Growth and Characterization of (E)-1-(5-Chlorothiophene-2-Yl)-3-(4- Dimethylamino)Phenyl)Prop-2-En-1-One, Novel NLO Single Crystal

C. Shruthi; V. Ravindrachary; K. Byrappa; B. Guruswamy; D. Jagadeesh Prasad; Karthik Kumara; N.K. Lokanath

doi:10.4028/www.scientific.net/MSF.962.3

Paper Titles

Growth and Characterization of (E)-1-(5-Chlorothiophene-2-Yl)-3-(4- Dimethylamino)Phenyl)Prop-2-En-1-One, Novel NLO Single Crystal
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Synthesis, Optical and Thermal Properties of 1-(4-Methoxyphenyl)-2-((5-(1-(Naphthalene-1-Yloxy)Ethyl)-[1,3,4]-Oxadiazol-2-Yl)Sulfanyl)Ethanoe - A Novel Heterocyclic Compound
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Strong Hole Self-Doping in LaMnO₃ Thin Film on a-SiO₂ Substrate Produced by Metal Organic Decomposition Method
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Preparation, Structure, Optical and Morphological Properties of Co, Ga₂O₃ Co-Doped ZnS/Se
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Effects of the Inclusion of Armchair Graphene Nanoribbons on the Electrical Conduction Properties of NN-Heterojunction 4H-6H/SiC Diodes
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HomeMaterials Science ForumMaterials Science Forum Vol. 962Growth and Characterization of...

Growth and Characterization of (E)-1-(5-Chlorothiophene-2-Yl)-3-(4- Dimethylamino)Phenyl)Prop-2-En-1-One, Novel NLO Single Crystal

Abstract:

A novel NLO compound (E)-1-(5-chlorothiophene-2-yl)-3-(4-dimethylamino) phenyl) prop-2-en-1-one has been synthesized by adopting claisen schmidt condensation reaction method and the single crystals are grown using slow solvent evaporation technique. The FT-IR spectrum confirms the various functional groups present in the compound. The crystal structure was studied by XRD method, which reveals that the compound crystallizes in Monoclinic crystal system with a space group P21/n and the corresponding lattice parameters are a = 7.595 (2) Å, b = 17.441 (4) Å, c = 10.917 (3) Å, α = 90^o, β = 102.500 (12)^o, γ = 90^o. UV-Visible spectrum shows that the crystal is transparent in the entire visible region. Refractive index of the crystal was determined using Brewster’s angle method. Thermal stability of the material was determined from TG/DTA test. The Second harmonic generation efficiency of the crystal was estimated using NLO test and the efficiency was found to be 0.84 times that of UREA.

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Materials Science Forum (Volume 962)

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3-9

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.962.3

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July 2019

Authors:

C. Shruthi, V. Ravindrachary*, K. Byrappa, B. Guruswamy, D. Jagadeesh Prasad, Karthik Kumara, N.K. Lokanath

Keywords:

Nonlinear Optics, Single Crystal, Solution Growth, Thienyl Chalcone

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