Competitive Reactions and Formation Mechanism of Microstructures in Mg/Cu Super-Laminate Composites during Initial Hydrogenation

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Competitive reactions and formation mechanism of microstructures in Mg/Cu super-laminate composites (SLCs) during initial hydrogenation were studied. During initial hydrogenation of Mg/Cu SLCs, hydrogenation of Mg and alloying of Mg with Cu followed by hydrogenation of Mg2Cu are competitive. It is found that microstructures of Mg/Cu SLCs during initial hydrogenation have changed drastically depending on the order of hydrogenation of Mg and Mg2Cu. The microstructures of Mg/Cu SLCs after initial hydrogenation can be categorized in 3 types.

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December 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.F. Stampfer Jr., C.E. Holley Jr., J.F. Suttle, The magnesium-hydrogen system, J. Am. Chem. Soc. 82 (1960) 3504-3508.

DOI: 10.1021/ja01499a006

Google Scholar

[2] M. Danaie, C. Mauer, D. Mitlin, J. Huot, Hydrogen storage in bulk Mg-Ti and Mg-stainless steel multilayer composites synthesized via accumulative roll-bonding (ARB), Int. J. Hydrogen. Energ. 36 (2011) 3022-3036.

DOI: 10.1016/j.ijhydene.2010.12.006

Google Scholar

[3] G.F. Lima, M.R.M. Triques, C.S. Kiminami, W.J. Botta, A.M. Jorge Jr., Hydrogen storage properties of pure Mg after the combined processes of ECAP and cold-rolling, J. Alloy. Compd. 520 (2014) 287-294.

DOI: 10.1016/j.jallcom.2013.03.106

Google Scholar

[4] T. Vegge, L.S. Hedergaad-Jansen, J. Bonde, T.R. Munter, J.K. Nørskov, Trends in hydride formation energies for magnesium-3d transition metal alloys J. Alloy. Compd. 386 (2005) 1-7.

DOI: 10.1016/j.jallcom.2004.03.143

Google Scholar

[5] N. Hanada, T. Ichikawa, S. Hino, H. Fujii, Remarkable improvement of hydrogen sorption kinetics in magnesium catalysed with Nb2O5, J. Alloy. Compd. 420 (2006) 46-49.

DOI: 10.1016/j.jallcom.2005.08.084

Google Scholar

[6] H. Shao, Y. Wang, H. Xu, X. Li, Preparation and hydrogen storage properties of nanostructured Mg2Cu alloy, J. Solid State Chem. 178 (2005) 2211-2217.

DOI: 10.1016/j.jssc.2005.04.036

Google Scholar

[7] K.Tanaka, N. Takeichi, H. Tanaka, N. Kuriyama, T.T. Ueda, M. Tsukahara, H. Miyamura, S. Kikuchi, Investigation of micro-structural transition through disproportion and recombination during hydrogenation and dehydrogenation in Mg/Cu super-laminates, J. Mater. Sci. 43 (2008) 3812-3816.

DOI: 10.1007/s10853-007-2134-4

Google Scholar

[8] K.Tanaka, H.T. Takeshita, K. Kurumatani, H. Miyamura, S. Kikuchi, The effect of initial structures of Mg/Cu super-laminates on hydrogen absorption/desorption properties, J. Alloy. Compd. 580 (2013) S222-S225.

DOI: 10.1016/j.jallcom.2013.03.155

Google Scholar

[9] K. Tanaka, K. Shibata, K. Kurumatani, S. Ikeuchi, S. Kikuchi, R. Kondo, H.T. Takeshita, Formation mechanism of micro/nano-strucutures through competitive reactions in Mg/Cu super-laminate composites during initial hydrogenation, J. Alloy. Compd. 645 (2015) S72-S75.

DOI: 10.1016/j.jallcom.2015.01.196

Google Scholar

[10] K. Shibata, K. Tanaka, K. Kurumatani, Y. Nishida, R. Kondo, H.T. Takeshita, Formation of MgCu2 from MgH2 and Cu in pressurized hydrogen atmosphere, Mater. Trans. JIM 56 (2015) 785-789.

DOI: 10.2320/matertrans.m2014426

Google Scholar

[11] K. Tanaka, H.T. Takeshita, H. Shin, K. Kurumatani, T. Kiyobayashi, N. Takeichi, H. Miyamura, S. Kikuchi, Micro/nano-structural transition and hydrogen absorption mechanism in Mg/Cu super-laminate composites, Mater. Trans. JIM 55 (2014) 1122-1128.

DOI: 10.2320/matertrans.mg201413

Google Scholar

[12] K. Nonaka, T. Sakazawa, H. Nakajima, Reaction diffusion in Mg-Cu system, Mater Trans JIM 36 (1995) 1463-1466.

DOI: 10.2320/matertrans1989.36.1463

Google Scholar

[13] J. Dai, B. Jian, J. Zhang, Q. Yang, Z. Jian, H. Dong, F. Pan, Diffusion kinetics in Mg-Cu binary system, J. Phase Equilib. and Diffus. 36 (2015) 613-619.

DOI: 10.1007/s11669-015-0417-z

Google Scholar

[14] K. Tanaka, D. Nishino, K. Hayashi, S. Ikeuchi, R. Kondo, H.T. Takeshita, Formation of Mg2Cu at low temperature in Mg/Cu super-laminate composites during initial hydrogenation, Int. J. Hydrogen Energ. 42 (2017) 22502-22510.

DOI: 10.1016/j.ijhydene.2017.02.193

Google Scholar