Materials Science Forum Vol. 956

Abstract: ZnSe quantum dots (QDs) with high intrinsic fluorescence quantum efficiency (QY) and low defect luminescence were prepared by hydrothermal method assisted with ammonia, in which the selenium powder and zinc acetate were used as Se and Zn source, and the mercaptopropionic acid (MPA) was used as ligand. Effect of ammonia amount, Zn/Se ratio, Zn/MPA ratio, and reaction time was investigated in detail in this study. The as-prepared ZnSe QDs were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-visible absorption spectrum (UV-Vis), fluorescence spectrum (PL). ZnSe QDs assisted with ammonia were sphalerite, and with emission peak in the range of 380~405nm. The optimal condition was following: Zn/Se ratio was 5, Zn/MPA ration was 0.25, reaction temperature was 110 °C and reaction time was 6 h. Under the optimal condition, ZnSe QDs with intrinsic emission QY of 47% and diameter of 3.8±0.3 nm can be obtained. The ZnSe QDs prepared in this study were expected to replace toxic Cd-related QDs in biomarkers, violet and blue light solid luminescent devices, and provide excellent parent materials for the doped ZnSe QDs system.

Abstract: Porous Ni_0.5Zn_0.5Fe_2-xCr_xO₄ (x = 0, 0.1, 0.2, 0.3, 0.4 and 0.5) ceramics were prepared by a sol-gel method using basswood as the mold. At the same time, Ni_0.5Zn_0.5Fe_2-xCr_xO₄ nanocrystalline powders were obtained by sintering the gel in oxygen at high temperature. The result of the XRD test showed that all samples presented the single-phase of the cubic spinel structure. With the increase of doping amount x, both porous ceramics and nanopowders decreased their grain size; At the same doping amount, the grain size of powder ferrites was about twice as large as that of porous ceramics. The magnetic test results showed that with the increase of doping amount x, the coercivity values increased monotonously and the saturation magnetization values decreased monotonously for all samples. Under the same doping content, the saturation magnetization values were lower but the coercivity values were higher as compared to the powder ferrites.

Abstract: During the storage process, the HTPB (hydroxyl-terminated polybutadiene) coating is continuously affected by the strain, and the microstructure and mechanical properties will be degraded, which will seriously affect the performance of composite solid propellant and solid rocket motor and cause great harm. In order to analyze the microstructure and transverse relaxation characteristics of HTPB coating under different strains, low-field ¹H NMR tests was carried out under 0%, 5%, 10% and 15% strain conditions, and the crosslinking density and transverse relaxation parameters of HTPB coating were analyzed. The results show that, the transverse relaxation decay can be divided into two segmental mobilities corresponding to two distinct transverse relaxation times. With the increase of strain, the crosslinking density shows a decline tendency, the transverse relaxation decay amplitude slows down, and the inversion curve has a tendency to move to the right. The ratio of the fast transverse relaxation time and the peak area are much larger than the slow transverse relaxation time, and the proportion of the fast relaxation time and the peak area enlarge with the increase of the strain, while the proportion of slow transverse relaxation time is reduced. With the increase of strain, there is a transition from slow transverse relaxation to fast transverse relaxation, and there is an inverse linear relationship between crosslinking density and transverse relaxation time.

Abstract: Control rod drive mechanism is one of the key main components in nuclear power plants and serves in harsh environments such as high temperature, high pressure and nuclear radiation. In order to ensure the service life and to prevent biting when assembling, some of the threads of control rod drive mechanism need to be chromium plated. In view of the high demands of the same chromium plating thickness on all surfaces of the threads of control rod drive mechanism of nuclear power and non-uniformity in chromium plating thickness of threads due to poor throwing power of chromium plating solution, five representative kinds of threads of control rod drive mechanism were selected and the plating thickness change of the root diameter, pitch diameter and crest diameter of threads was studied in this paper by means of depositing different thickness chromium coating on the surface of threads. The experimental results show that thicker coating is deposited on the crest of thread because of high current density and thinner coating is deposited on the root of thread because of low current density, which can provide reference for specification of chromium plating thickness of thread products of control rod drive mechanism.

