The Effect of Calcination Time on Crystallite Size of LiMn1.8Ni0.2O4 Cathode Materials

Michelle Matius; Norlida Kamarulzaman; Mohd Sufri Mastuli; Nor Syamilah Syamimi Mohd Abdillih; Kelimah Elong

doi:10.4028/www.scientific.net/SSP.307.136

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The Effect of Calcination Time on Crystallite Size of LiMn_1.8Ni_0.2O₄ Cathode Materials

Abstract:

Spinel LiMn₂O₄ is one of the promising cathode materials used in commercial Li-ion batteries. In this study, Ni was partially substituted in order to give the material LiMn_1.8Ni_0.2O₄, which was successfully synthesized using a self-propagating combustion (SPC) method. Results from Simultaneous Thermogravimetric Analysis (STA) show the small mass loss about 4.6%. The precursor then was calcined at temperature of 800 °C for 24 h, 48 h and 72 h. X-Ray Diffraction (XRD) confirms that the final products are pure and single phase with no impurities present. The morphology and crystallite size of pure samples are examined using Field Emission Scanning Electron Microscope (FESEM). The result shows that all the materials consist of crystalline particles with smooth surface and polyhedral shaped materials.

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Solid State Phenomena (Volume 307)

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136-140

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.307.136

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July 2020

Authors:

Michelle Matius, Norlida Kamarulzaman, Mohd Sufri Mastuli, Nor Syamilah Syamimi Mohd Abdillih, Kelimah Elong

Keywords:

Calcination, Cathode Material, Li-Ion Batteries, LiMn₂O₄

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References

[1] B.N, and D.H, Review on synthesis, characterizations, and electrochemical properties of cathode materials for lithium ion batteries, J. Material Science & Eng. 5 (2016) 1-21.

Google Scholar

[2] X. Li, Y. Xu and C. Wang, Suppression of Jahn-Teller distortion of spinel LiMn2O4 cathode, Journal of Alloys and Compounds. 6 (2002) 507-512.

DOI: 10.1016/j.jallcom.2008.12.081

Google Scholar

[3] B. Scrosati, L. Sapienza and P.A Aldo, Recent advances in lithium ion battery materials, ElectrochimicaActa. 45 (2000) 2461-2466.

DOI: 10.1016/s0013-4686(00)00333-9

Google Scholar

[4] J. Huang, F. Yang, Y. Guo, C. Peng, H. Bai, J. Peng and J. Guo, LiMgxMn2-x (x ≤ 0.10) cathode materials with high rate performance prepared by molten-salt combustion at low temperature, Ceramics International. 41 (2005) 9662-9667.

DOI: 10.1016/j.ceramint.2015.04.032

Google Scholar

[5] W. Xu, H. Bai, Q. Li, T. Feng, J. Guo, L. Feng, C. Su, W. Bai and X. Liu, Preparation and electrochemical performance of nano-LiNi0.05Mn1.95O4 cathode materials by a low temperature molten-salt combustion method, International Journal of Electrochemical Science. 12 (2017) 9758-9773.

DOI: 10.20964/2017.10.11

Google Scholar

[6] S. Jayapal, R. Mariappan, S. Sundar and S. Piraman, Electrochemical behavior of LiMn2-X-YTixFeYO4 as cathode material for Lithium ion batteries, Journal of Electroanalytical Chemistry. 720-721 (2014) 58-63.

DOI: 10.1016/j.jelechem.2014.03.016

Google Scholar

[7] N.F. Yahya, N. Kamarulzaman, K. Elong, N.A.M. Mokhtar, A.F.M. Fadzil, N.H. Zainol, A. Azahidi, Synthesis of LiMn1.9Ti0.1O4,, AIP Conference Proceedings. Volume 1877 (2017), p.040008.

DOI: 10.1063/1.4999874

Google Scholar

[8] N. Kamarulzaman, N. Kamarudin, R. Rusdi, K. Elong, M.H. Jaafar, Synthesis and Electrochemical Behaviour of Lithium Manganese Vanadates,, Advanced Materials Research, Vol. 545 (2012) pp.195-198.

DOI: 10.4028/www.scientific.net/amr.545.195

Google Scholar

[9] A.A. Rahman, R. Rusdi, K. Elong and N. Kamarulzaman, Synthesis and Electrochemical Behaviour of LiMn(2-x)ZnxO4 Cathode Materials,, Advanced Materials Research, Vol. 545 (2012) pp.199-203.

DOI: 10.4028/www.scientific.net/amr.545.199

Google Scholar

[10] K. Elong, N. Kamarulzaman, R. Rusli, N. Badar, M.H. Jaafar, Solid Solutions of LiCo1-xNixO2 (x=0,0.1,…,0.9) Obtained via a Combustion Synthesis Route and Their Electrochemical Characteristics. ISRN Condensed Matter Physics, Vol. 2013 (2013) 2.

Google Scholar