Effect of Isovalent Substitution on the Formation and Luminescence Properties of Solid Solutions BiPXV1-XO4 Doped with Europium (III)

Konstantin L. Bychkov; Katerina V. Terebilenko; Rostyslav P. Linnik; Nikolay S. Slobodyanik

doi:10.4028/www.scientific.net/SSP.230.62

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HomeSolid State PhenomenaSolid State Phenomena Vol. 230Effect of Isovalent Substitution on the Formation...

Effect of Isovalent Substitution on the Formation and Luminescence Properties of Solid Solutions BiP_XV_1-XO₄ Doped with Europium (III)

Abstract:

Solid solution BiP_0.9V_0.1O₄ from BiP_XV_1-XO₄ system has been synthesized by solid state synthesis at 973 K. It has been shown that the phosphate-vanadate can be prepared as a single phase for x =0.9, while higher degree of (P/V)O₄ substitution in BiVO₄ has not been detected for the range studied. The substitution peculiarities have been investigated by X-Ray powder diffraction, infrared and photoluminescence spectroscopy. The luminescence spectrum of BiP_XV_1-XO₄:Eu³⁺ solid solution reveal intensive photoluminescence lines related to f-f electronic transitions in Eu³⁺ ions.

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Solid State Phenomena (Volume 230)

Pages:

62-66

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.230.62

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Online since:

June 2015

Authors:

Konstantin L. Bychkov*, Katerina V. Terebilenko, Rostyslav P. Linnik, Nikolay S. Slobodyanik

Keywords:

Isovalent Substitution, Phosphates, Solid State Synthesis, Vanadate

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