Abstract: The comparison and analysis for the preparation of related performance indicators of the thermal protection such as the ablation resistance performance, thermal stability at high temperature and reflection ability of the heat ray of kaolin double-layer coated flexible composites were carried on. Because of the 2 d stratified structure of kaolin, and at the same time it processes the higher refractoriness, excellent resistance to the elevated temperature, the certain heat insulation and the reflection performance of the heat ray, the adequate padding of kaolin can improve the prepared thermal protection ability of double-layer coating of flexible composites.

Abstract: In this paper, the influence of texture on wear and temperature rise is studied by comparing experiments at the normal temperature. Firstly, the preparation of experimental samples and the design of experimental methods are introduced. Secondly, based on the observation and analysis of two groups of experiment, the effects of surface texture on friction coefficient, temperature rise and wear are discussed respectively. The main reasons of surface texture on temperature rise are analyzed from the energy point of view, which lays a foundation for quantitative analysis of temperature rise mechanism.

Abstract: For the purpose of expanding the application scope of HEA coating manufactured on the surface modification of materials, in this work, the Al_1.5CrFeNiTi_0.5 and Al_1.5CrFeNiTi_0.5W_0.5 HEA coatings were successfully manufactured using laser cladding method on SUS304. The microstructures and wear resistance of coatings are researched systematically. It is found that the W0 and W0.5 HEA coatings all exhibit the dendritic structure, which are constituted by BCC phases and Laves phases. With W element addition, the phase structures of W0.5 coating remain unchanged. W is dissolved in both two phases, but the solid solubility in Laves phase is higher compared to that in BCC phase. W0.5 coating with the highest microhardness of 848.34 HV, and the W0 coating with the microhardness of 811.45 HV, both of whose microhardness are four times more than that of SUS304 substrate. Among all samples, the W0.5 coating shows the optimal wear performance because of its larger content of hard second phase ( Laves phase).

Abstract: Surface self-nanocrystallization (SSNC) is a new surface modification technology to develop new materials, which can obtain nanostructured layers with nanograins on the metals surface without changing the chemical composition of the metals. In this study, SSNC was introduced from the aspects of the preparation methods, microstructural mechanism, mechanical properties, surface roughness, corrosion resistance and applications. This paper will provide experience and reference for further comprehensive researches and industrial applications of SSNC.

Abstract: The high-elastic Cu-20.0Ni-5.0Sn-0.25Zn-0.22Mn alloy was designed and prepared using a 830°C/2h+850°C/2h dual-stage homogenization annealing process. The true stress-strain curves of well annealed Cu-20.0Ni-5.0Sn-0.25Zn-0.22Mn alloy were plotted as a function of compressive temperature and strain rate. The results showed that the stage division of thermal compression deformation is temperature dependent, which involves work hardening, dynamic recovery and recrystallization stages. The maximum value of the true stress increases as the strain rate gets larger, but decreases as the deformation temperature rises. The high temperature compression deformation process of the alloy is a thermal activated process, and the corresponding constitutive equation of the true stress-strain is established.

Abstract: The thermal decomposition kinetics of polybutylene terephthalate (PBT) and flame-retardant PBT (FR-PBT) were investigated by thermogravimetric analysis at various heating rates. The kinetic parameters were determined by using Kissinger, Flynn-Wall-Ozawa and Friedman methods. The y (α) and z (α) master plots were used to identify the thermal decomposition model. The results show that the rate of residual carbon of FR-PBT is higher than that of PBT and the maximum mass loss rate of FR-PBT is lower than that of PBT. The values of activation energy of PBT (208.71 kJ/mol) and FR-PBT (244.78 kJ/mol) calculated by Kissinger method were higher than those of PBT (PBT: 195.54 kJ/mol) and FR-PBT (FR-PBT: 196.00 kJ/mol) calculated by Flynn-Wall-Ozawa method and those of PBT and FR-PBT (PBT: 199.10 kJ/mol, FR-PBT: 206.03 kJ/mol) calculated by Friedman methods. There is a common thing that the values of activation energy of FR-PBT are higher than that of PBT in different methods. The thermal decomposition reaction models of the PBT and FR-PBT can be described by Avarami-Erofeyev model (A₁).