Preparation and Photocatalytic Properties of Terrace Composite SnO2/TiO2:Cu2+ Film

Article Preview

Abstract:

nanoSnO2 and Cu-doped TiO2 gelatins were prepared by sol-gel method, coated onto glass substrates by spin coating method, followed by drying at low temperature and calcined at high temperature, the influence on the structure and properties made by doping amount and composite form was discussed about. The films were characterized by XRD, SEM , EDS and UV-Vis, the photocatalysis degradation efficiency was studied as well. The results showed that the SnO2/ TiO2:Cu2+films were anatase structure, the surface were flat and stable without obvious crack, average diameter was about 20 nm. EDS indicated that Cu was introduced to TiO2 stratum of the SnO2TiO2 films ; UV-Vis showed the absorbance at visible region increased comparing to pure TiO2 and mixed SnO2TiO2 system. The degradation experiment under UV light showed degradation efficiency of SnO2/ TiO2: Cu2+films was higher compared with the mixed structure films, When the doping amount of Cu increased to 10% (mole fraction), the photocatalysis degradation efficiency reached its maximum.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1112-1117

Citation:

Online since:

April 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H.B. Li: Preparation, Characterization and Properties of CuO and TiO2 micro-and nano-materials (MS., Tianjin University of Technology, China 2013), p.4.

Google Scholar

[2] X. J. Zheng, J. B. Zhao, J. Huang, et al: Journal of Guilin University of Technology, Vol. 32 (2012) No. 4, p.575. (In Chinese).

Google Scholar

[3] C. Lin, M. Y. Liu: CIESC Journal, Vol. 65 (2014) No. 11, p.4325. (In Chinese).

Google Scholar

[4] W. N. Mu, Y.C. Zhai and S. Z. Shi: Trans. Nonferrous Met. Soc. China, (2013) No. 23, p.1390.

Google Scholar

[5] Y . Wu, G. Lu and S. Li : Catalysis Letters, Vol. 1/2 (2009) No. 133, p.97.

Google Scholar

[6] W.W. Fu: Synthesis and Preparation of Transition Metal Compounds (Ti, V, Cu)as Energy and Catalytic Materials (Ph.D., Jilin University , China 2013), p.16.

Google Scholar

[7] S. X. Wu, Z. Ma, Y. N. Qin, et al: Acta Phys. -Chim. Sin, Vol. 10 (2003) No. 19, p.967.

Google Scholar

[8] X. J . Yang, S. Wang , H. M. Sun , et al: Trans. Nonferrous Met . Soc. China, (2015) No. 25,P. 504.

Google Scholar

[9] Z.L. Ma: Preparation and Performance Study of Titanium Dioxide nano-photocatalyst, (MS., Hunan University , China 2013), p.6.

Google Scholar

[10] Z. F. Sun , Y. G. Li: Chinese Journal of Inorganic Chemistry, Vol. 22 (2006) No. 12, p.2173.

Google Scholar

[11] X. J. Hu, Y. K. Shi , B. L. Zhu et al: Chinese Journal of Catalysis, (2015) No. 36, p.221.

Google Scholar

[12] J. H. Yu, M. G. Fan, B. Li, et al: Acta Phys. -Chim. Sin, Vol. 31 (2015) No. 3, p.519.

Google Scholar

[13] W. F. Xi, X. L. Zheng, Z. H. Li, et al: Journal of the Chinese Ceramic Society, Vol. 37 (2009) No. 2, p.275.

Google Scholar

[14] X. M. Sun, Q. Sun, C. C. Xie et al: Chinese Journal of Luminescence, Vol. 34 (2013) No. 3, P. 257.

Google Scholar

[15] P.J. Zhao, R. Wu, J. Hou, et al: Acta Phys. -Chim. Sin, Vol. 28 (2012) No. 8, p. (1971).

Google Scholar

[16] K. Ma, Y. Zhu, J. Wang, et al: Applied Chemical Industry, Vol. 41(2012) No. 8, p.1426. (In Chinese).

Google Scholar