Synthesis and Characterization of Layered Double Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite

Abstract:

Zn/Al layered double hydroxide (LDH) intercalated by an anionic phenoxyherbicide guest, 3-(4-methoxypheny) propionate (MPP) were prepared by ion-exchange method. Power XRD and FTIR shows that the MPP phenoxyherbicide were successfully intercalated into the LDH interlayer. The basal spacing for Zn/Al layered double hydroxide-3-(4-methoxyphenyl) propionate nanocomposite (LDH-MPP) was 18.7 Å - 20.5 Å for 0.015 M, 0.025 M, and 0.050 M of MPP, respectively. Thermal analysis shows that the thermal stability of MPP was improved by the intercalation into the LDH interlayer. The results were also supported by elemental analysis and the surface morphology of this nanocomposite.

• Periodical: Nano Hybrids (Volume 8)
• Pages: 39-56
• DOI: https://doi.org/10.4028/www.scientific.net/NH.8.39
• Online since: December 2014
• Authors: Zuhailimuna Muda, Norhayati Hashim, Nur Hidayah Yusri, Illyas Md Isa, Azlan Kamari, Azmi Mohamed, Noorshida Mohd Ali
• Keywords: 3-(4-Methoxyphenyl) Propionate, Intercalation, Layered Double Hydroxide, Nanocomposite

References

[1] S. Aisawa, Y. Ohnuma, K. Hirose, S. Takahashi, H. Hirahara, E. Narita, Intercalation of nucleotides into layered double hydroxides by ion-exchange reaction, Appl. Clay Sci. 28 (2005) 137-145.

DOI: 10.1016/j.clay.2004.01.008

[2] X. Duan, D.G. Evans, Layered Double Hydroxides, Series Structure Bonding, Vol. 119, Springer, Berlin, 2006. Berlin.

[3] P. Nalawade, B. Aware, V.J. Kadam, R.S. Hirlekar, Layered double hydroxides: A review, J. Sci. Ind. Res. 68 (2009) 267-272.

[4] S.H. Sarijo, S.A.I.S.M. Ghazali, M.Z. Hussein, N.J. Sidek, Synthesis of nanocomposite 2-methyl-4-chlorophenoxyacetic acid with layered double hydroxide: Physicochemical characterization and controlled release properties, J. Nanopart. Res. 15 (2013).

DOI: 10.1007/s11051-012-1356-9

[5] F. Cavani, F. Trifirò, A. Vaccari, Hydrotalcite-type anionic clays: Preparation, properties and applications, Catal. Today 11 (1991) 173-301.

DOI: 10.1016/0920-5861(91)80068-k

[6] F.L. Theiss, G.A. Ayoko, R.L. Frost, Thermogravimetric analysis of selected double hydroxides, J. Therm. Anal. Calorim. 112 (2013) 649-657.

DOI: 10.1007/s10973-012-2584-z

[7] N. Hashim, M.Z. Hussein, I.M. Isa, A. Kamari, A. Mohamed, A.M. Jaafar, H. Taha, Synthesis and controlled release of cloprop herbicides from cloprop-layered double hydroxide and cloprop-zinc-layered hydroxide nanocomposites, OJIC. 4 (2014) 1-9.

DOI: 10.4236/ojic.2014.41001

[8] S. Gago, A.S. Dias, B. Monteiro, M. Pillinger, A.A. Valente, T.M. Santos, I.S. Goncalves, Synthesis and characterization of layered double hydroxides intercalated by an oxomolybdenum complex, J. Phys. Chem. Solids 67 (2006) 1011-1015.

DOI: 10.1016/j.jpcs.2006.01.019

[9] V. Rives, M.D. Arco, C. Martín, Intercalation of drugs in layered double hydroxides and their controlled release: A review, Appl. Clay Sci. (2013) DOI: 10. 1016/j. clay. 2013. 12. 002.

DOI: 10.1016/j.clay.2013.12.002

[10] M.B.A. Rahman, M. Basri, M.Z. Hussein, M.N.H. Idris, R.N.Z.R.A. Rahman, A.B. Salleh, Immobilisation of lipase from candida rugosa on layered double hydroxides of Mg/Al and its nanocomposite as biocatalyst for the synthesis of ester, Catal. Today 93-95 (2004).

DOI: 10.1016/j.cattod.2004.06.048

[11] I.M. Isa, S.N.A. Dahlan, N. Hashim, M. Ahmad, S.A. Ghani, Electrochemical Sensor for cobalt(II) by modified carbon paste electrode with Zn/Al-2(3-chlorophenoxy) propionate nanocomposite, Int. J. Electrochem. Sci. 7 (2012) 7797-7808.

DOI: 10.1016/s1452-3981(23)17955-7

[12] J. He, M. Wei, B. Li, Y. Kang, D.G. Evans, X. Duan, Preparation of layered double hydroxide, Struct. Bond. 119 (2006) 89-119.

