Degradation of Mechanically Surface Treated AZ31B Magnesium Alloy in 3.5 wt.% NaCl Solution

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Surface mechanical attrition treatment (SMAT) has so far been used as a technique for improving mechanical and tribological properties of magnesium and its alloys. However, the effects of the SMAT on corrosion and degradability of these materials are still rarely reported in open literature. In this research, the degradation behavior of AZ31B magnesium alloy after receiving the SMAT was characterized. The degradation behavior of the Mg alloy was determined from the weight losses after an immersion test for 24 h in 3.5 wt.% NaCl solution. During the test, the pH of the solution was also monitored. The results obviously showed higher corrosion rates of the Mg alloy that had been treated by using the SMAT. Interestingly, the degradation rate of the Mg alloy decreased once a longer duration of SMAT was applied. Meanwhile, the pH of NaCl solution increased up to 12 and 13.9 once the non-treated and the SMAT specimens were immersed into the solution, respectively. In addition, the energy dispersive X-ray spectroscopy (EDS) analysis confirmed the presence of corrosion products in all the Mg samples that were similar to those revealed in the literature.

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237-242

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March 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y.-h. Wei, B.-s. Liu, L.-f. Hou, B.-s. Xu, G. Liu, Characterization and properties of nanocrystalline surface layer in Mg alloy induced by surface mechanical attrition treatment, J. Alloys Comp. 452 (2008) 336-342.

DOI: 10.1016/j.jallcom.2006.11.079

Google Scholar

[2] H.Q. Sun, Y.-N. Shi, M.-X. Zhang, Wear behavior of AZ91D magnesium alloy with a nanocrystalline surface layer, Surf. Coat. Technol. 202 (2008) 2859-2864.

DOI: 10.1016/j.surfcoat.2007.10.025

Google Scholar

[3] M. Laleh, F. Kargar, Effect of surface nanocrystallization on the microstructural and corrosion characteristics of AZ91D magnesium alloy, J. Alloys Comp. 509 (2011) 9150-9156.

DOI: 10.1016/j.jallcom.2011.06.094

Google Scholar

[4] K. Lu and J. Lu, Nanostructured surface layer on metallic materials induced by surface mechanical attrition treatment, Mater. Sci. Eng. A 375-377 (2004) 38-45.

DOI: 10.1016/j.msea.2003.10.261

Google Scholar

[5] X.H. Chen, J. Lu, L. Lu, K. Lu, Tensile properties of a nanocrystalline 316L austenitic stainless steel, Scr. Mater. 52 (2005) 1039-1044.

DOI: 10.1016/j.scriptamat.2005.01.023

Google Scholar

[6] B. Arifvianto, Suyitno, M. Mahardika, P. Dewo, P.T. Iswanto, U.A. Salim, Effect of surface mechanical attrition treatment (SMAT) on microhardness, surface roughness and wettability of AISI 316L, Mater. Chem. Phys. 126 (2011) 418-426.

DOI: 10.1016/j.matchemphys.2010.10.038

Google Scholar

[7] B. Arifvianto, Suyitno, M. Mahardika, Effect of sandblasting and surface mechanical attrition treatment on surface roughness, wettability and microhardness distribution of AISI 316L, Key Eng. Mater. 462-463 (2011) 738-743.

DOI: 10.4028/www.scientific.net/kem.462-463.738

Google Scholar

[8] B. Arifvianto, Suyitno, M. Mahardika, Effects of surface mechanical attrition treatment (SMAT) on a rough surface of AISI 316L stainless steel, Appl. Surf. Sci. 258 (2012) 4538-4543.

DOI: 10.1016/j.apsusc.2012.01.021

Google Scholar

[9] N.T. Kirkland, N. Birbilis, M.P. Staiger, Assessing the corrosion of biodegradable magnesium implants: A critical review of current methodologies and their limitations, Acta Biomater. 8 (2012) 925-936.

DOI: 10.1016/j.actbio.2011.11.014

Google Scholar

[10] T.L. Nguyen, A. Blanquet, M.P. Staiger, G.J. Dias, T.B.F. Woodfield, On the role of surface roughness in the corrosion of pure magnesium in vitro, J. Biomed. Mater. Res. B 100 (2012) 1310-1318.

DOI: 10.1002/jbm.b.32697

Google Scholar

[11] R. Walter, M.B. Kannan, Influence of surface roughness on the corrosion behaviour of magnesium alloy, Mater. Des. 32 (2011) 2350-2354.

DOI: 10.1016/j.matdes.2010.12.016

Google Scholar

[12] L. Wen, Y. Wang, Y. Zhou, L.X. Guo, J.H. Ouyang, Iron-rich layer introduced by SMAT and its effect on corrosion resistance and wear behavior of 2024 Al alloy, Mater. Chem. Phys. 126 (2011) 301-309.

DOI: 10.1016/j.matchemphys.2010.11.022

Google Scholar

[13] A. Pardo, M.C. Merino, A.E. Coy, R. Arrabal, F. Viejo, E. Matykina, Corrosion behaviour of magnesium/aluminium alloys in 3.5 wt.% NaCl, Corr. Sci. 50 (2008) 823-834.

DOI: 10.1016/j.corsci.2007.11.005

Google Scholar