Synthesis and Luminescence Properties of Rare Earth (Eu, Tb) Complexes of Octanoylphenylalanine

Article Preview

Abstract:

Tb (oct-phe)3·H2O and Eu (oct-phe)3·H2O were prepared by chemical reaction in solution. The molecular formula of the complex was determined by elemental analysis and FT-IR. The optical properties of rare earth complexes were further tested by ultraviolet-visible-infrared absorption measurements. The results show that the optical absorption performance is better in the wavelength range of 200-300 nm. The luminescent properties of the rare earth complexes in the wavelength range of 450-750 nm were tested. It was found that the rare earth (Eu, Tb) complexes of octylphenylalanine have good luminescent properties.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 310)

Pages:

22-28

Citation:

Online since:

September 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. K. Zhang, G. Naren, Y. Zhang, et al. Research progress on rare earth amino acid complexes. Chinese Rare Earths, 40 (2019) 127-142.

Google Scholar

[2] J Kido, K Nagai, Y Okamoto, et al. Electroluminescence from polysilane film doped with europium complex. Chemistry Letters, 235 (1991) 1267-1271.

DOI: 10.1246/cl.1991.1267

Google Scholar

[3] Kido J, Hayase H, Hongaw K. Bright red light emitting organic electroluminescent devices having a europium complex as an emitter. Applied Physics Letters, 65 (1994) 2124-2128.

DOI: 10.1063/1.112810

Google Scholar

[4] Q. P. Fan, Y. Liu, Zh. R. Hao, et al. Polymer light-emitting devices based on europium (III) complex with 11-bromo-dipyrido[3, 2-a: 2', 3'-c]phenazine. Science China Chemistry, 58 (2015) 1152-1158.

DOI: 10.1007/s11426-015-5404-z

Google Scholar

[5] F. L. Hong, T. F. Zhu, M. Guo, et al. Synthesis, structure and luminescence property of europium complex coordinated by ionic liquid with phosphoryl functionality. Journal of the Chinese Rare Earth Society, 4 (2014) 466-472.

Google Scholar

[6] G. Naren, B. Q. Zhou, X. Tian, et al. Preparation and Characterization of Capryloyl Alanine Europium and Terbium Complexes. Chinese Rare Earths. 37(2016) 27-33.

Google Scholar

[7] G. Naren, E. Hua, B. G. Menggen, et al. Preparation and performance characterization of amino acid magnesium, calcium, zinc complex. Journal of Inner Mongolia University, 45 (2014) 151-157.

Google Scholar

[8] G. Naren, L. H. Bao, J. K. Zhang, et al. Effect of Moisture Content on the Diverse Structure State of the Octanoyl Alanine Metal (Mg, Ca) Complexes. Solid State Phenomena. 288 (2019) 1-8.

DOI: 10.4028/www.scientific.net/ssp.288.1

Google Scholar

[9] J. F. Li, J. P. Wang, J. H. Sun, et al. Grafting of derivatives of naphthalic anhydride onto amine-modifed surfaces of dense nanosilica and their fractal features for luminescent performance. Journal of Luminescence. 206 (2019) 547-553.

DOI: 10.1016/j.jlumin.2018.10.094

Google Scholar

[10] Y. C. Ning. Structural Identification of Organic Compounds and Organic Popper Science. (2) 2002 485-498.

Google Scholar

[11] X. Sun, G. Ding, G. Mo, et al. Dilatancy signatures of amorphous plasticity probed by X-ray synchrotron radiation. Intermetallics. 107 (2019) 34-38.

DOI: 10.1016/j.intermet.2019.01.009

Google Scholar

[12] G. Naren, J. K. Zhang, Y. Zhang, et al. Fluorescence properties of acyl alaninato europium complexes. Journal of Inner Mongolia Agricultural University (Natural Science Edition). 39 (2018) 84-89.

Google Scholar

[13] C. Yang. Photoluminescence Properties of Rare Earth Organic Complexes and Their Composites. Beijing University of Chemical Technology. (2006).

Google Scholar

[14] Z. X. Zhang. Organic Spectrum Analysis. People's Health Publishing House. Chemical Industry Press. 1 (2009) 1-39.

Google Scholar

[15] G. A. Parolin, A. S. Menandro, C. G. Barbosa, et al. The effect of UV light on luminescent blends. Synthetic Metals. 253 (2019) 94-99.

DOI: 10.1016/j.synthmet.2019.05.005

Google Scholar

[16] Y. Zhang, Y. Q. Feng, J. H. Wang, et al. Moiety effect on the luminescent property of starshaped triphenylamine (TPA) derivatives as mechanochromic materials. RSC Advances. 7 (2017) 35672–35680.

DOI: 10.1039/c7ra03123h

Google Scholar