Microstructure and Mechanical Properties of the W-Ni-Co System Refractory High-Entropy Alloys

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The elements Mo, Cr and V were added to the W-Ni-Co system high entropy alloys, the effects of these added elements on microstructure and mechanical properties of these alloys were studied. The alloys were produced by vacuum arc melting. The compositions were W0.5Ni2Co2VMo0.5, W0.5Ni2Co2VCr0.5 and W0.5Ni2Co2CrMo0.5 (denoted as Alloy 1, Alloy 2 and Alloy 3) respectively. The theoretical melting temperatures were higher than 2000 K. X-ray diffraction, SEM and energy dispersive spectroscopy (EDS) results indicated that the matrix of the alloys is face-centered cubic (FCC) solid-solution, the alloys showed dendrite crystal structure. Ni, Co elements were enriched in the dendrite areas, the W, Mo were enriched in the inter-dendrite regions ,while V, Cr elements were uniform distribution. The Vickers hardness of these alloys was 376.1 HV, 255.88 HV and 306.8 HV, respectively. The yield strength values (σ0.2) of Alloy 1, Alloy 2 and Alloy 3 were approximately 1000MPa, 750MPa, 250MPa, respectively. The alloys show good compression plasticity deformation capacity at RT.

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324-329

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] C.J. Tong, Y.L. Chen, J.W. Yeh. Microstructure Characterization of AlxCoCrCuFeNi high-entropy alloy system with multi-principal elements, Metall. Mater. Trans. A. 36(2005) 881-893.

DOI: 10.1007/s11661-005-0283-0

Google Scholar

[2] W.R. Wang, W.L. Wang., J.W. Yeh, Effects of Al addition on the microstructure and mechanical property of AlxCoCrFeNi high-entropy alloys, Intermetallics, 26(2012) 44-51.

DOI: 10.1016/j.intermet.2012.03.005

Google Scholar

[3] T.T. Shun, L.Y. Chang, M.H. Shiu. Age -hardening of the CoCrFeNiMo0. 85 high-entropy alloy, Meter. Charact. 81(2013) 92-96.

DOI: 10.1016/j.matchar.2013.04.012

Google Scholar

[4] G.E. Totten, L. Xie, K. Funatani. Hand book of mechanical alloy design, . New York: Marcel Dekker Inc (2004).

Google Scholar

[5] J.W. Yeh, S.K. Chen, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, et al. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes, Adv. Eng. Mater. 6(2004) 299–303.

DOI: 10.1002/adem.200300567

Google Scholar

[6] J.W. Yeh, Recent progress in high-entropy alloys, Ann. Chim-Sci. Mat. 31(2006) 633–648.

DOI: 10.3166/acsm.31.633-648

Google Scholar

[7] W.P. Chen, Z.Q. Fu, S.C. Fang, H.Q. Xiao, D.Z. Zhu, Alloying behavior, microstructure and mechanical properties in a FeNiCrCo0. 3Al0. 7 high entropy alloy, Mater. Des. 51(2013) 854–60.

DOI: 10.1016/j.matdes.2013.04.061

Google Scholar

[8] J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li, Z.Q. Hu, Microstructures and compressive properties of multicomponent AlCoCrFeNiMox alloys, Mater. Sci. Eng. A, 527(2010) 697–9.

DOI: 10.1016/j.msea.2010.07.028

Google Scholar

[9] S.G. Ma, Y. Zhang, Effect of N b addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy, Mater . Sci. Eng. A. 532(2012) 48–6.

Google Scholar

[10] Y.Y. Du, Y.P. Lu, T.J. Li, T.M. Wang, G. L Zhang, Effect of aluminium content of AlxCrFe1. 5Ni0. 5 multiprincipal alloys on microstructure and alloy hardness, Mater. Res. Innovations. 15(2011) 107-10.

DOI: 10.1179/143307511x12998222918796

Google Scholar

[11] Y.Y. Du, Y.P. Lu, T.M. Wang, T.J. Li, J.L. Zhang, Effect of electromagnetic stirring on microstructure and properties of Al0. 5CoCrCuFeNi alloy, Procedia. Eng. 63(2012), 1129-34.

DOI: 10.1016/j.proeng.2011.12.562

Google Scholar

[12] M.H. Tsai, J.W. Yeh. A Critical Review, Materials Research Letters, Mater. Res. Letters, 2(2014) 107-123.

Google Scholar

[13] Y. Zhang, T.T. Zuo, Z. Tang, Microstructure and properties of high-entropy alloys, Prog. Mater. SCI. 61(2014) 1-93.

Google Scholar

[14] O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P. K Liaw, Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys, Intermetallics. 18(2010) 1758-65.

DOI: 10.1016/j.intermet.2011.01.004

Google Scholar

[15] O.N. Senkov, C.F. Woodward. Microstructure and properties of a refractoryNbCrMo0. 5Ta0. 5Zr alloy. Mate. Sci. Eng. A. 529(2011) 311-20.

Google Scholar

[16] S. Guo, C. Ng, J. Lu, C.T. Liu. Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase, Progress in Natural Science: Material International 21(2011) 433-446.

DOI: 10.1016/s1002-0071(12)60080-x

Google Scholar

[17] S. Guo, Q. Hu, C. Ng, C.T. Liu. More than entropy in high-entropy alloys: Forming solid solutions or amorphous phase, Intermetallics. 41(2013) 96-103.

DOI: 10.1016/j.intermet.2013.05.002

Google Scholar