Effect of Degassing Treatment on the Crystalline Morphology of XLPE Insulation Used for 110kV XLPE Cable

Article Preview

Abstract:

Cross-linked polyethylene (XLPE) is a main kind of insulation materials, used in medium and high voltage power cable. High voltage XLPE cable production mainly adopts peroxide crosslinking method, and the performance of XLPE cable will be affected by decomposing by-products of crosslinking agent (DCP, dicumyl peroxide).In this paper, the XLPE cable was degassed with different times. The XLPE samples were analyzed by infrared spectrum analysis, DSC analysis and electron microscopy, and the influences of degassing on XLPE crystalline morphology were analyzed. The results showed that the crystal structure of XLPE in the cable was affected by degassing treatment. With the degassing treatment time went on, the by-products kept releasing. The content of by-products in 110kV XLPE cable decreased obviously in 2-7 days’ degassing treatment, and changed slowly after 7 days’. The growth and perfection of the original crystal in XLPE material were obtained, and the new small grains were formed in the material.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

33-37

Citation:

Online since:

August 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J.V. Gulmine and L. Akcelrud. Correlations between structure and accelerated artificial ageing of XLPE, Eur. Polym. J., 42, (2006) 553-562.

DOI: 10.1016/j.eurpolymj.2005.09.006

Google Scholar

[2] I. Krupa and A.S. Luyt, Mechanical properties of uncrosslinked and crosslinked linear low-density polyethylene/wax blends. J. Appl. Polym. Sci., 81(2001) 973-980.

DOI: 10.1002/app.1519

Google Scholar

[3] N. Hayashi, H. Suzuki, H. Miyake, Effect of cumylalcohol in XLPE on space charge formation and electric breakdown under DC high electric field, Proceeding of 2011 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP 2011), In Cancun, Mexico, 16-19 Oct. 2011, 145-148.

DOI: 10.1109/ceidp.2011.6232617

Google Scholar

[4] Y. Ohki, N. Hirai, K. Kobayashi and R. Minami, Effects of byproducts of crosslinking agent on space charge formation in polyethylene - comparison between acetophenone and α-methylstyrene, Proceeding of 69th Annual Conference on Electrical Insulation and Dielectric Phenomena, Victoria, Canada, OCT 15-18, 2000, 535-538.

DOI: 10.1109/ceidp.2000.884016

Google Scholar

[5] A. Smedberg, D. Wald, Determination of diffusion constants for peroxide by-products formed during the crosslinking of polyethylene, Proceeding of 17th Biennial IEEE International Symposium on Electrical Insulation, Vancouver, Canada, JUN 09-12, 2008, 586-590.

DOI: 10.1109/elinsl.2008.4570400

Google Scholar

[6] X. H. Zhu, B.X. Du, Y. Gao, Z.Z. Meng. Effects of Cross-linking Process on Crystallinity of XLPE. Insul. Mater.,. 6 (2010) 44-47.

Google Scholar