A New Synthesis Method for Lithium Tantalate Charge Doped with Rare-Earth Elements

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Abstract:

A method was developed for synthesis of a single phase lithium tantalate charge doped by rare earth elements (TR) from highly pure solutions containing tantalum. The method is based on obtaining and thermal treatment of citrate precursor containing Li, Ta and TR. Charge samples were obtained due to suggested technological scheme; the dopant had given concentration and was chemically uniformly distributed. The charge can be applied both in single crystal growing technology and at obtaining of functional ceramics based on LiTaO3:TR.

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Solid State Phenomena (Volume 310)

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53-57

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September 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Lines, A. Glass, Principles and applications of ferroelectrics and related materials, Clarendon Press, Oxford, (1977).

Google Scholar

[2] Yu. Kuzminov, Lithium niobate and tantalate - materials for nonlinear optics, Nauka, Moscow, (1975).

Google Scholar

[3] T. Volk, M. Wöhlecke, Lithium Niobate. Defects, photorefraction and ferroelectric switching, Springer-Verlag, Berlin, (2008).

DOI: 10.1007/978-3-540-70766-0

Google Scholar

[4] P. Ferraro, S. Grilli, P. De Natale, Ferroelectric crystals for photonic applications, Springer-Verlag, Berlin-Heidelberg, (2009).

Google Scholar

[5] D. Sinclair, A. West, Electrical properties of a LiTaO3 single crystal, Physical Review B 39 (1989) 13486-13492.

Google Scholar

[6] Y. Jinfeng, M. Qianhui, S. Jifang, Preparation and characterization of thick stoichiometric lithium tantalate crystals by vapor transport equilibration method, Materials Letters 232 (2018) 150–152.

DOI: 10.1016/j.matlet.2018.08.105

Google Scholar

[7] T. Feng, L. Siwei, Y. Xin et al., Optimization of pyroelectric figures of merit via magnesia doping in lithium tantalate single crystal, J. of Physics D: Applied Physics 51 (2018) P 395101.

DOI: 10.1088/1361-6463/aad88d

Google Scholar

[8] A. Vyalikh, M. Zschornak, T. Kohler et al., Analysis of the defect clusters in congruent lithium tantalite, Physical Review Materials 2 (2018) P 013804.

Google Scholar

[9] V. Pryakhina, E. Greshnyakov, B. Lisjikh, As-grown domain structure in lithium tantalate with spatially nonuniform composition, Ferroelectrics 525 (2018) 47‒53.

DOI: 10.1080/00150193.2018.1432926

Google Scholar

[10] A. Buzady, M. Unferdorben, D. Toth et al., Refractive Index and Absorption Coefficient of Undoped and Mg-Doped Lithium Tantalate in the Terahertz Range, J. of Infrared Millimeter and Terahertz Waves 38 (2017) 963‒967.

DOI: 10.1007/s10762-017-0393-y

Google Scholar

[11] L. Kyu-Sup, K. Do-Kyeong, E.Y. Nan, Temperature-dependent Sellmeier equation at terahertz frequency range for 1 mol % MgO-doped stoichiometric lithium tantalite, Japanese J. of Applied Physics 56 (2017) Р 040303.

DOI: 10.7567/jjap.56.040303

Google Scholar

[12] Z. Xiaoling, Y. Ming, L. Mengxue, Comparison of broadband second-harmonic generation in periodically poled stoichiometric lithium tantalate with different magnesium oxide doping concentrations, J. of Optoelectronics and Advanced Materials 18 (2016) 613‒617.

Google Scholar

[13] S. Masloboeva, M. Palatnikov, L. Arutyunyan et al., Obtaining and studying microcrystalline powders of lithium niobate and tantalite, Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials (Tver: Tver State University) 8 (2016) 239‒246.

DOI: 10.26456/pcascnn/2019.11.478

Google Scholar

[14] H. Ichioka, S. Furuya, T. Asaka Crystal structures and enhancement of photoluminescence intensities by effective doping for lithium tantalate phosphors, Powder Diffraction 30 (2015) 326‒332.

DOI: 10.1017/s0885715615000688

Google Scholar

[15] I. Levina, Z. Shapiro, V. Shishov, Methods for the synthesis of methaniobates and metatantalates of alkali metals, Inorganic glasses, coatings and materials 2 (1975) 144‒151.

Google Scholar

[16] G. Janson, I. Vinogradova, H. Zanetskite et al., Formation reactions and properties of alkaline tantalates, Inorganic glasses, coatings and materials 2 (1983), 137-147.

Google Scholar

[17] M. Palatnikov, N. Sidorov, V. Kalinnikov, Ferroelectric solid solutions based on oxide compounds of niobium and tantalum: synthesis, study of structural ordering and physical characteristics, Nauka, St. Petersburg, (2002).

Google Scholar

[18] S. Masloboeva, I. Elizarova, L. Arutyunyan et al., Synthesis and study of a mixture of lithium tantalate doped with rare-earth elements, Reports of the Academy of Sciences 460 (2015) 427‒431.

DOI: 10.1134/s0012501615020037

Google Scholar

[19] S. Masloboeva, G. Duboshin, L. Arutyunyan, Studies on the production of potassium heptafluorotantalate from fluoride-sulphate solutions, Vestnik MSTU 12 (2009) 279-285.

Google Scholar

[20] R. Hsu, E. Maslen, D. du Boulay et al., Synchrotron X-ray Studies of LiNbO3 and LiTaO3 Acta Crystallographica Section B: Structural Science 53 (1997) 420‒428.

DOI: 10.1107/s010876819600777x

Google Scholar