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Paper Titles
Foreword
Molecular Mechanism of Water Oxidation Reaction at Photo-Irradiated TiO2 and Related Metal Oxide Surfaces
p.1
Development of Visible-Light-Driven TiO2 and SrTiO3 Photocatalysts Doped with Metal Cations for H2 or O2 Evolution
p.29
Investigations of Photo-Excited TiO2 Based on Time Resolved Microwave Conductivity and Oxygen Isotopic Exchange
p.41
Surface Modified Titania Visible Light Photocatalyst Powders
p.49
Titanium Dioxide Photocatalyst - Unresolved Problems
p.77
Tayloring the Photocatalytical Activity of Anatase TiO2 Thin Film Electrodes by Three-Dimensional Mesoporosity
p.91
Surface Science Approach to Photochemistry of TiO2
p.115
Composite Titanium Dioxide Photocatalysts and the "Adsorb & Shuttle" Approach: A Review
p.135

Development of Visible-Light-Driven TiO2 and SrTiO3 Photocatalysts Doped with Metal Cations for H2 or O2 Evolution

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Abstract:

This review paper represents photocatalytic properties of metal cation-doped TiO2 (rutile) and SrTiO3 photocatalysts for O2 evolution from an aqueous silver nitrate solution and H2 evolution from an aqueous methanol solution under visible light irradiation. Photocatalytic activities for the O2 evolution of Cr/Sb and Rh/Sb-codoped TiO2 are strongly dependent on the codoping ratio and the amount of doped chromium and rhodium. The codopant controls the oxidation number of doped chromium and rhodium. Rh-doped SrTiO3 in which the doped Rh species possesses a reversible redox property is active for the H2 evolution reaction under visible light irradiation. Overall water splitting under visible light irradiation proceeds with Z-scheme photocatalyst systems consisting of the Rh-doped SrTiO3 as a H2 evolution photocatalyst combined with BiVO4 as an O2 evolution photocatalyst and an Fe3+/Fe2+ electron mediator.

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Periodical:

Solid State Phenomena (Volume 162)

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29-40

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.162.29

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Online since:

June 2010

Authors:

Ryo Niishiro, Akihiko Kudo

Keywords:

Co-Doping, Doping, Hydrogen Evolution, Oxygen Evolution, Photocatalytic, Visible-Light Response, Water Splitting

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