Iron-Rich Glass-Ceramics Obtained from Mill Scale

Article Preview

Abstract:

Mill scale contains high amounts of iron and it is classified as residue Class 2 – Not Inert (ABNT NBR 10.004:2004). Considering its availability, this study aimed to investigate glass-ceramics from this residue focused on its valorization. The influence of lithium oxide and zirconia was also evaluated. Six formulations were melted at 1350 °C and obtained frits were wet ground, dried and characterized: X-ray fluorescence, X-ray diffraction, thermal differential analysis and dilatometry. Pressed bodies were dried and heat treated at 950 °C. After, crystallized samples were characterized by different techniques: X-ray diffraction, apparent and theoretical density, coefficient of thermal expansion, hardness and bending strength. Results showed that lithium oxide and zirconia significantly influenced the thermal and structural behavior of obtained glass-ceramics.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

411-416

Citation:

Online since:

June 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.L. Luza, D.C.N. Fabris, E.S. Gislon, M.M. Machado, O.R.K. Montedo: Mater. Sci. Forum Vols. 775-776 (2014), p.244.

DOI: 10.4028/www.scientific.net/msf.775-776.244

Google Scholar

[2] W. Han: Acta Metall. Sin. Vol. 22 (2009), p.181.

Google Scholar

[3] A.K. Varshneya: Fundamentals of Inorganic Glasses. (Academic Press, New York, 1994).

Google Scholar

[4] Z. Strnad: Glass Science and Technology. (Elsevier, New York, 1996).

Google Scholar

[5] W. Pannhorst: Overwiew, in: H. Bach (ed. ), Low Thermal Expansion Glass Ceramics, Springer, Germany, 1995, pp.1-12.

Google Scholar

[6] J.A. Rodrigues, F.S. Ortega, A.E.M. Paiva, E.L.G. Villaboim, V.C. Pandolfelli: Cerâmica Vol. 50 (2004), p.209.

Google Scholar

[7] O.R.K. Montedo, F.M. Bertan, R. Piccoli, D. Hotza, A.N. Klein, A.P.N. Oliveira: Amer. Cer. Soc. Bul. Vol. 87 (2008), p.34.

Google Scholar

[8] O.R.K. Montedo, F.J. Floriano, J. Oliveira Filho, E. Angioletto, A.M. Bernardin: Mater. Res. Vol. 12 (2009), p.197.

Google Scholar

[9] O.R.K. Montedo, F.J. Floriano, J. Oliveira Filho, C.M. Gomes, D. Hotza, A.P.N. Oliveira: Ceram. Int. Vol. 37 (2011), p.1865.

Google Scholar

[10] O.R.K. Montedo, D. Hotza, A.P.N. Oliveira, R. Meszaros, N. Travitzky, P. Greil: Adv. in Mater. Sci. and Eng. (2012), p.1.

Google Scholar

[11] B.M. French, P.A. Jezek, D.E. Appleman: Americ. Miner. Vol. 63 (1978), p.461.

Google Scholar

[12] S. Habelitz, G. Carl, C. Riissel, S. Thiel, U. Gerth, J.D. Schnapp, A. Jordanov, H. Knake: J. of Non-Cryst. Sol. Vol. 220 (1997), p.291.

DOI: 10.1016/s0022-3093(97)00299-8

Google Scholar

[13] Y.M. Sung: Ceram. Int. Vol. 23 (1997), p.401.

Google Scholar

[14] K.J. Anusavice, N. -Z. Zhang, J.E. Moorhead: Dental Mater. Vol. 10 (1994), p.141.

Google Scholar