Preparation of Poly-Hydrazide and Use as Pour Point Depressor for Heavy Oil

Article Preview

Abstract:

To develop new pour point depressor, in this work, a poly-hydrazide is designed and prepared from vegetable oil, hydrazine hydrate and epichlorohydrin. The effectiveness of the poly-hydrazides on four crude oils was tested as pour point depressants as well as paraffin inhibiters. The results showed that the highest pour point reduction depression was achieved as 9.8°C with 2000ppm PH3O-3 in 2# crude oil. Below the pour point of the crude and processed oils, paraffin crystals will deposit and tend to plug flow lines and filters. The saturated hydrocarbons were separated, and the paraffin crystal morphology studies were conducted to elucidate the mechanism of pour point reduction.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

135-140

Citation:

Online since:

January 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Chen G., Lin J., Hu W., Gu X., Du W., Zhang J., Qu C., Characteristics of a crude oil composition and its in situ waxing inhibition behavior. Fuel, 218 (2018) 213-217.

DOI: 10.1016/j.fuel.2017.12.116

Google Scholar

[2] Rafael M.P., María de Lourdes M., Beatriz Z.R., Transportation of heavy and extra-heavy crude oil by pipeline: A review. J. Petrol. Sci. & Eng. 75 (2011) 274-282.

Google Scholar

[3] Thanh, N.X., Hsieh, M., Philp, R.P., Waxes and asphaltenes in crude oils. Org. Geochem. 30 (1999) 119-132.

DOI: 10.1016/s0146-6380(98)00208-3

Google Scholar

[4] Coutinho J.A.P., Mirante F., Ribeiro J.C., Sansot J.M., Daridon J.L., Cloud and pour points in fuel blends. Fuel, 81(7) (2002) 963-967.

DOI: 10.1016/s0016-2361(01)00213-7

Google Scholar

[5] Song Y.P., Ren T.H., Fu X.S., Xu X.H., Study on the relationship between the structure and activities of alkyl methacrylate-maleic anhydride polymers as cold flow improvers in diesel fuels. Fuel Process. Technol. 86 (2005) 641-650.

DOI: 10.1016/j.fuproc.2004.05.011

Google Scholar

[6] Jorda M.R., Paraffin deposition and prevention in oil wells. J. Petrol. Technol. December (1966) 1605-1612.

Google Scholar

[7] Chen G., Yuan W., Zhang F., Gu X., Du W., Zhang J., Li J., Qu C., Application of polymethacrylate from waste organic glass as a pour point depressor in heavy crude oil, J. Petrol. Sci. Eng. 165(2018) 1049-1053.

DOI: 10.1016/j.petrol.2017.12.041

Google Scholar

[8] Wei X.M., Liu X.L., Wang W.D., Xu F.T., Overview on viscosity reducing methods of heavy oil, Specialty Petrochemicals 5 (2002) 45-48.

Google Scholar

[9] Al-Sabagh A.M., Noor El-Din M.R., Morsi R.E., Elsabee M.Z., Styrene-maleic anhydride copolymer esters as flow improvers of waxy crude oil. J. Petrol. Sci. & Eng. 65 (2009) 139-146.

DOI: 10.1016/j.petrol.2008.12.022

Google Scholar

[10] Chen G., Bai Y., Zhang J., Yuan W., Song H., Jeje A., Synthesis of new flow improvers from canola oil and application to waxy crude oil, Petrol. Sci. Technol. 34(14) (2016) 1285-1290.

DOI: 10.1080/10916466.2016.1198804

Google Scholar

[11] Jafari B. T., Golpasha R., Akbarnia H. Effect of wax inhibitors on pour point and rheological properties of Iranian waxy crude oil. Fuel Process. Technol. 89 (2008) 973-977.

DOI: 10.1016/j.fuproc.2008.03.013

Google Scholar

[12] Kuzmić A.E., Radošević M., Bogdanić G., Srića V., Vuković R., Studies on the influence of long chain acrylic esters polymers with polar monomers as crude oil flow improver additives. Fuel 87 (2008) 2943-2950.

DOI: 10.1016/j.fuel.2008.04.006

Google Scholar

[13] Gu X., Zhang F., Li Y., Zhang J., Chen S., Qu C., Chen G., Investigation of cationic surfactants as clean flow improvers for crude oil and a mechanism study, J. Petrol. Sci. Eng. 164(2018) 87-90.

DOI: 10.1016/j.petrol.2018.01.045

Google Scholar

[14] Lucas A.G., Modern petroleum technology, John Wiley and Sons, Ltd., England. (2000).

Google Scholar

[15] Manka J.S., Ziegler K.L., Factors affecting the performance of crude oil wax-control additives, SPE 67326. SPE Inc. (2001).

DOI: 10.2118/67326-ms

Google Scholar

[16] Chen G., Tang Y., Zhang J., Synthesis and application of polyaminoamide as paraffin inhibitor from vegetable oil. Chem. Cent. J. 5 (2011) 82.

Google Scholar