Low-Power Triplet-Triplet Annihilation Upconversion with a New Anthracene Derivatives

Sai Jiang Zhu; Chang Qing Ye; Yan Fu; Zuo Qing Liang; Xiao Mei Wang

doi:10.4028/www.scientific.net/MSF.852.1265

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HomeMaterials Science ForumMaterials Science Forum Vol. 852Low-Power Triplet-Triplet Annihilation...

Low-Power Triplet-Triplet Annihilation Upconversion with a New Anthracene Derivatives

Abstract:

Two new anthracene derivatives were synthesized as emitter for low power triplet-triplet annihilation upconversion. Compared with anthracene, the emitter exhibits high quantum yields up to 85%. Pd (II) tetraphenylporphyrin which was selected as the sensitizer with the existence of BBA in DMF, We find a pretty high efficiency (Φuc=21.9%) of the upconversion fluorescence at 532nm with a low excitation power density of 0.5w/cm2.With the comparison of Anthracene, BBA and BTPA systems, quantum yield of the emitter is very important to the improving of the efficiency of upconversion.

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Periodical:

Materials Science Forum (Volume 852)

Pages:

1265-1270

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.852.1265

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Online since:

April 2016

Authors:

Sai Jiang Zhu, Chang Qing Ye, Yan Fu, Zuo Qing Liang, Xiao Mei Wang*

Keywords:

Anthracene Derivatives, Triplet-Triplet Annihilation, Upconversion

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