Synthesis and Characterisation of Li1-xNaxNi1/3Co1/3Mn1/3O2  as Cathode Materials for Rechargeable Lithium Batteries

Zulkifeli Abdullah; Rozana Aina Maulat Osman; S.P. Soo; N. Farahin; Mohd Sobri Idris

doi:10.4028/www.scientific.net/MSF.819.232

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HomeMaterials Science ForumMaterials Science Forum Vol. 819Synthesis and Characterisation of...

Synthesis and Characterisation of Li_1-xNa_xNi_1/3Co_1/3Mn_1/3O₂ as Cathode Materials for Rechargeable Lithium Batteries

Abstract:

Preliminary study on Na-doped LiNi_1/3Mn_1/3Co_1/3O₂ was carried out to investigate possibility substitution Li with Na. Samples were prepared using modified solid state synthesis route. X-ray diffraction (XRD) results show that the most optimum synthesis temperature for parent composition x=0 in Li_1-xNa_xNi_1/3Co_1/3Mn_1/3O₂ was 900°C. Solid solution limit for Na-doped LiNi_1/3Mn_1/3Co_1/₃O₂ is x < 0.2 (or 20% Na). For x ≥ 0.2 in Li_1-xNa_xNi_1/3Co_1/3Mn_1/3O_2,a secondary phase of sodium cobalt oxide (Na_0.6CoO₂) start to exist. Furthermore, at x ≥ 0.4, the secondary phase became a dominant phase in Li_1-xNa_xNi_1/3Co_1/3Mn_1/3O₂.

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Materials Science Forum (Volume 819)

Pages:

232-237

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.819.232

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Online since:

June 2015

Authors:

Zulkifeli Abdullah*, Rozana Aina Maulat Osman, S.P. Soo, N. Farahin, Mohd Sobri Idris

Keywords:

Lattice Parameters, Lithium Ion Battery, Sodium Battery, X-Ray Diffraction

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