Investigation of the Ga Complexation Behaviour of the Siderophore Desferrioxamine B

Rohan Jain; Francesca Cirina; Peter Kaden; Katrin Pollmann

doi:10.4028/www.scientific.net/SSP.262.643

Paper Titles

Biodegradation of Thiocyanate and Cyanide in CIL Leaching Waste’s Liquid Phase
p.626

Utilization of Fe-Oxide Composites for as Removal from Aqueous Solutions
p.630

Intensification of Arsenic and Zinc Mobilization by Combination of Bio-Chemical Leaching with EDTA in the Soil and Sediment Bioremediation
p.634

Comparative Analysis of the Sulfate-Reducing Performance and Microbial Colonisation of Three Continuous Reactor Configurations with Varying Degrees of Biomass Retention
p.638

Investigation of the Ga Complexation Behaviour of the Siderophore Desferrioxamine B
p.643

Removal of Arsenic from Aqueous Solution by Aeromonas hydrophila
p.647

In Situ Bioremediation of Tailings by Sulfate Reducing Bacteria and Iron Reducing Bacteria: Lab- and Field-Scale Remediation of Sulfidic Mine Tailings
p.651

Immobilization of Arsenic by a Thermoacidophilic Mixed Culture with Pyrite as Energy Source
p.656

Genomic Characterization of the Arsenic-Tolerant Actinobacterium, Rhodococcus erythropolis S43
p.660

HomeSolid State PhenomenaSolid State Phenomena Vol. 262Investigation of the Ga Complexation Behaviour of...

Investigation of the Ga Complexation Behaviour of the Siderophore Desferrioxamine B

Abstract:

Gallium (Ga) is a critical element for the electronic industry, however, its long-term supply is not assured. Thus, the recovery of Ga from industrial wastewaters is important. Selective sorption is a recommended technology for the recovery of Ga from industrial wastewaters, however, selective sorbents are elusive. Desferrioxamine B (DFOB), a hydroxomate siderophore that is known to be highly selective towards Fe³⁺, is tested for its ability to complex Ga. This study demonstrated that DFOB forms 1:1 complex with Ga and the maximum Q_e-Ga is 124.4 mg of Ga complexed per g of DFOB. Further, the complexation mechanism of Ga³⁺ and Fe³⁺ with DFOB is similar, as indicated by NMR, suggesting that the selectivity of DFOB towards Fe³⁺ will be extended to Ga³⁺ as well. Thus, DFOB seems to be a suitable candidate for the sorption of Ga from industrial wastewaters.

You might also be interested in these eBooks

22nd International Biohydrometallurgy Symposium

View Preview

Info:

Periodical:

Solid State Phenomena (Volume 262)

Pages:

643-646

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.262.643

Citation:

Cite this paper

Online since:

August 2017

Authors:

Rohan Jain*, Francesca Cirina, Peter Kaden, Katrin Pollmann

Keywords:

Complexation, HPLC, NMR, Selective, Siderophore

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] R.R. Moskalyk, Gallium: The backbone of the electronics industry, Miner. Eng. 16 (2003) 921–929.

DOI: 10.1016/j.mineng.2003.08.003

Google Scholar

[2] R. Moss, E. Tzimas, H. Kara, P. Willis, J. Koorosh, Critical Metals in Strategic Energy Technologies - Assessing Rare Metals as Supply-Chain Bottlenecks in Low-Carbon Energy Technologies, JRC report to EC, Publications Office of the European Union, (2011).

DOI: 10.1016/j.enpol.2012.12.053

Google Scholar

[3] Z. Zhao, Y. Yang, Y. Xiao, Y. Fan, Recovery of gallium from Bayer liquor: A review, Hydrometallurgy. 125–126 (2012) 115–124.

DOI: 10.1016/j.hydromet.2012.06.002

Google Scholar

[4] M. Hua, S. Zhang, B. Pan, W. Zhang, L. Lv, Q. Zhang, Heavy metal removal from water/wastewater by nanosized metal oxides: a review., J. Hazard. Mater. 211–212 (2012) 317–31.

DOI: 10.1016/j.jhazmat.2011.10.016

Google Scholar

[5] R.C. Hider, X. Kong, Chemistry and biology of siderophores., Nat. Prod. Rep. 27 (2010) 637–657.

DOI: 10.1039/b906679a

Google Scholar

[6] B.J. Hernlem, L.M. Vane, G.D. Sayles, The application of siderophores for metal recovery and waste remediation: Examination of correlations for prediction of metal affinities, Water Res. 33 (1999) 951–960.

DOI: 10.1016/s0043-1354(98)00293-0

Google Scholar

[7] B.L. Su, N. Moniotte, N. Nivarlet, L.H. Chen, Z.Y. Fu, J. Desmet, J. Li, Fl-DFO molecules@mesoporous silica materials: Highly sensitive and selective nanosensor for dosing with iron ions, J. Colloid Interface Sci. 358 (2011) 136–145.

DOI: 10.1016/j.jcis.2011.02.050

Google Scholar

[8] B. Borgias, A.D. Hugi, Raymond Kenneth N., isomerization and solution structures of Desferrioxamine B complexes of Al3+ and Ga3+, Inorg. Chem. 28 (1989) 3538–3545.

DOI: 10.1021/ic00317a029

Google Scholar

[9] S. Konetschny-Rapp, H. Huschka, G. Winkelmann, G. Jung, High-performance liquid chromatography of siderophores from fungi, Biol. Met. 1 (1988) 9–17.

DOI: 10.1007/bf01128012

Google Scholar

[10] L. Zhang, Y. Zhu, H. Li, N. Liu, X. Liu, X. Guo, Kinetic and thermodynamic studies of adsorption of gallium(III) on nano-TiO2, Rare Met. 29 (2010) 16–20.

DOI: 10.1007/s12598-010-0003-9

Google Scholar