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Effect of Grain Size on the Behavior of Exfoliation Corrosion in Cold-Rolled Mg-14Mass%Li-3Mass%Al Alloy

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Abstract:

The effect of grain size on the initiation behavior of exfoliation corrosion in cold-rolled Mg-14mass%Li-3mass%Al alloy was examined. Exfoliation corrosion initiated after 30 minutes in the coarse-grained structure (279μm), whereas it was delayed to 60 minutes in the fine-grained structure (75μm) and further to 75 minutes in the ultrafine-grained structure (39μm). This delay is attributed to the suppression of shear band formation and localization during cold rolling with decreasing grain size, which enhances the uniformity of surface reactions in the corrosive environment and promotes faster and denser formation of the protective film at the early stage. Accordingly, the improved condition of the initial corrosion film is considered the primary factor responsible for the delayed onset of exfoliation corrosion.

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Periodical:

Solid State Phenomena (Volume 384)

Pages:

39-44

DOI:

https://doi.org/10.4028/p-N4Mll0

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Online since:

January 2026

Authors:

Yuta Kawahara*, Taiki Morishige

Keywords:

Corrosion, Dislocation, Exfoliation Corrosion, Grain Boundary, Grain Size, Mg-Li Alloy, Microstructure, Oxide Film, Shear Band

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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* - Corresponding Author

References

[1] Yutaro Obata, Materials Transactions, Vol. 57, No. 10 (2016) p.1853 to 1856.

Google Scholar

[2] Hirokazu Doi, Materials Transactions, Vol. 54, No. 9 (2013) p.1863 to 1866.

Google Scholar

[3] G.R. Argade, S.K. Panigrahi, R.S. Mishra. Corrosion Science 58 (2012) 145-151.

Google Scholar

[4] Zezhou Li, Bingfeng Wang, Shiteng Zhao, RusLan Z. Valiev, Kenneth S. Vecchio, Marc A. Mevers Acta Materialia 125 (2017) 210-218.

Google Scholar

[5] Srikant Gollapudi, Corrosion Science, 62 (2012) 90-94.

Google Scholar

[6] K.D. Ralston, N. Birbilis and C.H.J. Davies, Scripta Materialia 63 (2010) 1201–1204.

DOI: 10.1016/j.scriptamat.2010.08.035

Google Scholar

[7] Yuanxiang Zhang, Yukun Xia, Hao Dun, Yang Wang, Feng Fang, Yu Zhang, Jiecheng Zhang, Qi Chen, Kuangyu Zhai and Raja Devesh Kumar Misra, Materials 2021, 14(4), 775.

Google Scholar

[8] Yinghui Zhang, Jingfu Yang, JingQin and Haibin Zhao, Material Research Express 8(2021) 016303.

Google Scholar

[9] Daniela Nickel, Dangmar Dietrich, Thomas Mehner, Philipp Frint, Dagobert Spieler and Thomas Lampke, Metals 2015,5(1), 172-191.

DOI: 10.3390/met5010172

Google Scholar

[10] Ramatou Ly, Karl T. Hartwig, Homero Castaneda, Corrosion science 139 (2018) 47-57.

Google Scholar