Segregation and Precipitation Behavior of Phosphorus in a Ni-Fe-Cr Base Wrought Superalloy

Article Preview

Abstract:

The segregation and precipitation behavior of phosphoruswas studied in aNi-Fe-Cr base wroughtsuperalloy. The precipitation behavior of phosphides in the alloy contained 0.025% Pwas examined after soaking at 750-1080°C to determine the precipitation temperature range of MNP-type phosphide. The microstructuresunder these various conditions wereinvestigated by scanning electron microscope(SEM) and energy dispersive spectroscopy (EDS). The precipitation temperature of the phosphide in the alloy was determined to be in the range of 850-1040 °C and the precipitation peak temperature was around 980°C.In addition, the melting temperatureof the phosphide was determined to be between 1200 °C and 1250 °C. The current results indicate the tendency of phosphorus segregated at grain boundaries.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

150-156

Citation:

Online since:

February 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. X. Zhu, S. N. Zhang, L. Y. Xu, B. Jing, Z. Q. Hu, C. X. Shi, Superalloys with low segregation, Superalloys 1988. TMS, Warrendale, PA. (1988) 703-712.

Google Scholar

[2] W. R. Sun, S. R. Guo, D .Z. Lu, Z. Q. Hu, Effect of phosphorus on the microstructure and stress rupture properties in an Fe-Ni-Cr base superalloy, Metall. Mater. Trans. A. 28 (1997) 649-654.

DOI: 10.1007/s11661-997-0050-5

Google Scholar

[3] W. D. Cao, R. L. Kennedy, The effect of phosphorus on mechanical properties of alloy 718, Superalloys 718, 625, 706 and Various Derivatives 1994. TMS, Warrendale, PA. (1994) 463-477.

DOI: 10.7449/1994/superalloys_1994_463_477

Google Scholar

[4] M. Q. Wang, J. H. Du, Q. Deng, Z. L. Tian, J. Zhu, The effect of phosphorus on the microstructure and mechanical properties of ATI 718Plus alloy, Mater. Sci. Eng. A. 626 (2015) 382-389.

DOI: 10.1016/j.msea.2014.12.094

Google Scholar

[5] T. Alam, P. J. Felfer, M. Chaturvedi, L. T. Stephenson, M. R. Kilburn, J. M. Cairney, Segregation of B, P, and C in the Ni-based superalloy Inconel 718, Metall. Mater. Trans. A. 43 (2012) 2183-2191.

DOI: 10.1007/s11661-012-1085-9

Google Scholar

[6] L. Zheng, T. D. Xu, Q. Deng, J. X. Dong, Experimental study on the characteristic of grain-boundary segregation of phosphorus in Ni-base superalloy, Mater. Lett. 62 (2008) 54-56.

DOI: 10.1016/j.matlet.2007.04.082

Google Scholar

[7] P. W. Schilke, J. J. Pepe, R. C. Schwant, Alloy 706 metallurgy and turbine wheel application, Superalloys 718, 625, 706 and Various Derivatives 1994. TMS, Warrendale, PA. (1994) 1-12.

DOI: 10.7449/1994/superalloys_1994_1_12

Google Scholar

[8] K. A. Heck, The time-temperature-transformation behavior of alloy 706, Superalloys 718, 625, 706 and Various Derivatives 1994. TMS, Warrendale, PA. (1994) 393-404.

DOI: 10.7449/1994/superalloys_1994_393_404

Google Scholar

[9] S. Zhang, L. J. Huang, A. W. Zhang, L. X. Yu, X. Xin, W. R. Sun, X. F. Sun, Segregation of phosphorus and precipitation of MNP-type phosphide at the grain boundary of IN706 superalloy, J. Mater. Sci. Technol. 33 (2017) 187-191.

DOI: 10.1016/j.jmst.2016.09.010

Google Scholar

[10] S. Zhang, X. Xin, L. X. Yu, A. W. Zhang, W. R. Sun, X. F. Sun, Effect of phosphorus on the grain boundary cohesion and g¢ precipitation in IN706 alloy, Metall. Mater. Trans. A. 47 (2016) 4092-4103.

DOI: 10.1007/s11661-016-3495-6

Google Scholar

[11] M. Q. Wang, J. H. Du, Q. Deng, Z. L. Tian, J. Zhu, Effect of the precipitation of the η-Ni3Al0. 5Nb0. 5 phase on the microstructure and mechanical properties of ATI 718Plus, J. Alloy Compd. 701 (2017) 635-644.

DOI: 10.1016/j.jallcom.2017.01.145

Google Scholar