The Influence of the Interactions between the Organic and Inorganic Species on the Structural Stabilities of Hybrids (CnH2n+1NH3)2 MCl4

L.L. Guo; L.M. Chen; H.X. Liu; Shi Xi Ouyang

doi:10.4028/www.scientific.net/SSP.111.143

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The Influence of the Interactions between the Organic and Inorganic Species on the Structural Stabilities of Hybrids (C_nH_2n+1NH₃)₂ MCl₄

Abstract:

This paper focuses on the influence of interactions between different species in hybrids (CnH2n+1NH3)2MCl4 (M = Mn, Cu; n =2,4,6,8,10) on the structural stabilities. DSC-TG curves were used to find out the onset and the end decomposition temperatures. The results show that the hybrids of M =Cu start to decompose at about 210 centigrade degrees, average 25 centigrade degrees lower than that of M=Mn. The end temperatures of M=Cu are also lower. This suggests that in this case the thermal stabilities of the hybrids would be governed by the interactions between the organic and inorganic species and are little affected by weak Van de Waals interactions between the organic and organic species.

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Periodical:

Solid State Phenomena (Volume 111)

Pages:

143-146

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.111.143

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Online since:

April 2006

Authors:

L.L. Guo, L.M. Chen, H.X. Liu, Shi Xi Ouyang

Keywords:

Layered Perovskite, Organic-Inorganic Hybrid, Thermal Stability

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References

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