Paper Titles

The Use of Long Chain Diol for Obtaining Nickel Embedded in Silica-Carbon Matrix through the Polymeric Precursor Method
p.447

Synthesis of Nickel-Silica Nanocomposite Embedded in Amorphous Carbon through the Polymeric Precursor Method
p.453

Graphite Dispersions as a Basis for Development of High Thermal Conductivity Fluids
p.459

The Influence of a Nickel Precursor on the Synthesis of Nanosized NiO Material Using the Hydrothermal Method: Characterization and Electrocatalytic Oxidation of Methanol
p.464

Production and Characterization of Carbon Thin Films by the Magnetron Sputtering Technique
p.471

Effect of Multi Walled Carbon Nanotubes Incorporated on Refractory Castables
p.475

Study of Thermal Degradation of PEG/PVP Coating Adsorbed in Fe₃O₄ Nanoparticles
p.481

Study of Synthesis of Nanoparticulate Zinc Oxide Aiming at the Confection of Appropriated Targets for the Production of Radioisotopes
p.485

X-Ray Peak Broadening and Raman Spectroscopy Studies of Ce_0.08Fe_0.02O_2-δNanoparticles Prepared by a Sol-Gel-Based Method
p.491

HomeMaterials Science ForumMaterials Science Forum Vol. 881X-Ray Peak Broadening and Raman Spectroscopy...

X-Ray Peak Broadening and Raman Spectroscopy Studies of Ce_0.08Fe_0.02O_2-δNanoparticles Prepared by a Sol-Gel-Based Method

Article Preview

Abstract:

Fe-doped (Ce_0.9₈Fe_0.0₂O_2−δ) cerium oxide nanoparticles were synthesized by a sol-gel-based method at 1000 °C during different calcination time (1.0, 1.5, 2.0, and 2.5h). The effect of calcination time on microstructure and structural properties of the Ce_0.98Fe_0.02O_2−δ nanoparticles was studied by X-ray diffraction (XRD) and Raman spectroscopy measurements. Analysis of the XRD pattern shows that all samples exhibited a single-phase fluorite structurewith lattice parameters ranging from 0.540991 Å (1.0h) to0.540635 Å (2.5h). Raman spectroscopy also confirms that the Fe atoms successfully displaced some of the Ce atoms in the CeO₂ lattice without forming any impure phases. XRD and Raman spectroscopy results showed that both crystallite size and the particle size increased as the calcination time increased from around 36 nm (1.0h) to 64 nm (2.5h).

You might also be interested in these eBooks

The 59th Brazilian Ceramic Conference

Info:

Periodical:

Materials Science Forum (Volume 881)

Pages:

491-496

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.881.491

Citation:

Cite this paper

Online since:

November 2016

Authors:

Nilson Santos Ferreira*, A.C.B. de Oliveira, G.V.S. Mota, A.C. Cunha, Marcelo S. Silva

Keywords:

Calcination, Iron-Doped CeO₂, Microstrain, Structural, Temperature Influences

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Ooi, M. Dayana, A.A. Azlan, M.J. Abdullah: Materials Science Forum, Trans Tech Publ (2013), p.3.

[2] G.N. Gerasimov, M.I. Ikim, P.S. Timashev, V.F. Gromov, T.V. Belysheva, E.Y. Spiridonova, V.N. Bagratashvili, L.I. Trakhtenberg: Russ J Phys Chem a+ Vol. 89 (2015), p.1059.

DOI: 10.1134/s0036024415060126

[3] H.S. Kil, Y.J. Jung, J.I. Moon, J.H. Song, D.Y. Lim, S.B. Cho: J Nanosci Nanotechno Vol. 15 (2015), p.6193.

[4] S. Banerjee, P. Nag, S. Majumdar, P.S. Devi: Mater Res Bull Vol. 65 (2015), p.216.

[5] L. Zhang, H. Jiang, M. Selke, X.M. Wang: J Biomed Nanotechnol Vol. 10 (2014), p.278.

[6] N. Wang, H. Fan, S.Y. Ai: Chem Eng J. Vol. 260 (2015), p.785.

[7] Z. Wang, Z. Quan, J. Lin: Inorg Chem Vol. 46 (2007), p.5237.

[8] W.Y. Xie, B. Liu, S.H. Xiao, H. Li, Y.R. Wang, D.P. Cai, D.D. Wang, L.L. Wang, Y. Liu, Q.H. Li, T.H. Wang: Sensor Actuat B-Chem Vol. 215 (2015), p.125.

[9] J. Rodriguez-Carvajal, FullProf: A Rietveld refinement and pattern matching analysis program (Version: October 2013), in, Laboratoire Léon Brillouin (CEA-CNRS), France, (2013).

[10] B.D. Cullity, S.R. Stock: Elements of X-Ray Diffraction. (Prentice-Hall, 3rd ed. New Jersey, 2001).

[11] J.C.A. Menezes, N.S. Ferreira, L.G. Abraçado, M.A. Macêdo: J Nanosci Nanotechno Vol. 14 (2014), p.5903.

[12] G.K. Williamson, W.H. Hall,: Acta Metallurgica, 1 (1953) 22-31.

[13] P. Patsalas, S. Logothetidis, L. Sygellou, S. Kennou, Structure-dependent electronic properties of nanocrystalline cerium oxide films, Phys Rev B, 68 (2003).

DOI: 10.1103/physrevb.68.035104

[14] B. Choudhury, A. Choudhury, Ce3+ and oxygen vacancy mediated tuning of structural and optical properties of CeO2 nanoparticles, Mater Chem Phys, 131 (2012) 666-671.

DOI: 10.1016/j.matchemphys.2011.10.032

[15] I. Kosacki, V. Petrovsky, H.U. Anderson, P. Colomban, Raman spectroscopy of nanocrystalline ceria and zirconia thin films, J Am Ceram Soc, 85 (2002) 2646-2650.

DOI: 10.1111/j.1151-2916.2002.tb00509.x

[16] I.H. Campbell, P.M. Fauchet, The Effects of Microcrystal Size and Shape on the One Phonon Raman-Spectra of Crystalline Semiconductors, Solid State Commun, 58 (1986) 739-741.

DOI: 10.1016/0038-1098(86)90513-2

[17] J.E. Spanier, R.D. Robinson, F. Zheng, S.W. Chan, I.P. Herman, Size-dependent properties of CeO2-y nanoparticles as studied by Raman scattering, Phys Rev B, 64 (2001).

[18] Z.D. Dohcevic-Mitrovic, M.J. Scepanovic, M.U. Grujic-Brojcin, Z.V. Popovic, S.B. Boskovic, B.M. Matovic, M.V. Zinkevich, F. Aldinger, The size and strain effects on the Raman spectra of Ce1-xNdxO2-delta (0 <= x <= 0. 25) nanopowders, Solid State Commun, 137 (2006).

DOI: 10.2298/sos0703281r

[19] I. Kosacki, T. Suzuki, H.U. Anderson, P. Colomban, Raman scattering and lattice defects in nanocrystalline CeO2 thin films, Solid State Ionics, 149 (2002) 99-105.

DOI: 10.1016/s0167-2738(02)00104-2

[20] W.H. Weber, K.C. Hass, J.R. Mcbride, Raman-Study of Ceo2 - 2nd-Order Scattering, Lattice-Dynamics, and Particle-Size Effects, Phys Rev B, 48 (1993) 178-185.