Acrylate and Methacrylate Guanidine-Ionic Liquids for Dissolution of Cellulose

Article Preview

Abstract:

It was shown for the first time that guanidine acrylate and methacrylate can act as ionic liquids for direct dissolution of cellulose (the solubility of dialdehyde cellulose is 27 % at the temperature of 60 °C). The conditions for the use of new ionic liquids as a dialdehyde cellulose solvent are found out: the temperature (60 °C), concentration of aqueous solution of acrylate (methacrylate) guanidine (1 mol/L).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

45-48

Citation:

Online since:

October 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yoshio Uesu N., Gomez Pineda E.A., Winkler A.A., Hechenleitner Microcrystalline cellulose from soybean husk: effects of solvent treatments on its properties as acetylsalicylic acid carrier, Internat. J. Pharmaceutics. 206 (1-2) (2000) 85-96.

DOI: 10.1016/s0378-5173(00)00532-9

Google Scholar

[2] Swatloski R.P., Spear S.K., Holbrey J.D., Rogers R.D., Dissolution of cellulose with ionic liquids, Journal of the American Chemical Society. 124 (18) (2002) 4974-4975.

DOI: 10.1021/ja025790m

Google Scholar

[3] Isupova Z.Yu., Khashirova S.Yu., Zhansitov A.A., Kvashin V.A., Hakyasheva E.V., Musaev Yu.I., Malkanduyev Yu.A., New metal-containing complexes based on guanidine-containing dialdehyde cellulose, Chemical fibers. 6 (2017) 92-95.

DOI: 10.1007/s10692-018-9916-0

Google Scholar

[4] Isupova Z.Yu., Elcheparova S.A., Zhansitov A.A., Khashirov A.A., Investigation of new composite materials based on dialdehyde cellulose and guanidine acrylate with cobalt ions, Proceedings of Kabardino-Balkarian State University. VI (2016) 41-44.

Google Scholar

[5] Khashirov A.A., Zhansitov A.A., Khashirova S.Y., Zaikov G.E., New biologically active composite materials on the basis of dialdehyde cellulose, Proceedings of the 7th International Conference on Times of Polymers (TOP) and Composites. (2014).

DOI: 10.1063/1.4876900

Google Scholar

[6] Tlupova Z.A., Zhansitov A.A., Elcheparova S.A., Khashirova S.Yu., New water-soluble bactericidal materials based on dialdehydcellulose and diallylguanidine derivatives, Fundamental research (Fundamental'nyye issledovaniya). 11-4 (2012) 970-974.

Google Scholar

[7] Remsing R.C., Swatloski R.P., Rogers R.D., Moyna G., Mechanism of cellulose dissolution in the ionic liquid 1-N-butyl-3-methylimidazolium chloride: a 13 Cand35/37 Cl NMR relaxation study on model systems, Chemical Communications. 12 (2006).

DOI: 10.1039/b600586c

Google Scholar

[8] Zhang J., Zhang H., Wu J., Zhang J., He J., Xiang J., NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids, Physical Chemistry Chemical Physics. 12(8) (2010).

DOI: 10.1039/b920446f

Google Scholar