Thermal Expansion, Oxygen Non-Stoichiometry and Diffusion Mobility in some Ferrites-Nickelites

Vladimir Vashook; Jean Rebello; J.Y. Chen; Leonid Vasylechko; Dmytro Trots; J. Zosel; Ulrich Guth

doi:10.4028/www.scientific.net/SSP.200.86

Paper Titles

Experimental Study of the Surface of Steel 15Kh13MF after the Nanosecond Laser Shock Processing
p.60

Interface Phenomena
p.69

Crystallization Paths and Microstructures in Ternary Oxide Systems with Stoichiometric Compounds
p.73

The Size Factor as Criterion for the Formation of M₁₄Cu₂₄O₄₁ Phases
p.79

Thermal Expansion, Oxygen Non-Stoichiometry and Diffusion Mobility in some Ferrites-Nickelites
p.86

Phase and Structural Behaviour in the NdAlO₃-EuAlO₃ System
p.93

Phase and Crystal Structure Behaviour of Bi_1-xR_xFeO₃ (R = Er, Tm, Yb)
p.100

Defect Structure of Nanosized Zirconium Oxide Powders Doped with Y₂O₃, Sc₂O₃, Cr₂O₃
p.108

Electronic Structure and Luminescence Spectroscopy of M'Bi(MoO₄)₂ (M' = Li, Na, K), LiY(MoO₄)₂ and NaFe(MoO₄)₂ Molybdates
p.114

HomeSolid State PhenomenaSolid State Phenomena Vol. 200Thermal Expansion, Oxygen Non-Stoichiometry and...

Thermal Expansion, Oxygen Non-Stoichiometry and Diffusion Mobility in some Ferrites-Nickelites

Abstract:

Crystal structure,thermal expansion, oxygen non-stoichiometry, electrical conductivity and diffusion characteristics of two analogous LaFe_0.7Ni_0.3O_3‑_d and PrFe_0.7Ni_0.3O_3‑_d compositions were investigated depending on temperature (201000 °C) and oxygen partial pressure (0.6–21000 Pa). The found oxygen diffusion and oxygen exchange coefficients for the both compositions at similar conditions are near to each other and varied in the range of 110^‑7110^‑5 cm²s^‑1 and 510^‑6110^‑4 cms^‑1, respectively.

You might also be interested in these eBooks

Oxide Materials for Electronic Engineering - Fabrication, Properties and Applications

View Preview

Info:

Periodical:

Solid State Phenomena (Volume 200)

Pages:

86-92

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.200.86

Citation:

Cite this paper

Online since:

April 2013

Authors:

Vladimir Vashook, Jean Rebello, J.Y. Chen, Leonid Vasylechko, Dmytro Trots, J. Zosel, Ulrich Guth

Keywords:

Chemical Diffusion, Electrical Conductivity, Mixed Nickelites-Ferrites, Oxygen Exchange Index, Oxygennon-Stoichiometry, Thermal Expansion

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] E.P. Murray, M.J. Sever, S.A. Barnett, Electrochemical performance of (La, Sr)(Co, Fe)O3- (Ce, Gd)O3 composite cathodes, Solid State Ionics 148 (2002) 27-34.

DOI: 10.1016/s0167-2738(02)00102-9

Google Scholar

[2] S. Hashimoto, K. Kammer, F.W. Poulsen, M. Mogensen, Conductivity and electrochemical characterization of PrFe1−xNixO3−δ at high temperature, J. Alloys Compd. 428 (2007) 256261.

DOI: 10.1016/j.jallcom.2006.02.068

Google Scholar

[3] R. Kumar, R. Choudhary, M. Ikram, D. Shukla, S. Mollah, P. Thakur, K. Chae, B. Angadi, W. Choi, Structural, electrical, magnetic, and electronic structure studies of PrFe1−xNixO3 (x≤0. 5), J. App. Phys. 102 (2007) 073707-073715.

DOI: 10.1063/1.2786895

Google Scholar

[4] W.R. Cannon, M. Yoshimura, J. Mizusaki, T. Sasamoto, R.L. Pober, I. Hart, H.K. Bowen, and J.F. Louis, Properties and Test Results of Super-Hot Wall Electrode Materials, Proc. 17th Symp. Eng. Aspects of MHD, Stanford University, March. (1978) 17.

Google Scholar

[5] J. Mizusaki, W.R. Cannon, and H.K. Bowen, Electrochemical Degradation of Ceramic Electrodes, J. Am. Ceram. Soc. 63 (1980) 391-397.

DOI: 10.1111/j.1151-2916.1980.tb10198.x

Google Scholar

[6] R. Chiba, F. Yoshimura, Y. Sakurai, An investigation of LaNi1-xFexO3 as a cathode material for solid oxide fuel cells, Solid State Ionics 124 (1999) 281-288.

DOI: 10.1016/s0167-2738(99)00222-2

Google Scholar

[7] J. -Y. Chen, J. Rebello, V. Vashook, D.M. Trots, S. -R. Wang, T. -L. Wen, J. Zosel, U. Guth, Thermal stability, oxygen non-stoichiometry and transport properties of LaNi0. 6Fe0. 4O3, Solid State Ionics 192 (2011) 424-430.

DOI: 10.1016/j.ssi.2010.04.019

Google Scholar

[8] J. Rebello, V. Vashook, D. Trots, U. Guth, Thermal stability, oxygen non-stoichiometry, electrical conductivity and diffusion characteristics of PrNi0. 4Fe0. 6O3−δ, a potential cathode material for IT-SOFCs, J. Power Sources 196 (2011) 3705-3712.

DOI: 10.1016/j.jpowsour.2011.01.003

Google Scholar

[9] M. Knapp, C. Baehtz, H. Ehrenberg and H. Fuess, The synchrotron powder diffractometer at beamline B2 at HASYLAB/DESY: status and capabilities, J. Synchrotron Rad. 11 (2004) 319-327.

DOI: 10.1107/s0909049504009367

Google Scholar

[10] M. Knapp, V. Joco, C. Baehtz, H. -H. Brecht, A. Berghaeuser, H. Ehrenberg, H. von Seggern and H. Fuess, Position-sensitive detector system OBI for High Resolution X-Ray Powder Diffraction using on-site readable image plates, Nucl. Instrum. Methods A 521 (2004).

DOI: 10.1016/j.nima.2003.10.100

Google Scholar

[11] L.G. Akselrud, P. Yu. Zavalij, Yu. Grin, V.K. Pecharsky, B. Baumgartner, E. Wölfel, Use of the CSD Program Package for Structure Determination from Powder Data, Mater. Sci. Forum 133-136 (1993) 335-342.

DOI: 10.4028/www.scientific.net/msf.133-136.335

Google Scholar

[12] V. Vashook, L. Vasylechko, J. Zosel, W. Gruner, H. Ullmann, U. Guth, Crystal structure and electrical conductivity of lanthanum-calcium chromites-titanates La1-xCaxCr1-yTiyO3-δ (x=0-1, y=0-1), J. Solid State Chem. 177 (2004) 3784-3794.

DOI: 10.1016/j.jssc.2004.07.007

Google Scholar

[13] I. Yasuda, M. Hishinuma, Electrical Conductivity and Chemical Diffusion Coefficient of Strontium-Doped Lanthanum Manganites, J. Solid State Chem. 123 (1996) 382-390.

DOI: 10.1006/jssc.1996.0193

Google Scholar