Effect of Silicon Sources on Self-Assembly in Acidic Environment and Impact on Morphology and Grain Size of Mesoporous Material

Article Preview

Abstract:

Alkaline hydrothermal process with using cetyl-trimenthylammonium bromide as template is typical method to prepare MCM-41 mesoporous material. Synthesis in acid media was seldom researched deeply. With cheap inorganic water glass, effect of different silicon sources on self-assembly in acid media was investigated. Not like typical MCM-41 mesoporous materials, it is found that results of analysis are a little different and morphology of mesoporous materials synthesized in acid media does not rely on silicon sources, regardless of organic or inorganic silicon source. It is also noticed that nanometer granule of mesoporous material can be directly made by simply adjusting water dosage, which open up a new way for preparing nanometer material by self-assembly.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volumes 121-123)

Pages:

465-468

Citation:

Online since:

March 2007

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Q. S. Huo, D. I. Margolese, G.D. Stucky, et. al.: Nature 368 (1994), p.317.

Google Scholar

[2] Q. S. Huo, D. I. Margolese, G.D. Stucky: Chem. Mater. 8 (1996) , p.1147.

Google Scholar

[3] D. Zhao, J. Feng, N. Melosh, G. H. Fredrickson, B. F. Chemlka, G. D. Stucky: Science 279 (1998), p.48.

Google Scholar

[4] D. Zhao, Q. Huo, J. Feng, B. F. Chemlka, G. D. Stucky: J. Am. Chem, Soc. 120 (1998) , p.6024.

Google Scholar

[5] L X. iu, B. Tian, C. Yu, F. Gao, S. Xie, B. Tu, R. Che, L. Peng, D. Zhao: Angew. Chem. Int. Ed Engl. (2002) , p.413876.

Google Scholar

[6] C. Yu, Y. Yu, D. Zhao: Chem. Commun. (2000) , p.575.

Google Scholar

[7] L.Z. Wang, J.L. Shi, et. al.: Journal of Inorganic Material , 14 (1999) , p.558.

Google Scholar

[8] H.M. Wei, N.Y. He, et. al.: Natural Science Journal of Xiangtan University 22 (2000) , p.49.

Google Scholar

[9] P. T. Tanev, M. Chibwe, T. Pinnavaia, et. al.: Nature 368(1994) , p.321.

Google Scholar

[10] X.Y. Chen, L.M. Huang, G.Z. Ding, et. Al.: Cata. Lett. 44 (1997) , p.123.

Google Scholar

[11] S. J. Gregg, Sing KSW: Adsorption, Surface Area and Porosity, 2nd ed. Academic Press, London, (1982).

Google Scholar

[12] K. Huang, R.Q. Han: Solid Physics, Beijing: High Edu. Press, 1988, p.126.

Google Scholar