et al: Research and Exploration in Labratory, Vol, 22(2003), No. 1, p.44. (In Chinese).

Google Scholar