Ti Doped LiMn1/3Co1/3Ni1/3O2 for Li-Ion Battery Application

Kelimah Elong; Norlida Kamarulzaman; Rusdi Roshidah

doi:10.4028/www.scientific.net/MSF.846.493

Paper Titles

Microwave Absorption Study of Polyaniline Nanocomposites with Different Dimension of Multiwalled Carbon Nanotubes
p.465

Characterization of Cu-Al₂O₃ and Ni-Al₂O₃ Nanocomposites Electrodeposited on Copper Substrate
p.471

Mechanochemical Synthesis of CNT/ZnO Hybrid Materials
p.479

Ultra-Sensitive Breath Sensor Device for Sleep Disorder Monitoring and Clinical Studying
p.484

Ti Doped LiMn_1/3Co_1/3Ni_1/3O₂ for Li-Ion Battery Application
p.493

Review of Energy and Power of Supercapacitor Using Carbon Electrodes from Fibers of Oil Palm Fruit Bunches
p.497

Conductivity and FTIR Studies of NaI-Na₃PO₄-PLL Electrolyte for Solid State Batteries
p.505

Effect of 1-Ethyl-3-Methylimidazolium Nitrate on the Electrical Properties of Starch/Chitosan Blend Polymer Electrolyte
p.510

Electrical Impedance Spectroscopy and Fourier Transform Infrared Studies of New Binary Li₂CO₃-LiI Solid Electrolyte
p.517

HomeMaterials Science ForumMaterials Science Forum Vol. 846Ti Doped LiMn1/3Co1/3Ni1/3O2 for Li-Ion Battery...

Ti Doped LiMn_1/3Co_1/3Ni_1/3O₂ for Li-Ion Battery Application

Abstract:

Single phase LiMn_0.3Co_0.3Ni_0.3Ti_0.1O₂ materials are prepared using a self-propagating combustion method. The structure and morphology of the materials were characterized using X-Ray powder diffraction (XRPD) and Field Emission Scanning Electron Microscopy (FESEM). The electrochemical performances of the materials were characterized by means of galvanostatic charge-discharge test on the fabricated cells. XRD results showed that the materials are impurity-free and single phase with well ordered hexaganol structure of Rm space group. The compound was annealed at 700 °C and 800 °C for 24 h. The discharge capacities obtained was 143 mAhg^-1 in the first cycle for both materials. The voltage range was between 2.5 to 4.2 V. The 30^thcycle, however, revealed that the material annealed at 700 °C shows the better performance. The capacity fading is only about 14% compared to 17% for the 800 °C sample. This implies that LiMn_0.3Co_0.3Ni_0.3Ti_0.1O₂ material is sensitive to annealing temperature. They exhibited good specific capacity values and looked promising for Li-ion battery application.

You might also be interested in these eBooks

Main Tendencies in Applied Materials Science

View Preview

Info:

Periodical:

Materials Science Forum (Volume 846)

Pages:

493-496

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.846.493

Citation:

Cite this paper

Online since:

March 2016

Authors:

Kelimah Elong, Norlida Kamarulzaman*, Rusdi Roshidah

Keywords:

Capacity Fading, Cathode, Li-Ion Battery, X-Ray Diffraction

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] K. Du, C. Hua, C. Tan, Z. Peng, Y. Cao, G. Hu, A high-powered concentration-gradient Li(Ni0. 85Co0. 12Mn0. 03)O2 cathode material for lithium ion batteries, J. Power Sources (2014), 203-208.

DOI: 10.1016/j.jpowsour.2014.04.047

Google Scholar

[2] J.M. Kim, N. Kumagai, Y. Kadoma, H. Yashiro, Synthesis and electrochemical properties of lithium non-stoichiometric Li1+x(Ni1/3Co1/3Mn1/3)O2+δ prepared by a spray drying method, J. Power Sources 174 (2007) 473–479.

DOI: 10.1016/j.jpowsour.2007.06.183

Google Scholar

[3] S. Hu, G.H. Cheng, M.Y. Cheng, B.J. Hwang, R. Santhanam, Cycle life improvement of ZrO2-coated spherical LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries, Journal of Power Sources 188 (2009) 564–569.

DOI: 10.1016/j.jpowsour.2008.11.113

Google Scholar

[4] N. Kamarulzaman , R.H.Y. Subban, K. Ismail, N. Othman, W.J. Basirun, M.A. Bustam, S.A. Puad, R. Yusof and A.F. M Fadzil, Characterization and microstructural studies of LiFeSO8 synthesized by the self propagating high temperature combustion method, Ionics 11 (2005).

DOI: 10.1007/bf02430264

Google Scholar

[5] N. Kamarulzaman, R. Yusooff, N. Kamarudin, N.H. Shaari, N.A. Abdul Aziz, M.A. Bustam, N. Blagojevic, M. Elcombe, M. Blackford, M. Avdeev and A.K. Arof, Investigation of cell parameters, microstructures and electrochemical behaviour of LiMn2O4 normal and nanopowders, J. Power Sources 188 (2009).

DOI: 10.1016/j.jpowsour.2008.10.139

Google Scholar

[6] W. Yuan, H.Z. Zhang, Q. Liu, G.R. Li, X.P. Gao, Surface modification of Li(Li0. 17Ni0. 2Co0. 05Mn0. 58)O2 with CeO2 as cathode material for Li-ion batteries, Electrochimica Acta 135 (2014) 199–207.

DOI: 10.1016/j.electacta.2014.04.181

Google Scholar

[7] J. Shu, R. Ma, L. Shao, M. Shui, K. Wu, M. Lao, D. Wang, N. Long, Y. Ren, In-situ X-ray diffraction study on the structural evolutions of LiNi0. 5Co0. 3Mn0. 2O2 in different working potential windows, J. Power Sources 245 (2014) 7-18.

DOI: 10.1016/j.jpowsour.2013.06.049

Google Scholar