[13] C.S. Liao, W.B. Ye, Structure and conductive properties of poly (ethylene oxide)/ layered double hydroxide nanocomposite polymer electrolytes, Electrochim. Acta 49 (2004) 4993-4998.

DOI: 10.1016/j.electacta.2004.06.018

[14] H. Nakayama, N. Wada, M. Tsuhako, Intercalation of amino acids and peptides into Mg-Al layered double hydroxide by reconstruction method, Int. J. Pharm. 269 (2004) 469-478.

DOI: 10.1016/j.ijpharm.2003.09.043

[15] Q. Tao, Y. Zhang, Z. Zhang, P. Yuan, H. He, Synthesis and characterization of layered double hydroxides with a high aspect ratio, J. Solid State Chem. 179 (2006) 708-715.

DOI: 10.1016/j.jssc.2005.11.023

[16] D. Tichit, O. Lorret, B. Coq, F. Prinetto, G. Ghiotti, Synthesis and characterization of Zn/Al layered double hydroxides obtained by the sol-gel method, Microporous Mesoporous Mater. 39 (2005) 213-220.

DOI: 10.1016/j.micromeso.2004.12.015

[17] M.Z. Hussein, N.S.S.A. Rahman, S.H. Sarijo, Z. Zainal, Herbicide-intercalated zinc layered hydroxide nanohybrid for a dual-guest controlled release formulation, Int. J. Mol. Sci. 13 (2012) 7328-7342.

DOI: 10.3390/ijms13067328

[18] N. Hashim, M.Z. Hussein, I.M. Isa, A. Kamari, A. Mohamed, Layered double hydroxide as a potential matrix for controlled release formulation for phenoxyherbicide, JSM. 4 (2012) 22-36.

[19] V. Rives, M.D. Arco, C. Martín, Intercalation of drugs in layered double hydroxides and their controlled release: A review, Appl. Clay Sci. (2013) DOI: 10. 1016/j. clay. 2013. 12. 002.

DOI: 10.1016/j.clay.2013.12.002

[20] Y. Feng, D. Li, Y. Wang, D.G. Evans, X. Duan, Synthesis and characterization of a uv absorbent-intercalated Zn-Al layered double hydroxide, Polym. Degrad. Stab. 91 (2005) 789-794.

DOI: 10.1016/j.polymdegradstab.2005.06.006

[21] M.Z. Hussein, A.H. Yahaya, Z. Zainal, L.H. Kian, Nanocomposite-based controlled release formulation of an herbicide, 2, 4-dichlorophenoxyacetate incapsulate in zinc-aluminium-layered double hydroxide, Sci. Technol. Adv. Mater. 6 (2005) 956-962.

DOI: 10.1016/j.stam.2005.09.004

[22] A.M. Bashi, M.Z. Hussein, Z. Zainal, D. Tichit, Synthesis and controlled release properties of 2, 4-dichlorophenoxy acetate-zinc layered hydroxide nanohybrid, J. Solid State Chem. 203 (2013) 19-24.

DOI: 10.1016/j.jssc.2013.03.047

[23] S. Aisawa, H. Kudo, T. Hoshi, S. Takahashi, H. Hirahara, Y. Umetsu, E. Narita, Intercalation behavior of amino acids into Zn/Al-layered double hydroxide by calcination-rehydration reaction, J. Solid State Chem. 177 (2004) 3887-3994.

DOI: 10.1016/j.jssc.2004.07.024

[24] S. Aisawa, S. Takahashi, W. Ogasawara, Y. Umetsu, E. Narita, Direct intercalation of amino acids into layered double hydroxides by coprecipitation, J. Solid State Chem. 162 (2001) 52-62.

DOI: 10.1006/jssc.2001.9340

[25] R. Marangoni, L.P. Ramos, F. Wypych, New multifunctional materials obtained by the intercalation of anionic dyes into layered zinc hydroxide nitrate followed by dispersion into poly (vinyl alcohol) (PVA), J. Colloid Interface Sci. 330 (2009).

DOI: 10.1016/j.jcis.2008.10.081

[26] T. Shokuhfar, M.R. Vaezi, S.K. Sadrnezhad, A. Shokuhfar, Synthesis of zinc oxide nanopowder and nanolayer via chemical processing, Int. J. Nanomanuf. 2 (2008) 149-162.

DOI: 10.1504/ijnm.2008.017846

[27] M.B.A. Rahman, M. Basri, M.Z. Hussein, M.N.H. Idris, R.N.Z.R.A. Rahman, A.B. Salleh, Immobilisation of lipase from candida rugosa on layered double hydroxides of Mg/Al and its nanocomposite as biocatalyst for the synthesis of ester, Catal. Today 93-95 (2004).

DOI: 10.1016/j.cattod.2004.06.048