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Y-Type Hexaferrites: Structural, Dielectric and Magnetic Properties

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Abstract:

This paper attempts to provide a historical survey of structure of various types of hexaferrites. It provides information about synthesis, characterization, structural, magnetic and dielectric properties of Y-type hexagonal ferrites using various chemical routes. We have prepared a series of cobalt doped Sr2Cu2-xCoxFe12O22 (x = 0.0 to 1.0) hexaferrites using a wet chemical co-precipitation technique. The prepared hexaferrite precursors were calcined at 950 °C for 4 hours in a furnace and slowly cooled to room temperature. The crystal structure of Y-type hexaferrites is rather complicated. The chemical and structural changes were examined in detail by X-ray diffraction (XRD), Differential scanning calorimetry (DSC), Scanning electron microscopy (SEM), and Fourier transform infra-red (FTIR) spectroscopy. X-ray diffraction studies showed that sintering temperature as low as 950°C was sufficient to produce a single-phase Y-type hexaferrite material. The dielectric measurements were carried out over the frequency range of 100 Hz to 2 MHz at room temperature using an LCR meter to study the variation of dielectric constant and loss tangent with frequency. The magnetic properties of hexaferrite samples were investigated using a vibration sample magnetometer (VSM), and a superconducting quantum interference device (SQUID) magnetometer in the temperature range 30K to 200K. A change from ferromagnetic state to super paramagnetic state has been observed in Co doped Sr2Cu2-xCoxFe12O22 (x= 0.6 to 1.0) hexaferrite. The novel applications of all types of hexaferrite materials have been described.

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Periodical:

Solid State Phenomena (Volume 189)

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209-232

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https://doi.org/10.4028/www.scientific.net/SSP.189.209

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June 2012

Authors:

Rajshree B. Jotania, Hardev Singh Virk

Keywords:

Characterization, Dielectric Property, Hexaferrites, Magnetic Property, Synthesis, Y-Type Hexaferrites

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